Unexpected Ring Opening During the Imination of Camphor‐Type Bicyclic Ketones

A new ring opening reaction was found while attempting to isolate the imines from ortho‐heteroatom substituted anilines and camphor‐like bicyclic ketones. The benzoazoles containing a cyclopentanemethyl group at position 2 of the heterocycle were isolated instead of the expected imines. The detailed...

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Veröffentlicht in:	European journal of organic chemistry 2021-01, Vol.2021 (3), p.452-463
Hauptverfasser:	Chernyshov, Vladimir V., Yarovaya, Olga I., Vatsadze, Sergey Z., Borisevich, Sophia S., Trukhan, Sergey N., Gatilov, Yuri V., Peshkov, Roman Yu, Eltsov, Ilia V., Martyanov, Oleg N., Salakhutdinov, Nariman F.
Format:	Artikel
Sprache:	eng
Schlagworte:	(−)-Fenchone Aniline Benzimidazoles Camphor Imines Ketones Monoterpenoids Quantum chemistry Ring opening Single-stage synthesis
Online-Zugang:	Volltext
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