Modulation of morphological, optical and magnetic properties of Cr-doped La0.9Ce0.1FeO3 nanoferrites synthesized by surface-active ionic liquid aided hydrothermal route

The impact of doping of Cr ion on structural, magnetic and optical properties of La 0.9 Ce 0.1 Fe 1-x Cr x O 3 nanoferrites synthesized by surface-active ionic liquid (SAIL) aided hydrothermal route has been investigated. The presence of different oxidation state of Cr leads to appearance of seconda...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2021-02, Vol.127 (2), Article 141
Hauptverfasser: Arora, Komal, Shikha, Preet, Abdelbaky, Rasha Mohamed Kamal, Kang, Tejwant Singh
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container_title Applied physics. A, Materials science & processing
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creator Arora, Komal
Shikha, Preet
Abdelbaky, Rasha Mohamed Kamal
Kang, Tejwant Singh
description The impact of doping of Cr ion on structural, magnetic and optical properties of La 0.9 Ce 0.1 Fe 1-x Cr x O 3 nanoferrites synthesized by surface-active ionic liquid (SAIL) aided hydrothermal route has been investigated. The presence of different oxidation state of Cr leads to appearance of secondary phases in Cr-doped La 0.9 Ce 0.1 Fe 1-x Cr x O 3 samples as indicated by results obtained from XRD, FT-IR and Raman spectroscopy. Mӧssbauer spectroscopy and magnetic studies also revealed structural distortion and formation of mixed phases in Cr-doped samples. The random occupancy by Cr at Fe-site leads to decrease in magnetization. The use of SAILs for preparation of nanoferrites helped to achieve directional growth of nanoparticles as suggested by transmission electron microscopy (TEM). It is anticipated that present study would help to understand the role of Cr ion in modulating various physico-chemical properties of La 0.9 Ce 0.1 FeO 3 .
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A</stitle><date>2021-02-01</date><risdate>2021</risdate><volume>127</volume><issue>2</issue><artnum>141</artnum><issn>0947-8396</issn><eissn>1432-0630</eissn><abstract>The impact of doping of Cr ion on structural, magnetic and optical properties of La 0.9 Ce 0.1 Fe 1-x Cr x O 3 nanoferrites synthesized by surface-active ionic liquid (SAIL) aided hydrothermal route has been investigated. The presence of different oxidation state of Cr leads to appearance of secondary phases in Cr-doped La 0.9 Ce 0.1 Fe 1-x Cr x O 3 samples as indicated by results obtained from XRD, FT-IR and Raman spectroscopy. Mӧssbauer spectroscopy and magnetic studies also revealed structural distortion and formation of mixed phases in Cr-doped samples. The random occupancy by Cr at Fe-site leads to decrease in magnetization. The use of SAILs for preparation of nanoferrites helped to achieve directional growth of nanoparticles as suggested by transmission electron microscopy (TEM). 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subjects Applied physics
Characterization and Evaluation of Materials
Chemical properties
Chromium
Condensed Matter Physics
Infrared spectroscopy
Ionic liquids
Machines
Magnetic properties
Manufacturing
Materials science
Nanoparticles
Nanotechnology
Occupancy
Optical and Electronic Materials
Optical properties
Oxidation
Physics
Physics and Astronomy
Processes
Raman spectroscopy
Sails
Spectroscopic analysis
Spectrum analysis
Surfaces and Interfaces
Synthesis
Thin Films
Valence
title Modulation of morphological, optical and magnetic properties of Cr-doped La0.9Ce0.1FeO3 nanoferrites synthesized by surface-active ionic liquid aided hydrothermal route
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