Magnetic States of Fe2+ Ions in FexMn1 – xS Induced by Chemical Pressure
Influence of the chemical pressure ( x ) in single crystals of Fe x Mn 1 – x S (0.12 ≤ x ≤ 0.29) on the spin state of iron ions was studied by Mössbauer spectroscopy in the temperature range from 4.2 to 300 K. Peculiarities of formation of the paramagnetic and antiferromagnetic phases of solid sol...
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| Veröffentlicht in: | Physics of the solid state 2021, Vol.63 (1), p.68-74 |
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| creator | Abramova, G. M. Knyazev, Yu. V. Bayukov, O. A. Kubrin, S. P. |
| description | Influence of the chemical pressure (
x
) in single crystals of Fe
x
Mn
1 –
x
S (0.12 ≤
x
≤ 0.29) on the spin state of iron ions was studied by Mössbauer spectroscopy in the temperature range from 4.2 to 300 K. Peculiarities of formation of the paramagnetic and antiferromagnetic phases of solid solutions were found. Substitution of Fe
2+
cations in the high-spin state for Mn
2+
was found to occur in Fe
x
Mn
1 –
x
S as
x
changes. A decrease in the distance between the ions in Fe
x
Mn
1 –
x
S induces changes in the state of the Fe
2+
ions in the samples with
x
= 0.25 and 0.29. The asymmetry parameter of the electric field gradient (EFG) tensor and the angle between the directions of the magnetic moment and the principal axis of the electric field gradient were found to change in the magnetically ordered phase at 4.2 K; the angle between the magnetic moment and the electric field gradient axis changes from 21° in the sample with
x
= 0.12 to 33° when
x
= 0.29. |
| doi_str_mv | 10.1134/S1063783421010029 |
| format | Article |
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x
) in single crystals of Fe
x
Mn
1 –
x
S (0.12 ≤
x
≤ 0.29) on the spin state of iron ions was studied by Mössbauer spectroscopy in the temperature range from 4.2 to 300 K. Peculiarities of formation of the paramagnetic and antiferromagnetic phases of solid solutions were found. Substitution of Fe
2+
cations in the high-spin state for Mn
2+
was found to occur in Fe
x
Mn
1 –
x
S as
x
changes. A decrease in the distance between the ions in Fe
x
Mn
1 –
x
S induces changes in the state of the Fe
2+
ions in the samples with
x
= 0.25 and 0.29. The asymmetry parameter of the electric field gradient (EFG) tensor and the angle between the directions of the magnetic moment and the principal axis of the electric field gradient were found to change in the magnetically ordered phase at 4.2 K; the angle between the magnetic moment and the electric field gradient axis changes from 21° in the sample with
x
= 0.12 to 33° when
x
= 0.29.</description><identifier>ISSN: 1063-7834</identifier><identifier>EISSN: 1090-6460</identifier><identifier>DOI: 10.1134/S1063783421010029</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Antiferromagnetism ; Charged particles ; Electric fields ; Ferrous ions ; Magnetic moments ; Mossbauer spectroscopy ; Physics ; Physics and Astronomy ; Semiconductors ; Single crystals ; Solid solutions ; Solid State Physics ; Tensors</subject><ispartof>Physics of the solid state, 2021, Vol.63 (1), p.68-74</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 1063-7834, Physics of the Solid State, 2021, Vol. 63, No. 1, pp. 68–74. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Fizika Tverdogo Tela, 2021, Vol. 63, No. 1, pp. 69–75.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1619-28720dd711d0517baf36a56565f91e6dc96dca66d4e0f5da8790bdd59f200cd93</citedby><cites>FETCH-LOGICAL-c1619-28720dd711d0517baf36a56565f91e6dc96dca66d4e0f5da8790bdd59f200cd93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1063783421010029$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1063783421010029$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Abramova, G. M.</creatorcontrib><creatorcontrib>Knyazev, Yu. V.</creatorcontrib><creatorcontrib>Bayukov, O. A.</creatorcontrib><creatorcontrib>Kubrin, S. P.</creatorcontrib><title>Magnetic States of Fe2+ Ions in FexMn1 – xS Induced by Chemical Pressure</title><title>Physics of the solid state</title><addtitle>Phys. Solid State</addtitle><description>Influence of the chemical pressure (
x
) in single crystals of Fe
x
Mn
1 –
x
S (0.12 ≤
x
≤ 0.29) on the spin state of iron ions was studied by Mössbauer spectroscopy in the temperature range from 4.2 to 300 K. Peculiarities of formation of the paramagnetic and antiferromagnetic phases of solid solutions were found. Substitution of Fe
2+
cations in the high-spin state for Mn
2+
was found to occur in Fe
x
Mn
1 –
x
S as
x
changes. A decrease in the distance between the ions in Fe
x
Mn
1 –
x
S induces changes in the state of the Fe
2+
ions in the samples with
x
= 0.25 and 0.29. The asymmetry parameter of the electric field gradient (EFG) tensor and the angle between the directions of the magnetic moment and the principal axis of the electric field gradient were found to change in the magnetically ordered phase at 4.2 K; the angle between the magnetic moment and the electric field gradient axis changes from 21° in the sample with
x
= 0.12 to 33° when
x
= 0.29.</description><subject>Antiferromagnetism</subject><subject>Charged particles</subject><subject>Electric fields</subject><subject>Ferrous ions</subject><subject>Magnetic moments</subject><subject>Mossbauer spectroscopy</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Semiconductors</subject><subject>Single crystals</subject><subject>Solid solutions</subject><subject>Solid State Physics</subject><subject>Tensors</subject><issn>1063-7834</issn><issn>1090-6460</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1UMFKAzEQDaJgrX6At4BHWZ3J7mY3RylWF1oUqucl3SR1S5utyS60N__BH-i39FP8ElMqeBAZhnnDvPcGHiGXCDeIcXI7QeBxlscJQ0AAJo5ID0FAxBMOx3vM42h_PyVn3s8BEDEVPTIay5nVbV3RSStb7Wlj6FCza1o01tPahmU9trjbfn187rbrCS2s6iqt6HRDB296WVdyQZ-d9r5z-pycGLnw-uJn9snr8P5l8BiNnh6Kwd0oqpCjiFieMVAqQ1SQYjaVJuYy5aGMQM1VJUJLzlWiwaRK5pmAqVKpMAygUiLuk6uD78o17532bTlvOmfDy5IlOccspJAEFh5YlWu8d9qUK1cvpduUCOU-tPJPaEHDDhofuHam3a_z_6Jvh6RtoA</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Abramova, G. M.</creator><creator>Knyazev, Yu. V.</creator><creator>Bayukov, O. A.</creator><creator>Kubrin, S. P.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>Magnetic States of Fe2+ Ions in FexMn1 – xS Induced by Chemical Pressure</title><author>Abramova, G. M. ; Knyazev, Yu. V. ; Bayukov, O. A. ; Kubrin, S. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1619-28720dd711d0517baf36a56565f91e6dc96dca66d4e0f5da8790bdd59f200cd93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Antiferromagnetism</topic><topic>Charged particles</topic><topic>Electric fields</topic><topic>Ferrous ions</topic><topic>Magnetic moments</topic><topic>Mossbauer spectroscopy</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Semiconductors</topic><topic>Single crystals</topic><topic>Solid solutions</topic><topic>Solid State Physics</topic><topic>Tensors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Abramova, G. M.</creatorcontrib><creatorcontrib>Knyazev, Yu. V.</creatorcontrib><creatorcontrib>Bayukov, O. A.</creatorcontrib><creatorcontrib>Kubrin, S. P.</creatorcontrib><collection>CrossRef</collection><jtitle>Physics of the solid state</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abramova, G. M.</au><au>Knyazev, Yu. V.</au><au>Bayukov, O. A.</au><au>Kubrin, S. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Magnetic States of Fe2+ Ions in FexMn1 – xS Induced by Chemical Pressure</atitle><jtitle>Physics of the solid state</jtitle><stitle>Phys. Solid State</stitle><date>2021</date><risdate>2021</risdate><volume>63</volume><issue>1</issue><spage>68</spage><epage>74</epage><pages>68-74</pages><issn>1063-7834</issn><eissn>1090-6460</eissn><abstract>Influence of the chemical pressure (
x
) in single crystals of Fe
x
Mn
1 –
x
S (0.12 ≤
x
≤ 0.29) on the spin state of iron ions was studied by Mössbauer spectroscopy in the temperature range from 4.2 to 300 K. Peculiarities of formation of the paramagnetic and antiferromagnetic phases of solid solutions were found. Substitution of Fe
2+
cations in the high-spin state for Mn
2+
was found to occur in Fe
x
Mn
1 –
x
S as
x
changes. A decrease in the distance between the ions in Fe
x
Mn
1 –
x
S induces changes in the state of the Fe
2+
ions in the samples with
x
= 0.25 and 0.29. The asymmetry parameter of the electric field gradient (EFG) tensor and the angle between the directions of the magnetic moment and the principal axis of the electric field gradient were found to change in the magnetically ordered phase at 4.2 K; the angle between the magnetic moment and the electric field gradient axis changes from 21° in the sample with
x
= 0.12 to 33° when
x
= 0.29.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1063783421010029</doi><tpages>7</tpages></addata></record> |
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| subjects | Antiferromagnetism Charged particles Electric fields Ferrous ions Magnetic moments Mossbauer spectroscopy Physics Physics and Astronomy Semiconductors Single crystals Solid solutions Solid State Physics Tensors |
| title | Magnetic States of Fe2+ Ions in FexMn1 – xS Induced by Chemical Pressure |
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