Design of a smart sensor mesh for the measurement of pH in ostomy applications
A carbon-loaded polyethylene film was modified through a combination of laser ablation and electrochemical anodisation to yield a mechanically flexible yet electroanalytically sensitive mesh. A custom flavin derivative bearing a pendant phenol substituent was electropolymerised onto the substrate, a...
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| Veröffentlicht in: | Journal of materials science 2019-07, Vol.54 (14), p.10410-10419 |
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| creator | McLister, Anna Casimero, Charnete McConville, Aaron Taylor, Charlotte M. Lawrence, Clare L. Smith, Robert B. Mathur, Ashish Davis, James |
| description | A carbon-loaded polyethylene film was modified through a combination of laser ablation and electrochemical anodisation to yield a mechanically flexible yet electroanalytically sensitive mesh. A custom flavin derivative bearing a pendant phenol substituent was electropolymerised onto the substrate, and its electrochemical properties were investigated. The reversible flavin electrochemistry was retained (Ep = −0.374 V vs. Ag/AgCl, pH 7), and the peak position was found to shift by 60 mV/pH over a range covering pH 2.55 to pH 8.12. The stability of the resulting composite has been evaluated, and the analytical applicability towards the voltammetric measurement of pH in human urine was critically assessed. |
| doi_str_mv | 10.1007/s10853-019-03600-x |
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| subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Electrochemical analysis Electrochemical reactions Electrochemistry Hydrogen-ion concentration Laser ablation Materials for Life Sciences Materials Science Measurement Polyethylene Polyethylene films Polymer Sciences Sensors Silver chloride Smart sensors Solid Mechanics Stability analysis Substrates |
| title | Design of a smart sensor mesh for the measurement of pH in ostomy applications |
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