Improved capture of carbon dioxide and methane via adding micropores within porous boron nitride fibers

In this paper, a novel type of micropore-rich boron nitride (BN) fibers (m-BNFs) was prepared by adding a surfactant hexamethylenetetramine in the traditional melamine-diborate (M·2B) precursor of conventional porous BN fibers (BNFs). As a result, extra micropore distribution could be introduced wit...

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Veröffentlicht in:Journal of materials science 2019-07, Vol.54 (14), p.10168-10178
Hauptverfasser: Wang, DeKun, Xue, Yanming, Wang, Chenyang, Ji, Jiawei, Zhou, Zheng, Tang, Chengchun
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container_end_page 10178
container_issue 14
container_start_page 10168
container_title Journal of materials science
container_volume 54
creator Wang, DeKun
Xue, Yanming
Wang, Chenyang
Ji, Jiawei
Zhou, Zheng
Tang, Chengchun
description In this paper, a novel type of micropore-rich boron nitride (BN) fibers (m-BNFs) was prepared by adding a surfactant hexamethylenetetramine in the traditional melamine-diborate (M·2B) precursor of conventional porous BN fibers (BNFs). As a result, extra micropore distribution could be introduced within m-BNFs bodies. Due to adding of the micropores, the CO 2 capture capacities of the BN fibers were improved to be 2.85 mmol g −1 , which were significantly higher than that of original porous BNFs. Also, these m-BNFs would have an enhanced adsorption capacity of methane, the amount of up to 0.71 mmol g −1 . At the same time, these new m-BNFs materials showed excellent thermal stability, which would be more valuable for advanced gas adsorption working in a high-temperature environment in the future.
doi_str_mv 10.1007/s10853-019-03617-2
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subjects Adsorption
Atmospheric pressure
Boron
Boron fibers
Boron nitride
Carbon dioxide
Carbon sequestration
Characterization and Evaluation of Materials
Chemical Routes to Materials
Chemical vapor deposition
Chemistry and Materials Science
Classical Mechanics
Crystallography and Scattering Methods
Gases
Hexamethylenetetramine
High temperature environments
Materials Science
Melamine
Methane
Morphology
Polymer Sciences
Porous materials
Solid Mechanics
Surfactants
Thermal stability
title Improved capture of carbon dioxide and methane via adding micropores within porous boron nitride fibers
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