Nitrogen doped carbon nanotubes supported Co9S8 nanoparticles for lithium-ion batteries with excellent electrochemical performance

[Display omitted] •Synthesized (Co9S8@C-NCNTs) using polypyrrole (PPy) tubes and ZIF-67 as the precursors.•Co9S8 nanoparticles were coated by carbon layer and attached on the carbon tubes.•Co9S8@C-NCNTs exhibits excellent electrochemical performance as the material of LIBs. Nitrogen doped carbon nan...

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Veröffentlicht in:Materials letters 2021-01, Vol.282, p.128850, Article 128850
Hauptverfasser: Yan, Zhanheng, Jiang, Lanlan, Chen, Dongchu, Huo, Baoyu, Zhou, Haihui, Huang, Zhongyuan
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container_issue
container_start_page 128850
container_title Materials letters
container_volume 282
creator Yan, Zhanheng
Jiang, Lanlan
Chen, Dongchu
Huo, Baoyu
Zhou, Haihui
Huang, Zhongyuan
description [Display omitted] •Synthesized (Co9S8@C-NCNTs) using polypyrrole (PPy) tubes and ZIF-67 as the precursors.•Co9S8 nanoparticles were coated by carbon layer and attached on the carbon tubes.•Co9S8@C-NCNTs exhibits excellent electrochemical performance as the material of LIBs. Nitrogen doped carbon nanotubes supported Co9S8 nanoparticles (Co9S8@C-NCNTs) was successfully prepared by solid state sulfurization reaction. As a result, the capacity, rate performance and cycling stability of Co9S8@C-NCNTs are obviously enhanced when it is used as anode material for LIBs. Co9S8@C-NCNTs composite exhibits a reversible capacity of 727 mAh g−1 after 100 cycles at a current density of 0.5 A g−1 and excellent rate performance (589 mAh g−1 after 500 cycles at 2 A g−1). This work provides a succinct and effective approach to prepare high-performance LIBs anode materials using metal organic framework (MOF) as precursor.
doi_str_mv 10.1016/j.matlet.2020.128850
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Nitrogen doped carbon nanotubes supported Co9S8 nanoparticles (Co9S8@C-NCNTs) was successfully prepared by solid state sulfurization reaction. As a result, the capacity, rate performance and cycling stability of Co9S8@C-NCNTs are obviously enhanced when it is used as anode material for LIBs. Co9S8@C-NCNTs composite exhibits a reversible capacity of 727 mAh g−1 after 100 cycles at a current density of 0.5 A g−1 and excellent rate performance (589 mAh g−1 after 500 cycles at 2 A g−1). 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subjects Anode effect
Carbon nanotubes
Co9S8
Cobalt sulfide
Electrochemical analysis
Electrode materials
Energy storage and conversion
Lithium
Lithium-ion batteries
Materials science
Metal-organic frameworks
Nanoparticles
Rechargeable batteries
Sulfurization
title Nitrogen doped carbon nanotubes supported Co9S8 nanoparticles for lithium-ion batteries with excellent electrochemical performance
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