Isolation of hydrazine oxidation products via halogen bonding: C–I bond scission and crystal polymorphism

Reaction of methylhydrazine with 1,3- and 1,4-diiodotetrafluorobenzene produced cocrystals with the oxidation product sym -hexahydro-1,4-dimethyltetrazine. In contrast, reaction of 1,1-dimethylhydrazine with 1,2-, 1,3-, and 1,4-diiodotetrafluorobenzene, as well as 1,3,5-triiodotrifluorobenzene, yiel...

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Veröffentlicht in:	CrystEngComm 2021-01, Vol.23 (2), p.419-426
Hauptverfasser:	Peloquin, Andrew J., Kobra, Khadijatul, McMillen, Colin D., Iacono, Scott T., Pennington, William T.
Format:	Artikel
Sprache:	eng
Schlagworte:	Cleavage Crystallography Dimethylhydrazines Methylhydrazine Oxidation Polymorphism Stoichiometry
Online-Zugang:	Volltext
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