Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes
Quaternary MAX phases, (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), have been synthesised via pressureless sintering of TaC, TiC, Ti and Al powders. Via chemical etching of the Al layers, (Ta0.38Ti0.62)3C2Tz – a new MXene, has also been synthesised. All materials contain an M-layer solid sol...
Gespeichert in:
| Veröffentlicht in: | RSC advances 2021-01, Vol.11 (5), p.3110-3114 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3114 |
|---|---|
| container_issue | 5 |
| container_start_page | 3110 |
| container_title | RSC advances |
| container_volume | 11 |
| creator | Rigby-Bell, Maxwell T P Natu, Varun Sokol, Maxim Kelly, Daniel J Hopkinson, David G Zou, Yichao Bird, James R T Evitts, Lee J Smith, Matt Race, Christopher P Frankel, Philipp Haigh, Sarah J Barsoum, Michel W |
| description | Quaternary MAX phases, (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), have been synthesised via pressureless sintering of TaC, TiC, Ti and Al powders. Via chemical etching of the Al layers, (Ta0.38Ti0.62)3C2Tz – a new MXene, has also been synthesised. All materials contain an M-layer solid solution of Ta and Ti, with a variable Ta concentration, paving the way for the synthesis of a range of alloyed (Ta,Ti)3C2Tz MXenes with tuneable compositions for a wide range of potential applications. |
| doi_str_mv | 10.1039/d0ra09761f |
| format | Article |
| fullrecord | <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_journals_2479641862</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2479641862</sourcerecordid><originalsourceid>FETCH-LOGICAL-p134f-77c55f61117c96d4429a80f95b489d11f68375b1001b51e7f68e37bd63d8013f3</originalsourceid><addsrcrecordid>eNotjctqAjEYhYdCoWLd9Al-6EbBsflznSy6EOkNlC5qwZ3MmKSOSDJNlOobdNFVH7FP0pH2LL7D2Zwvy66QjJAwfWNILIlWEt1Z1qGEy5wSqS-yXkob0kYKpBI72dfL0e_WNtUJggNvP2CWb8ujjZDCtjZ5y_2uDh4YUpiNF9Csy2QT9Ocl_nx-H-b1YcDG2wmF_gFugYz4sIWkJypxokYI8dRiMITSG2h1dYRViNGmJnhT-zeYLay36TI7d-U22d5_d7PX-7v55DGfPj88TcbTvEHGXa7USggnEVGttDScU10WxGlR8UIbRCcLpkSFhGAl0Kp2W6YqI5kpCDLHutn1328Tw_vept1yE_bRt8ol5UpLjoWk7Be-Klzu</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2479641862</pqid></control><display><type>article</type><title>Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes</title><source>DOAJ Directory of Open Access Journals</source><source>PubMed Central Open Access</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><creator>Rigby-Bell, Maxwell T P ; Natu, Varun ; Sokol, Maxim ; Kelly, Daniel J ; Hopkinson, David G ; Zou, Yichao ; Bird, James R T ; Evitts, Lee J ; Smith, Matt ; Race, Christopher P ; Frankel, Philipp ; Haigh, Sarah J ; Barsoum, Michel W</creator><creatorcontrib>Rigby-Bell, Maxwell T P ; Natu, Varun ; Sokol, Maxim ; Kelly, Daniel J ; Hopkinson, David G ; Zou, Yichao ; Bird, James R T ; Evitts, Lee J ; Smith, Matt ; Race, Christopher P ; Frankel, Philipp ; Haigh, Sarah J ; Barsoum, Michel W</creatorcontrib><description>Quaternary MAX phases, (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), have been synthesised via pressureless sintering of TaC, TiC, Ti and Al powders. Via chemical etching of the Al layers, (Ta0.38Ti0.62)3C2Tz – a new MXene, has also been synthesised. All materials contain an M-layer solid solution of Ta and Ti, with a variable Ta concentration, paving the way for the synthesis of a range of alloyed (Ta,Ti)3C2Tz MXenes with tuneable compositions for a wide range of potential applications.</description><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d0ra09761f</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Alloying ; Aluminum ; Chemical etching ; Crystallography ; Loose powder sintering ; MXenes ; Solid solutions ; Synthesis ; Titanium carbide</subject><ispartof>RSC advances, 2021-01, Vol.11 (5), p.3110-3114</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,27924,27925</link.rule.ids></links><search><creatorcontrib>Rigby-Bell, Maxwell T P</creatorcontrib><creatorcontrib>Natu, Varun</creatorcontrib><creatorcontrib>Sokol, Maxim</creatorcontrib><creatorcontrib>Kelly, Daniel J</creatorcontrib><creatorcontrib>Hopkinson, David G</creatorcontrib><creatorcontrib>Zou, Yichao</creatorcontrib><creatorcontrib>Bird, James R T</creatorcontrib><creatorcontrib>Evitts, Lee J</creatorcontrib><creatorcontrib>Smith, Matt</creatorcontrib><creatorcontrib>Race, Christopher P</creatorcontrib><creatorcontrib>Frankel, Philipp</creatorcontrib><creatorcontrib>Haigh, Sarah J</creatorcontrib><creatorcontrib>Barsoum, Michel W</creatorcontrib><title>Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes</title><title>RSC advances</title><description>Quaternary MAX phases, (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), have been synthesised via pressureless sintering of TaC, TiC, Ti and Al powders. Via chemical etching of the Al layers, (Ta0.38Ti0.62)3C2Tz – a new MXene, has also been synthesised. All materials contain an M-layer solid solution of Ta and Ti, with a variable Ta concentration, paving the way for the synthesis of a range of alloyed (Ta,Ti)3C2Tz MXenes with tuneable compositions for a wide range of potential applications.</description><subject>Alloying</subject><subject>Aluminum</subject><subject>Chemical etching</subject><subject>Crystallography</subject><subject>Loose powder sintering</subject><subject>MXenes</subject><subject>Solid solutions</subject><subject>Synthesis</subject><subject>Titanium carbide</subject><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNotjctqAjEYhYdCoWLd9Al-6EbBsflznSy6EOkNlC5qwZ3MmKSOSDJNlOobdNFVH7FP0pH2LL7D2Zwvy66QjJAwfWNILIlWEt1Z1qGEy5wSqS-yXkob0kYKpBI72dfL0e_WNtUJggNvP2CWb8ujjZDCtjZ5y_2uDh4YUpiNF9Csy2QT9Ocl_nx-H-b1YcDG2wmF_gFugYz4sIWkJypxokYI8dRiMITSG2h1dYRViNGmJnhT-zeYLay36TI7d-U22d5_d7PX-7v55DGfPj88TcbTvEHGXa7USggnEVGttDScU10WxGlR8UIbRCcLpkSFhGAl0Kp2W6YqI5kpCDLHutn1328Tw_vept1yE_bRt8ol5UpLjoWk7Be-Klzu</recordid><startdate>20210113</startdate><enddate>20210113</enddate><creator>Rigby-Bell, Maxwell T P</creator><creator>Natu, Varun</creator><creator>Sokol, Maxim</creator><creator>Kelly, Daniel J</creator><creator>Hopkinson, David G</creator><creator>Zou, Yichao</creator><creator>Bird, James R T</creator><creator>Evitts, Lee J</creator><creator>Smith, Matt</creator><creator>Race, Christopher P</creator><creator>Frankel, Philipp</creator><creator>Haigh, Sarah J</creator><creator>Barsoum, Michel W</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20210113</creationdate><title>Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes</title><author>Rigby-Bell, Maxwell T P ; Natu, Varun ; Sokol, Maxim ; Kelly, Daniel J ; Hopkinson, David G ; Zou, Yichao ; Bird, James R T ; Evitts, Lee J ; Smith, Matt ; Race, Christopher P ; Frankel, Philipp ; Haigh, Sarah J ; Barsoum, Michel W</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p134f-77c55f61117c96d4429a80f95b489d11f68375b1001b51e7f68e37bd63d8013f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Alloying</topic><topic>Aluminum</topic><topic>Chemical etching</topic><topic>Crystallography</topic><topic>Loose powder sintering</topic><topic>MXenes</topic><topic>Solid solutions</topic><topic>Synthesis</topic><topic>Titanium carbide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rigby-Bell, Maxwell T P</creatorcontrib><creatorcontrib>Natu, Varun</creatorcontrib><creatorcontrib>Sokol, Maxim</creatorcontrib><creatorcontrib>Kelly, Daniel J</creatorcontrib><creatorcontrib>Hopkinson, David G</creatorcontrib><creatorcontrib>Zou, Yichao</creatorcontrib><creatorcontrib>Bird, James R T</creatorcontrib><creatorcontrib>Evitts, Lee J</creatorcontrib><creatorcontrib>Smith, Matt</creatorcontrib><creatorcontrib>Race, Christopher P</creatorcontrib><creatorcontrib>Frankel, Philipp</creatorcontrib><creatorcontrib>Haigh, Sarah J</creatorcontrib><creatorcontrib>Barsoum, Michel W</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rigby-Bell, Maxwell T P</au><au>Natu, Varun</au><au>Sokol, Maxim</au><au>Kelly, Daniel J</au><au>Hopkinson, David G</au><au>Zou, Yichao</au><au>Bird, James R T</au><au>Evitts, Lee J</au><au>Smith, Matt</au><au>Race, Christopher P</au><au>Frankel, Philipp</au><au>Haigh, Sarah J</au><au>Barsoum, Michel W</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes</atitle><jtitle>RSC advances</jtitle><date>2021-01-13</date><risdate>2021</risdate><volume>11</volume><issue>5</issue><spage>3110</spage><epage>3114</epage><pages>3110-3114</pages><eissn>2046-2069</eissn><abstract>Quaternary MAX phases, (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), have been synthesised via pressureless sintering of TaC, TiC, Ti and Al powders. Via chemical etching of the Al layers, (Ta0.38Ti0.62)3C2Tz – a new MXene, has also been synthesised. All materials contain an M-layer solid solution of Ta and Ti, with a variable Ta concentration, paving the way for the synthesis of a range of alloyed (Ta,Ti)3C2Tz MXenes with tuneable compositions for a wide range of potential applications.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d0ra09761f</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 2046-2069 |
| ispartof | RSC advances, 2021-01, Vol.11 (5), p.3110-3114 |
| issn | 2046-2069 |
| language | eng |
| recordid | cdi_proquest_journals_2479641862 |
| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Alloying Aluminum Chemical etching Crystallography Loose powder sintering MXenes Solid solutions Synthesis Titanium carbide |
| title | Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T00%3A40%3A05IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20new%20M-layer%20solid-solution%20312%20MAX%20phases%20(Ta1%E2%88%92xTix)3AlC2%20(x%20=%200.4,%200.62,%200.75,%200.91%20or%200.95),%20and%20their%20corresponding%20MXenes&rft.jtitle=RSC%20advances&rft.au=Rigby-Bell,%20Maxwell%20T%20P&rft.date=2021-01-13&rft.volume=11&rft.issue=5&rft.spage=3110&rft.epage=3114&rft.pages=3110-3114&rft.eissn=2046-2069&rft_id=info:doi/10.1039/d0ra09761f&rft_dat=%3Cproquest%3E2479641862%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2479641862&rft_id=info:pmid/&rfr_iscdi=true |