Morphology characterization and chemical composition of United Arab Emirates date seeds and their potential for energy production

The seeds of a local date palm cultivar from the United Arab Emirates, Allig, were characterized in this study. Soxhlet, Folch, and CO2 supercritical extraction were employed to obtain oil from Allig date seed (DS) powder composed of 0.1–0.3 mm particles, yielding oil extraction yield percentages of...

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Veröffentlicht in:Energy (Oxford) 2020-12, Vol.213, p.118810, Article 118810
Hauptverfasser: Elnajjar, E., Al-Zuhair, S., Hasan, S., Almardeai, S., Al Omari, S.A.B., Hilal-Alnaqbi, A.
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container_start_page 118810
container_title Energy (Oxford)
container_volume 213
creator Elnajjar, E.
Al-Zuhair, S.
Hasan, S.
Almardeai, S.
Al Omari, S.A.B.
Hilal-Alnaqbi, A.
description The seeds of a local date palm cultivar from the United Arab Emirates, Allig, were characterized in this study. Soxhlet, Folch, and CO2 supercritical extraction were employed to obtain oil from Allig date seed (DS) powder composed of 0.1–0.3 mm particles, yielding oil extraction yield percentages of 10.2%, 9.5%, and 9.8%, respectively. The main fatty acid in the extracted oil was saturated stearic acid, comprising 47.9% of the total fatty acid content. After oil extraction, the total metal content in the DSs dropped from 3.2% to 2.8%, suggesting that some metals were extracted with the oil. On the other hand, the average heating value of the DSs increased from 28.55 ± 1.84 to 29.63 ± 1.28 MJ/kg after oil extraction. The average percentages of dehydration moisture, devitalization protein and carbohydrates, devitalization lipids, and solid decomposition in the DSs before oil extraction were 1–2%, 50–55%, 10–15%, and 30–35%, respectively, whereas those for the DSs after oil extraction were 20–25%, 35–30%, 0%, and 35–40%, respectively. As expected, the lipid content dropped after oil extraction. The heat of combustion and extracted oil results indicate that palm DSs, with their relatively high energy densities, have potential as a source of energy, among other notable organic products. •Allig date seed (DS) powder was analyzed before and after oil extraction.•The same heating values was observed for raw and after oil extraction DS.•Raw after oil extraction DS high heating values roughly 50% to Diesel fuel.•DS leftovers after oil extraction can be used in direct combustion or pyrolysis.•High contents of stearic acid (48%) and saturated fatty acid (71%) were observed.
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Soxhlet, Folch, and CO2 supercritical extraction were employed to obtain oil from Allig date seed (DS) powder composed of 0.1–0.3 mm particles, yielding oil extraction yield percentages of 10.2%, 9.5%, and 9.8%, respectively. The main fatty acid in the extracted oil was saturated stearic acid, comprising 47.9% of the total fatty acid content. After oil extraction, the total metal content in the DSs dropped from 3.2% to 2.8%, suggesting that some metals were extracted with the oil. On the other hand, the average heating value of the DSs increased from 28.55 ± 1.84 to 29.63 ± 1.28 MJ/kg after oil extraction. The average percentages of dehydration moisture, devitalization protein and carbohydrates, devitalization lipids, and solid decomposition in the DSs before oil extraction were 1–2%, 50–55%, 10–15%, and 30–35%, respectively, whereas those for the DSs after oil extraction were 20–25%, 35–30%, 0%, and 35–40%, respectively. As expected, the lipid content dropped after oil extraction. The heat of combustion and extracted oil results indicate that palm DSs, with their relatively high energy densities, have potential as a source of energy, among other notable organic products. •Allig date seed (DS) powder was analyzed before and after oil extraction.•The same heating values was observed for raw and after oil extraction DS.•Raw after oil extraction DS high heating values roughly 50% to Diesel fuel.•DS leftovers after oil extraction can be used in direct combustion or pyrolysis.•High contents of stearic acid (48%) and saturated fatty acid (71%) were observed.</description><identifier>ISSN: 0360-5442</identifier><identifier>EISSN: 1873-6785</identifier><identifier>DOI: 10.1016/j.energy.2020.118810</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Calorific value ; Carbohydrates ; Carbon dioxide ; Chemical composition ; Cultivars ; Date seeds ; Dehydration ; EDS ; Fatty acids ; Heat of combustion ; ICP-AES ; Lipids ; Metals ; Morphology ; Oil ; Oil extraction percentage yield ; Oils &amp; fats ; Seeds ; SEM ; Soxhlet ; Stearic acid ; Supercritical gas extraction ; TGA</subject><ispartof>Energy (Oxford), 2020-12, Vol.213, p.118810, Article 118810</ispartof><rights>2020 Elsevier Ltd</rights><rights>Copyright Elsevier BV Dec 15, 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c334t-6f7c675f9a9f7ea409fc09b93696043ca5cf82336f187a751e1f79c7e3ae54453</citedby><cites>FETCH-LOGICAL-c334t-6f7c675f9a9f7ea409fc09b93696043ca5cf82336f187a751e1f79c7e3ae54453</cites><orcidid>0000-0003-1365-0697</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.energy.2020.118810$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Elnajjar, E.</creatorcontrib><creatorcontrib>Al-Zuhair, S.</creatorcontrib><creatorcontrib>Hasan, S.</creatorcontrib><creatorcontrib>Almardeai, S.</creatorcontrib><creatorcontrib>Al Omari, S.A.B.</creatorcontrib><creatorcontrib>Hilal-Alnaqbi, A.</creatorcontrib><title>Morphology characterization and chemical composition of United Arab Emirates date seeds and their potential for energy production</title><title>Energy (Oxford)</title><description>The seeds of a local date palm cultivar from the United Arab Emirates, Allig, were characterized in this study. Soxhlet, Folch, and CO2 supercritical extraction were employed to obtain oil from Allig date seed (DS) powder composed of 0.1–0.3 mm particles, yielding oil extraction yield percentages of 10.2%, 9.5%, and 9.8%, respectively. The main fatty acid in the extracted oil was saturated stearic acid, comprising 47.9% of the total fatty acid content. After oil extraction, the total metal content in the DSs dropped from 3.2% to 2.8%, suggesting that some metals were extracted with the oil. On the other hand, the average heating value of the DSs increased from 28.55 ± 1.84 to 29.63 ± 1.28 MJ/kg after oil extraction. The average percentages of dehydration moisture, devitalization protein and carbohydrates, devitalization lipids, and solid decomposition in the DSs before oil extraction were 1–2%, 50–55%, 10–15%, and 30–35%, respectively, whereas those for the DSs after oil extraction were 20–25%, 35–30%, 0%, and 35–40%, respectively. As expected, the lipid content dropped after oil extraction. 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subjects Calorific value
Carbohydrates
Carbon dioxide
Chemical composition
Cultivars
Date seeds
Dehydration
EDS
Fatty acids
Heat of combustion
ICP-AES
Lipids
Metals
Morphology
Oil
Oil extraction percentage yield
Oils & fats
Seeds
SEM
Soxhlet
Stearic acid
Supercritical gas extraction
TGA
title Morphology characterization and chemical composition of United Arab Emirates date seeds and their potential for energy production
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