Aqueous chemistry of ruthenium(II) complexes containing dimethylsulfoxide, and a chelated disulfoxide ligand or a cyclotetrathia ligand
[Display omitted] •X-ray and aqueous chemistry studies on Ru-sulfoxide/cyclotetrathia complexes.•Ru complexes X-ray structures.•Aqueous chemistry kinetics. The aqueous chemistry, including some kinetic studies, of our recently reported [RuII/IIICl(BPSP)]2(μ-Cl)3 (complex 1), where BPSP = 1,2-bis(pro...
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| Veröffentlicht in: | Inorganica Chimica Acta 2020-11, Vol.512, p.119866, Article 119866 |
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| creator | Cheu, Elizabeth L.S. Huxham, Lynsey A. Patrick, Brian O. Ezhova, Maria B. James, Brian R. |
| description | [Display omitted]
•X-ray and aqueous chemistry studies on Ru-sulfoxide/cyclotetrathia complexes.•Ru complexes X-ray structures.•Aqueous chemistry kinetics.
The aqueous chemistry, including some kinetic studies, of our recently reported [RuII/IIICl(BPSP)]2(μ-Cl)3 (complex 1), where BPSP = 1,2-bis(propylsulfinyl)ethane, and a new complex cis-RuCl2(DMSO)(DMSO)(BESE) (2), where BESE = 1,2-bis(ethylsulfinyl)ethane, is described; both 1 and 2 are fully characterized. Such data are of importance for in vitro studies on cytotoxicity, accumulation and DNA-binding properties in selected cells, findings that will be published elsewhere. Discussed also are the complexes [Ru(12-ane-S4)(DMSO)(H2O)][OTf]2 (3), where 12-ane-S4 = 1,4,7,10-tetrathiacyclododecane, and cis-RuCl2(DMSO)L (4), where L = 3,6,9,14 tetrathiabicyclo-[9.2.1]-tetradeca-11,13-diene. Complexes 3 and 4 were first made by our group, but have been synthesized and studied subsequently by other groups; differences in findings are discussed. |
| doi_str_mv | 10.1016/j.ica.2020.119866 |
| format | Article |
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•X-ray and aqueous chemistry studies on Ru-sulfoxide/cyclotetrathia complexes.•Ru complexes X-ray structures.•Aqueous chemistry kinetics.
The aqueous chemistry, including some kinetic studies, of our recently reported [RuII/IIICl(BPSP)]2(μ-Cl)3 (complex 1), where BPSP = 1,2-bis(propylsulfinyl)ethane, and a new complex cis-RuCl2(DMSO)(DMSO)(BESE) (2), where BESE = 1,2-bis(ethylsulfinyl)ethane, is described; both 1 and 2 are fully characterized. Such data are of importance for in vitro studies on cytotoxicity, accumulation and DNA-binding properties in selected cells, findings that will be published elsewhere. Discussed also are the complexes [Ru(12-ane-S4)(DMSO)(H2O)][OTf]2 (3), where 12-ane-S4 = 1,4,7,10-tetrathiacyclododecane, and cis-RuCl2(DMSO)L (4), where L = 3,6,9,14 tetrathiabicyclo-[9.2.1]-tetradeca-11,13-diene. Complexes 3 and 4 were first made by our group, but have been synthesized and studied subsequently by other groups; differences in findings are discussed.</description><identifier>ISSN: 0020-1693</identifier><identifier>EISSN: 1873-3255</identifier><identifier>DOI: 10.1016/j.ica.2020.119866</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Aqueous chemistry ; Ethane ; Ligands ; Ruthenium ; Ruthenium compounds ; Toxicity</subject><ispartof>Inorganica Chimica Acta, 2020-11, Vol.512, p.119866, Article 119866</ispartof><rights>2020</rights><rights>Copyright Elsevier Science Ltd. Nov 1, 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c277t-9dc405506459517d8d2dc3cece1a3526c0ac9dc7b9c842fed7a5bee87be8105d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.ica.2020.119866$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27923,27924,45994</link.rule.ids></links><search><creatorcontrib>Cheu, Elizabeth L.S.</creatorcontrib><creatorcontrib>Huxham, Lynsey A.</creatorcontrib><creatorcontrib>Patrick, Brian O.</creatorcontrib><creatorcontrib>Ezhova, Maria B.</creatorcontrib><creatorcontrib>James, Brian R.</creatorcontrib><title>Aqueous chemistry of ruthenium(II) complexes containing dimethylsulfoxide, and a chelated disulfoxide ligand or a cyclotetrathia ligand</title><title>Inorganica Chimica Acta</title><description>[Display omitted]
•X-ray and aqueous chemistry studies on Ru-sulfoxide/cyclotetrathia complexes.•Ru complexes X-ray structures.•Aqueous chemistry kinetics.
The aqueous chemistry, including some kinetic studies, of our recently reported [RuII/IIICl(BPSP)]2(μ-Cl)3 (complex 1), where BPSP = 1,2-bis(propylsulfinyl)ethane, and a new complex cis-RuCl2(DMSO)(DMSO)(BESE) (2), where BESE = 1,2-bis(ethylsulfinyl)ethane, is described; both 1 and 2 are fully characterized. Such data are of importance for in vitro studies on cytotoxicity, accumulation and DNA-binding properties in selected cells, findings that will be published elsewhere. Discussed also are the complexes [Ru(12-ane-S4)(DMSO)(H2O)][OTf]2 (3), where 12-ane-S4 = 1,4,7,10-tetrathiacyclododecane, and cis-RuCl2(DMSO)L (4), where L = 3,6,9,14 tetrathiabicyclo-[9.2.1]-tetradeca-11,13-diene. Complexes 3 and 4 were first made by our group, but have been synthesized and studied subsequently by other groups; differences in findings are discussed.</description><subject>Aqueous chemistry</subject><subject>Ethane</subject><subject>Ligands</subject><subject>Ruthenium</subject><subject>Ruthenium compounds</subject><subject>Toxicity</subject><issn>0020-1693</issn><issn>1873-3255</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKxDAUhoMoOI4-gLuCGwU7Jk3TC65k8DIw4EbXIZOcTjO0zZikMn0CX9uUDi5dHQ7_95_Lj9A1wQuCSfawW2gpFglOQk_KIstO0IwUOY1pwtgpmuGgxCQr6Tm6cG6HMcUZZTP08_TVg-ldJGtotfN2iEwV2d7X0Om-vV2t7iJp2n0DBwiQ6bzQne62kdIt-HpoXN9U5qAV3EeiU5EYBzXCgwrEnxY1ejuqxo7AIBvjwVvhay2O0iU6q0Tj4OpY5-jz5flj-Rav319Xy6d1LJM893GpZIoZw1nKSkZyVahESSpBAhGUJZnEQgYm35SySJMKVC7YBqDIN1AQzBSdo5tp7t6a8LnzfGd624WVPEnzsiApzdJAkYmS1jhnoeJ7q1thB04wH_PmOx7y5mPefMo7eB4nD4TzvzVY7qSGToLSFqTnyuh_3L9oTIt0</recordid><startdate>20201101</startdate><enddate>20201101</enddate><creator>Cheu, Elizabeth L.S.</creator><creator>Huxham, Lynsey A.</creator><creator>Patrick, Brian O.</creator><creator>Ezhova, Maria B.</creator><creator>James, Brian R.</creator><general>Elsevier B.V</general><general>Elsevier Science Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20201101</creationdate><title>Aqueous chemistry of ruthenium(II) complexes containing dimethylsulfoxide, and a chelated disulfoxide ligand or a cyclotetrathia ligand</title><author>Cheu, Elizabeth L.S. ; Huxham, Lynsey A. ; Patrick, Brian O. ; Ezhova, Maria B. ; James, Brian R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c277t-9dc405506459517d8d2dc3cece1a3526c0ac9dc7b9c842fed7a5bee87be8105d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aqueous chemistry</topic><topic>Ethane</topic><topic>Ligands</topic><topic>Ruthenium</topic><topic>Ruthenium compounds</topic><topic>Toxicity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cheu, Elizabeth L.S.</creatorcontrib><creatorcontrib>Huxham, Lynsey A.</creatorcontrib><creatorcontrib>Patrick, Brian O.</creatorcontrib><creatorcontrib>Ezhova, Maria B.</creatorcontrib><creatorcontrib>James, Brian R.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Inorganica Chimica Acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cheu, Elizabeth L.S.</au><au>Huxham, Lynsey A.</au><au>Patrick, Brian O.</au><au>Ezhova, Maria B.</au><au>James, Brian R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Aqueous chemistry of ruthenium(II) complexes containing dimethylsulfoxide, and a chelated disulfoxide ligand or a cyclotetrathia ligand</atitle><jtitle>Inorganica Chimica Acta</jtitle><date>2020-11-01</date><risdate>2020</risdate><volume>512</volume><spage>119866</spage><pages>119866-</pages><artnum>119866</artnum><issn>0020-1693</issn><eissn>1873-3255</eissn><abstract>[Display omitted]
•X-ray and aqueous chemistry studies on Ru-sulfoxide/cyclotetrathia complexes.•Ru complexes X-ray structures.•Aqueous chemistry kinetics.
The aqueous chemistry, including some kinetic studies, of our recently reported [RuII/IIICl(BPSP)]2(μ-Cl)3 (complex 1), where BPSP = 1,2-bis(propylsulfinyl)ethane, and a new complex cis-RuCl2(DMSO)(DMSO)(BESE) (2), where BESE = 1,2-bis(ethylsulfinyl)ethane, is described; both 1 and 2 are fully characterized. Such data are of importance for in vitro studies on cytotoxicity, accumulation and DNA-binding properties in selected cells, findings that will be published elsewhere. Discussed also are the complexes [Ru(12-ane-S4)(DMSO)(H2O)][OTf]2 (3), where 12-ane-S4 = 1,4,7,10-tetrathiacyclododecane, and cis-RuCl2(DMSO)L (4), where L = 3,6,9,14 tetrathiabicyclo-[9.2.1]-tetradeca-11,13-diene. Complexes 3 and 4 were first made by our group, but have been synthesized and studied subsequently by other groups; differences in findings are discussed.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.ica.2020.119866</doi></addata></record> |
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| subjects | Aqueous chemistry Ethane Ligands Ruthenium Ruthenium compounds Toxicity |
| title | Aqueous chemistry of ruthenium(II) complexes containing dimethylsulfoxide, and a chelated disulfoxide ligand or a cyclotetrathia ligand |
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