Copper anchored on phosphorus g-C3N4 as a highly efficient photocatalyst for the synthesis of N-arylpyridin-2-amines
A heterogeneous photocatalyst based on copper modified phosphorus doped g-C3N4 (Cu/P-CN) has been prepared and characterized. This recyclable catalyst exhibited high photocatalytic activity for the synthesis of N-arylpyridin-2-amine derivatives by the reaction of 2-aminopyridine and aryl boronic aci...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2021-01, Vol.23 (2), p.1041-1049 |
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| container_issue | 2 |
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| container_title | Green chemistry : an international journal and green chemistry resource : GC |
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| creator | Jia-Qi, Di Zhang, Mo Yu-Xuan, Chen Jin-Xin, Wang Shan-Shan Geng Jia-Qi, Tang Zhan-Hui, Zhang |
| description | A heterogeneous photocatalyst based on copper modified phosphorus doped g-C3N4 (Cu/P-CN) has been prepared and characterized. This recyclable catalyst exhibited high photocatalytic activity for the synthesis of N-arylpyridin-2-amine derivatives by the reaction of 2-aminopyridine and aryl boronic acid at room temperature under the irradiation of blue light. Importantly, the range of substrates for this coupling reaction has been expanded to include aryl boronic acids with strong electron-withdrawing groups as viable raw materials. In addition, this heterogeneous catalyst can be used at least 6 times while maintaining its catalytic activity. |
| doi_str_mv | 10.1039/d0gc03400b |
| format | Article |
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This recyclable catalyst exhibited high photocatalytic activity for the synthesis of N-arylpyridin-2-amine derivatives by the reaction of 2-aminopyridine and aryl boronic acid at room temperature under the irradiation of blue light. Importantly, the range of substrates for this coupling reaction has been expanded to include aryl boronic acids with strong electron-withdrawing groups as viable raw materials. In addition, this heterogeneous catalyst can be used at least 6 times while maintaining its catalytic activity.</description><identifier>ISSN: 1463-9262</identifier><identifier>EISSN: 1463-9270</identifier><identifier>DOI: 10.1039/d0gc03400b</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Amines ; Aromatic compounds ; Carbon nitride ; Catalysts ; Catalytic activity ; Copper ; Green chemistry ; Irradiation ; Phosphorus ; Photocatalysis ; Photocatalysts ; Radiation ; Raw materials ; Room temperature ; Substrates</subject><ispartof>Green chemistry : an international journal and green chemistry resource : GC, 2021-01, Vol.23 (2), p.1041-1049</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c191t-2c1d437d787bc506cf0d67c5137e20a0c39bf1531a7b9e7ce26e9ab3866e0e043</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Jia-Qi, Di</creatorcontrib><creatorcontrib>Zhang, Mo</creatorcontrib><creatorcontrib>Yu-Xuan, Chen</creatorcontrib><creatorcontrib>Jin-Xin, Wang</creatorcontrib><creatorcontrib>Shan-Shan Geng</creatorcontrib><creatorcontrib>Jia-Qi, Tang</creatorcontrib><creatorcontrib>Zhan-Hui, Zhang</creatorcontrib><title>Copper anchored on phosphorus g-C3N4 as a highly efficient photocatalyst for the synthesis of N-arylpyridin-2-amines</title><title>Green chemistry : an international journal and green chemistry resource : GC</title><description>A heterogeneous photocatalyst based on copper modified phosphorus doped g-C3N4 (Cu/P-CN) has been prepared and characterized. This recyclable catalyst exhibited high photocatalytic activity for the synthesis of N-arylpyridin-2-amine derivatives by the reaction of 2-aminopyridine and aryl boronic acid at room temperature under the irradiation of blue light. Importantly, the range of substrates for this coupling reaction has been expanded to include aryl boronic acids with strong electron-withdrawing groups as viable raw materials. In addition, this heterogeneous catalyst can be used at least 6 times while maintaining its catalytic activity.</description><subject>Amines</subject><subject>Aromatic compounds</subject><subject>Carbon nitride</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Copper</subject><subject>Green chemistry</subject><subject>Irradiation</subject><subject>Phosphorus</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Radiation</subject><subject>Raw materials</subject><subject>Room temperature</subject><subject>Substrates</subject><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNo9jUtLxDAUhYMoOD42_oKA6-jNo0m7lOILhnGj6yFNb6YZalOTzKL_3hHFxeE7i49zCLnhcMdBNvc97BxIBdCdkBVXWrJGGDj971qck4uc9wCcG61WpLRxnjFRO7khJuxpnOg8xHxMOmS6Y63cKGoztXQIu2FcKHofXMCp_HglOlvsuORCfUy0DEjzMh2RQ6bR0w2zaRnnJYU-TEww-xkmzFfkzNsx4_UfL8nH0-N7-8LWb8-v7cOaOd7wwoTjvZKmN7XpXAXaeei1cRWXBgVYcLLpPK8kt6Zr0DgUGhvbyVprBAQlL8nt7-6c4tcBc9nu4yFNx8utULUSFa8rI78BnmFdTw</recordid><startdate>20210101</startdate><enddate>20210101</enddate><creator>Jia-Qi, Di</creator><creator>Zhang, Mo</creator><creator>Yu-Xuan, Chen</creator><creator>Jin-Xin, Wang</creator><creator>Shan-Shan Geng</creator><creator>Jia-Qi, Tang</creator><creator>Zhan-Hui, Zhang</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7ST</scope><scope>7U6</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope></search><sort><creationdate>20210101</creationdate><title>Copper anchored on phosphorus g-C3N4 as a highly efficient photocatalyst for the synthesis of N-arylpyridin-2-amines</title><author>Jia-Qi, Di ; Zhang, Mo ; Yu-Xuan, Chen ; Jin-Xin, Wang ; Shan-Shan Geng ; Jia-Qi, Tang ; Zhan-Hui, Zhang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c191t-2c1d437d787bc506cf0d67c5137e20a0c39bf1531a7b9e7ce26e9ab3866e0e043</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Amines</topic><topic>Aromatic compounds</topic><topic>Carbon nitride</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Copper</topic><topic>Green chemistry</topic><topic>Irradiation</topic><topic>Phosphorus</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><topic>Radiation</topic><topic>Raw materials</topic><topic>Room temperature</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jia-Qi, Di</creatorcontrib><creatorcontrib>Zhang, Mo</creatorcontrib><creatorcontrib>Yu-Xuan, Chen</creatorcontrib><creatorcontrib>Jin-Xin, Wang</creatorcontrib><creatorcontrib>Shan-Shan Geng</creatorcontrib><creatorcontrib>Jia-Qi, Tang</creatorcontrib><creatorcontrib>Zhan-Hui, Zhang</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jia-Qi, Di</au><au>Zhang, Mo</au><au>Yu-Xuan, Chen</au><au>Jin-Xin, Wang</au><au>Shan-Shan Geng</au><au>Jia-Qi, Tang</au><au>Zhan-Hui, Zhang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copper anchored on phosphorus g-C3N4 as a highly efficient photocatalyst for the synthesis of N-arylpyridin-2-amines</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><date>2021-01-01</date><risdate>2021</risdate><volume>23</volume><issue>2</issue><spage>1041</spage><epage>1049</epage><pages>1041-1049</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>A heterogeneous photocatalyst based on copper modified phosphorus doped g-C3N4 (Cu/P-CN) has been prepared and characterized. This recyclable catalyst exhibited high photocatalytic activity for the synthesis of N-arylpyridin-2-amine derivatives by the reaction of 2-aminopyridine and aryl boronic acid at room temperature under the irradiation of blue light. Importantly, the range of substrates for this coupling reaction has been expanded to include aryl boronic acids with strong electron-withdrawing groups as viable raw materials. In addition, this heterogeneous catalyst can be used at least 6 times while maintaining its catalytic activity.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d0gc03400b</doi><tpages>9</tpages></addata></record> |
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| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2021-01, Vol.23 (2), p.1041-1049 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Amines Aromatic compounds Carbon nitride Catalysts Catalytic activity Copper Green chemistry Irradiation Phosphorus Photocatalysis Photocatalysts Radiation Raw materials Room temperature Substrates |
| title | Copper anchored on phosphorus g-C3N4 as a highly efficient photocatalyst for the synthesis of N-arylpyridin-2-amines |
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