Boron group element doping of Li1.5Al0.5Ge1.5(PO4)3 based on microwave sintering
We report effectiveness of dopants selected from group 13, such as B, Ga, and In, on the conductivity of Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 (LAGP) that is recognized as one of the promising solid electrolytes for next-generation solid-state lithium batteries. To minimize loss of versatile element, cryst...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2021, Vol.25 (2), p.527-534 |
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| container_issue | 2 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Yan, Binggong Kang, Lei Kotobuki, Masashi He, Linchun Liu, Bin Jiang, Kaiyong |
| description | We report effectiveness of dopants selected from group 13, such as B, Ga, and In, on the conductivity of Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
(LAGP) that is recognized as one of the promising solid electrolytes for next-generation solid-state lithium batteries. To minimize loss of versatile element, crystallization of LAGP using a microwave irradiation is introduced. Experimental results demonstrate that B enhances grain boundary conductivity, while Ga improves the bulk ionic conductivity. Co-doping of B and Ga leads to enhanced total ionic conductivity and remarkably reduced activation energy. |
| doi_str_mv | 10.1007/s10008-020-04829-2 |
| format | Article |
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1.5
Al
0.5
Ge
1.5
(PO
4
)
3
(LAGP) that is recognized as one of the promising solid electrolytes for next-generation solid-state lithium batteries. To minimize loss of versatile element, crystallization of LAGP using a microwave irradiation is introduced. Experimental results demonstrate that B enhances grain boundary conductivity, while Ga improves the bulk ionic conductivity. Co-doping of B and Ga leads to enhanced total ionic conductivity and remarkably reduced activation energy.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-020-04829-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Boron ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Crystallization ; Doping ; Electrochemistry ; Energy Storage ; Gallium ; Grain boundaries ; Ion currents ; Ions ; Lithium ; Lithium batteries ; Microwave sintering ; Molten salt electrolytes ; Original Paper ; Physical Chemistry ; Solid electrolytes</subject><ispartof>Journal of solid state electrochemistry, 2021, Vol.25 (2), p.527-534</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2712-ebd31c7ff40c1f39c9e449d06db0f6e3abc1f7dd9f7d7ccb63991fb03f9239433</citedby><cites>FETCH-LOGICAL-c2712-ebd31c7ff40c1f39c9e449d06db0f6e3abc1f7dd9f7d7ccb63991fb03f9239433</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10008-020-04829-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10008-020-04829-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Yan, Binggong</creatorcontrib><creatorcontrib>Kang, Lei</creatorcontrib><creatorcontrib>Kotobuki, Masashi</creatorcontrib><creatorcontrib>He, Linchun</creatorcontrib><creatorcontrib>Liu, Bin</creatorcontrib><creatorcontrib>Jiang, Kaiyong</creatorcontrib><title>Boron group element doping of Li1.5Al0.5Ge1.5(PO4)3 based on microwave sintering</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>We report effectiveness of dopants selected from group 13, such as B, Ga, and In, on the conductivity of Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
(LAGP) that is recognized as one of the promising solid electrolytes for next-generation solid-state lithium batteries. To minimize loss of versatile element, crystallization of LAGP using a microwave irradiation is introduced. Experimental results demonstrate that B enhances grain boundary conductivity, while Ga improves the bulk ionic conductivity. Co-doping of B and Ga leads to enhanced total ionic conductivity and remarkably reduced activation energy.</description><subject>Analytical Chemistry</subject><subject>Boron</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Crystallization</subject><subject>Doping</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Gallium</subject><subject>Grain boundaries</subject><subject>Ion currents</subject><subject>Ions</subject><subject>Lithium</subject><subject>Lithium batteries</subject><subject>Microwave sintering</subject><subject>Molten salt electrolytes</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Solid electrolytes</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKt_wFPAix5SJx_dTY611CoU2oOew24-ypZ2syat4r837QrevLwzDPPMx4vQLYURBSgfU1aQBBgQEJIpws7QgArOCZSFPD_ljEgh5SW6SmkDQMuCwgCtnkIMLV7HcOiw27qda_fYhq5p1zh4vGjoaDzZwmg8dzm7Xy3FA8d1lZzFGds1Joav6tPh1LR7FzN1jS58tU3u5jcO0fvz7G36QhbL-et0siCGlZQRV1tOTem9AEM9V0Y5IZSFwtbgC8erOpdLa1WW0pi64EpRXwP3inGVHxuiu35uF8PHwaW93oRDbPNKzYSkDBiDYxfru_KdKUXndRebXRW_NQV9dE73zunsnD45p1mGeA-l7viRi3-j_6F-AE7ybqk</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Yan, Binggong</creator><creator>Kang, Lei</creator><creator>Kotobuki, Masashi</creator><creator>He, Linchun</creator><creator>Liu, Bin</creator><creator>Jiang, Kaiyong</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>Boron group element doping of Li1.5Al0.5Ge1.5(PO4)3 based on microwave sintering</title><author>Yan, Binggong ; Kang, Lei ; Kotobuki, Masashi ; He, Linchun ; Liu, Bin ; Jiang, Kaiyong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2712-ebd31c7ff40c1f39c9e449d06db0f6e3abc1f7dd9f7d7ccb63991fb03f9239433</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Analytical Chemistry</topic><topic>Boron</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Crystallization</topic><topic>Doping</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Gallium</topic><topic>Grain boundaries</topic><topic>Ion currents</topic><topic>Ions</topic><topic>Lithium</topic><topic>Lithium batteries</topic><topic>Microwave sintering</topic><topic>Molten salt electrolytes</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Solid electrolytes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yan, Binggong</creatorcontrib><creatorcontrib>Kang, Lei</creatorcontrib><creatorcontrib>Kotobuki, Masashi</creatorcontrib><creatorcontrib>He, Linchun</creatorcontrib><creatorcontrib>Liu, Bin</creatorcontrib><creatorcontrib>Jiang, Kaiyong</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yan, Binggong</au><au>Kang, Lei</au><au>Kotobuki, Masashi</au><au>He, Linchun</au><au>Liu, Bin</au><au>Jiang, Kaiyong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Boron group element doping of Li1.5Al0.5Ge1.5(PO4)3 based on microwave sintering</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2021</date><risdate>2021</risdate><volume>25</volume><issue>2</issue><spage>527</spage><epage>534</epage><pages>527-534</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>We report effectiveness of dopants selected from group 13, such as B, Ga, and In, on the conductivity of Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
(LAGP) that is recognized as one of the promising solid electrolytes for next-generation solid-state lithium batteries. To minimize loss of versatile element, crystallization of LAGP using a microwave irradiation is introduced. Experimental results demonstrate that B enhances grain boundary conductivity, while Ga improves the bulk ionic conductivity. Co-doping of B and Ga leads to enhanced total ionic conductivity and remarkably reduced activation energy.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-020-04829-2</doi><tpages>8</tpages></addata></record> |
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| ispartof | Journal of solid state electrochemistry, 2021, Vol.25 (2), p.527-534 |
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| source | SpringerNature Journals |
| subjects | Analytical Chemistry Boron Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Crystallization Doping Electrochemistry Energy Storage Gallium Grain boundaries Ion currents Ions Lithium Lithium batteries Microwave sintering Molten salt electrolytes Original Paper Physical Chemistry Solid electrolytes |
| title | Boron group element doping of Li1.5Al0.5Ge1.5(PO4)3 based on microwave sintering |
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