Engineering Ni3+ inside nickel selenide as efficient bifunctional oxygen electrocatalysts for Zn–air batteries
Developing a high-efficienct, low-cost and stable non-noble-metal-based bifunctional electrocatalyst for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) as oxygen electrode material in the rechargeable zinc–air battery is crucial in renewable energy conversion technologies. I...
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| Veröffentlicht in: | Journal of materials science 2019-06, Vol.54 (12), p.9063-9074 |
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| container_title | Journal of materials science |
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| creator | Pan, Qiu-Ren Li, Si-Jie Tong, Kaixin Xie, Chong Peng, Lijuan Li, Nan Wang, Dong-Yao Su, Hong |
| description | Developing a high-efficienct, low-cost and stable non-noble-metal-based bifunctional electrocatalyst for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) as oxygen electrode material in the rechargeable zinc–air battery is crucial in renewable energy conversion technologies. In this work, nitrogen-doped hollow carbon sphere (NHCS) decorated with various nickel selenide (Ni
x
Se) nanoparticles had been designed and successfully prepared. Among them, the Ni
0.85
Se–NHCS with the highest percentage of Ni
3+
could serve as a new efficient bifunctional electrocatalyst toward ORR/OER (with an onset potential of 0.850 V for ORR and a potential of 1.583 V at 10 mA·cm
−2
for OER) in an alkaline medium. Furthermore, the assembled Zn–air battery coupled with Ni
0.85
Se–NHCS electrode has excellent discharging–charging performance and long lifetime. This work provides a valuable understanding on transition metal non-oxide electrocatalysts and expands the applications of selenide-based materials. |
| doi_str_mv | 10.1007/s10853-019-03520-w |
| format | Article |
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x
Se) nanoparticles had been designed and successfully prepared. Among them, the Ni
0.85
Se–NHCS with the highest percentage of Ni
3+
could serve as a new efficient bifunctional electrocatalyst toward ORR/OER (with an onset potential of 0.850 V for ORR and a potential of 1.583 V at 10 mA·cm
−2
for OER) in an alkaline medium. Furthermore, the assembled Zn–air battery coupled with Ni
0.85
Se–NHCS electrode has excellent discharging–charging performance and long lifetime. This work provides a valuable understanding on transition metal non-oxide electrocatalysts and expands the applications of selenide-based materials.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-019-03520-w</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Charging ; Chemistry and Materials Science ; Classical Mechanics ; Crystallography and Scattering Methods ; Electrocatalysts ; Electrode materials ; Electrodes ; Energy conversion ; Energy Materials ; Materials Science ; Metal air batteries ; Nanoparticles ; Nickel ; Noble metals ; Oxygen evolution reactions ; Oxygen reduction reactions ; Polymer Sciences ; Rechargeable batteries ; Solid Mechanics ; Transition metals ; Zinc-oxygen batteries</subject><ispartof>Journal of materials science, 2019-06, Vol.54 (12), p.9063-9074</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c286t-db58debdf1808923987935f6bbce8e511de64a58dfca586da0df61205a1fc36a3</citedby><cites>FETCH-LOGICAL-c286t-db58debdf1808923987935f6bbce8e511de64a58dfca586da0df61205a1fc36a3</cites><orcidid>0000-0002-8148-1891</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-019-03520-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-019-03520-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Pan, Qiu-Ren</creatorcontrib><creatorcontrib>Li, Si-Jie</creatorcontrib><creatorcontrib>Tong, Kaixin</creatorcontrib><creatorcontrib>Xie, Chong</creatorcontrib><creatorcontrib>Peng, Lijuan</creatorcontrib><creatorcontrib>Li, Nan</creatorcontrib><creatorcontrib>Wang, Dong-Yao</creatorcontrib><creatorcontrib>Su, Hong</creatorcontrib><title>Engineering Ni3+ inside nickel selenide as efficient bifunctional oxygen electrocatalysts for Zn–air batteries</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Developing a high-efficienct, low-cost and stable non-noble-metal-based bifunctional electrocatalyst for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) as oxygen electrode material in the rechargeable zinc–air battery is crucial in renewable energy conversion technologies. In this work, nitrogen-doped hollow carbon sphere (NHCS) decorated with various nickel selenide (Ni
x
Se) nanoparticles had been designed and successfully prepared. Among them, the Ni
0.85
Se–NHCS with the highest percentage of Ni
3+
could serve as a new efficient bifunctional electrocatalyst toward ORR/OER (with an onset potential of 0.850 V for ORR and a potential of 1.583 V at 10 mA·cm
−2
for OER) in an alkaline medium. Furthermore, the assembled Zn–air battery coupled with Ni
0.85
Se–NHCS electrode has excellent discharging–charging performance and long lifetime. This work provides a valuable understanding on transition metal non-oxide electrocatalysts and expands the applications of selenide-based materials.</description><subject>Characterization and Evaluation of Materials</subject><subject>Charging</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crystallography and Scattering Methods</subject><subject>Electrocatalysts</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Energy conversion</subject><subject>Energy Materials</subject><subject>Materials Science</subject><subject>Metal air batteries</subject><subject>Nanoparticles</subject><subject>Nickel</subject><subject>Noble metals</subject><subject>Oxygen evolution reactions</subject><subject>Oxygen reduction reactions</subject><subject>Polymer Sciences</subject><subject>Rechargeable batteries</subject><subject>Solid Mechanics</subject><subject>Transition metals</subject><subject>Zinc-oxygen batteries</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kM1KAzEURoMoWKsv4CrgUkZvkk5mZiml_kDRjW7chEzmpqSOmTFJqd35Dr6hT-LUCu7c5BI433cvh5BTBhcMoLiMDMpcZMCqDETOIVvvkRHLC5FNShD7ZATAecYnkh2SoxiXAJAXnI1IP_ML5xGD8wt678Q5dT66Bql35gVbGrFFv_3rSNFaZxz6RGtnV94k13nd0u59s0BPB9Ck0BmddLuJKVLbBfrsvz4-tQu01ikNSzAekwOr24gnv3NMnq5nj9PbbP5wcze9mmeGlzJlTZ2XDdaNZSWUFRdVWVQit7KuDZaYM9agnOiBsWZ4ZaOhsZJxyDWzRkgtxuRs19uH7m2FMalltwrDvVHxybZTyoINFN9RJnQxBrSqD-5Vh41ioLZm1c6sGsyqH7NqPYTELhT7rTYMf9X_pL4B7C1_rQ</recordid><startdate>20190601</startdate><enddate>20190601</enddate><creator>Pan, Qiu-Ren</creator><creator>Li, Si-Jie</creator><creator>Tong, Kaixin</creator><creator>Xie, Chong</creator><creator>Peng, Lijuan</creator><creator>Li, Nan</creator><creator>Wang, Dong-Yao</creator><creator>Su, Hong</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-8148-1891</orcidid></search><sort><creationdate>20190601</creationdate><title>Engineering Ni3+ inside nickel selenide as efficient bifunctional oxygen electrocatalysts for Zn–air batteries</title><author>Pan, Qiu-Ren ; Li, Si-Jie ; Tong, Kaixin ; Xie, Chong ; Peng, Lijuan ; Li, Nan ; Wang, Dong-Yao ; Su, Hong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c286t-db58debdf1808923987935f6bbce8e511de64a58dfca586da0df61205a1fc36a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Charging</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crystallography and Scattering Methods</topic><topic>Electrocatalysts</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Energy conversion</topic><topic>Energy Materials</topic><topic>Materials Science</topic><topic>Metal air batteries</topic><topic>Nanoparticles</topic><topic>Nickel</topic><topic>Noble metals</topic><topic>Oxygen evolution reactions</topic><topic>Oxygen reduction reactions</topic><topic>Polymer Sciences</topic><topic>Rechargeable batteries</topic><topic>Solid Mechanics</topic><topic>Transition metals</topic><topic>Zinc-oxygen batteries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pan, Qiu-Ren</creatorcontrib><creatorcontrib>Li, Si-Jie</creatorcontrib><creatorcontrib>Tong, Kaixin</creatorcontrib><creatorcontrib>Xie, Chong</creatorcontrib><creatorcontrib>Peng, Lijuan</creatorcontrib><creatorcontrib>Li, Nan</creatorcontrib><creatorcontrib>Wang, Dong-Yao</creatorcontrib><creatorcontrib>Su, Hong</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pan, Qiu-Ren</au><au>Li, Si-Jie</au><au>Tong, Kaixin</au><au>Xie, Chong</au><au>Peng, Lijuan</au><au>Li, Nan</au><au>Wang, Dong-Yao</au><au>Su, Hong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Engineering Ni3+ inside nickel selenide as efficient bifunctional oxygen electrocatalysts for Zn–air batteries</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2019-06-01</date><risdate>2019</risdate><volume>54</volume><issue>12</issue><spage>9063</spage><epage>9074</epage><pages>9063-9074</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Developing a high-efficienct, low-cost and stable non-noble-metal-based bifunctional electrocatalyst for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) as oxygen electrode material in the rechargeable zinc–air battery is crucial in renewable energy conversion technologies. In this work, nitrogen-doped hollow carbon sphere (NHCS) decorated with various nickel selenide (Ni
x
Se) nanoparticles had been designed and successfully prepared. Among them, the Ni
0.85
Se–NHCS with the highest percentage of Ni
3+
could serve as a new efficient bifunctional electrocatalyst toward ORR/OER (with an onset potential of 0.850 V for ORR and a potential of 1.583 V at 10 mA·cm
−2
for OER) in an alkaline medium. Furthermore, the assembled Zn–air battery coupled with Ni
0.85
Se–NHCS electrode has excellent discharging–charging performance and long lifetime. This work provides a valuable understanding on transition metal non-oxide electrocatalysts and expands the applications of selenide-based materials.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-019-03520-w</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-8148-1891</orcidid></addata></record> |
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| subjects | Characterization and Evaluation of Materials Charging Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Electrocatalysts Electrode materials Electrodes Energy conversion Energy Materials Materials Science Metal air batteries Nanoparticles Nickel Noble metals Oxygen evolution reactions Oxygen reduction reactions Polymer Sciences Rechargeable batteries Solid Mechanics Transition metals Zinc-oxygen batteries |
| title | Engineering Ni3+ inside nickel selenide as efficient bifunctional oxygen electrocatalysts for Zn–air batteries |
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