Optimization and Biodiesel Production from Prosopis Julifera Oil with High Free Fatty Acids
Prosopis julifera is a non-edible feedstock found in the arid and semi-arid regions was used for the production of biodiesel. Solvent extraction technique was used for oil extraction from Prosopis julifera .The present work mainly concentrates on the three step process of biodiesel production from P...
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description | Prosopis julifera is a non-edible feedstock found in the arid and semi-arid regions was used for the production of biodiesel. Solvent extraction technique was used for oil extraction from Prosopis julifera .The present work mainly concentrates on the three step process of biodiesel production from Prosopis julifera oil .The acid value of Prosopis julifera oil was reduced below 1% using acid catalyst 1% v/v H2SO4 followed by esterification process using alkaline catalyst (KOH).Transesterification reaction is found to be affected by the reaction variables namely methanol to oil molar ratio, amount of catalyst used, reaction time and reaction temperature. Gas chromatography was used to analyse the Fatty acid methyl esters. The methyl ester obtained from the previous step was refined to produce biodiesel. The fuel properties of Prosopis julifera methyl ester (PJME) such as viscosity, cetane number, flash point, acid value, etc were determined and compared according to the ASTM standards. The optimum reaction conditions of Methanol/oil molar ratio of 9:1v/v, reaction temperature of 550C, reaction time of 2 hrs and 0.75% w/v of KOH usage were determined. Response surface Methodology (RSM) technique was used to optimize the maximum yield of Prosopis julifera methyl ester. |
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Solvent extraction technique was used for oil extraction from Prosopis julifera .The present work mainly concentrates on the three step process of biodiesel production from Prosopis julifera oil .The acid value of Prosopis julifera oil was reduced below 1% using acid catalyst 1% v/v H2SO4 followed by esterification process using alkaline catalyst (KOH).Transesterification reaction is found to be affected by the reaction variables namely methanol to oil molar ratio, amount of catalyst used, reaction time and reaction temperature. Gas chromatography was used to analyse the Fatty acid methyl esters. The methyl ester obtained from the previous step was refined to produce biodiesel. The fuel properties of Prosopis julifera methyl ester (PJME) such as viscosity, cetane number, flash point, acid value, etc were determined and compared according to the ASTM standards. The optimum reaction conditions of Methanol/oil molar ratio of 9:1v/v, reaction temperature of 550C, reaction time of 2 hrs and 0.75% w/v of KOH usage were determined. Response surface Methodology (RSM) technique was used to optimize the maximum yield of Prosopis julifera methyl ester.</description><identifier>ISSN: 1735-3572</identifier><identifier>EISSN: 1735-3645</identifier><identifier>DOI: 10.29252/jafm.11.01.28336</identifier><language>eng</language><publisher>Isfahan: Isfahan University of Technology</publisher><subject>Arid regions ; Arid zones ; Biodiesel fuels ; Biofuels ; Catalysts ; Cetane number ; Diesel ; Esterification ; Esters ; Fatty acid methyl esters ; Fatty acids ; Flash point ; Gas chromatography ; Methanol ; Oils & fats ; Optimization ; Prosopis ; Prosopis julifera; Acid Esterification; Transesterification; Process optimization ; Reaction time ; Response surface methodology ; Semi arid areas ; Semiarid zones ; Solvent extraction ; Sulfuric acid ; Transesterification</subject><ispartof>Journal of Applied Fluid Mechanics, 2018-01, Vol.11 (1), p.257-270</ispartof><rights>2018. This work is published under http://creativecommons.org/licenses/by-nc-nd/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2976-aa97edfc60fa8811eb5d4fc9905a94531897430e8e72f52b41b6695f2279d9713</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,860,27901,27902</link.rule.ids></links><search><creatorcontrib>Rajeshwaran, M.</creatorcontrib><creatorcontrib>Ganeshan, P.</creatorcontrib><creatorcontrib>Raja, K.</creatorcontrib><creatorcontrib>Department of Mechanical Engineering, Anna University, University college of Engineering, Dindigul - 624005, Tamil Nadu, India</creatorcontrib><creatorcontrib>Department of Mechanical Engineering, VSB Engineering College, Karur - 639 111, Tamil Nadu, India</creatorcontrib><creatorcontrib>Department of Mechanical Engineering, Mohamed Sathak Engineering College, Ramanathapuram – 623 806, Tamil Nadu, India</creatorcontrib><title>Optimization and Biodiesel Production from Prosopis Julifera Oil with High Free Fatty Acids</title><title>Journal of Applied Fluid Mechanics</title><description>Prosopis julifera is a non-edible feedstock found in the arid and semi-arid regions was used for the production of biodiesel. Solvent extraction technique was used for oil extraction from Prosopis julifera .The present work mainly concentrates on the three step process of biodiesel production from Prosopis julifera oil .The acid value of Prosopis julifera oil was reduced below 1% using acid catalyst 1% v/v H2SO4 followed by esterification process using alkaline catalyst (KOH).Transesterification reaction is found to be affected by the reaction variables namely methanol to oil molar ratio, amount of catalyst used, reaction time and reaction temperature. Gas chromatography was used to analyse the Fatty acid methyl esters. The methyl ester obtained from the previous step was refined to produce biodiesel. The fuel properties of Prosopis julifera methyl ester (PJME) such as viscosity, cetane number, flash point, acid value, etc were determined and compared according to the ASTM standards. The optimum reaction conditions of Methanol/oil molar ratio of 9:1v/v, reaction temperature of 550C, reaction time of 2 hrs and 0.75% w/v of KOH usage were determined. Response surface Methodology (RSM) technique was used to optimize the maximum yield of Prosopis julifera methyl ester.</description><subject>Arid regions</subject><subject>Arid zones</subject><subject>Biodiesel fuels</subject><subject>Biofuels</subject><subject>Catalysts</subject><subject>Cetane number</subject><subject>Diesel</subject><subject>Esterification</subject><subject>Esters</subject><subject>Fatty acid methyl esters</subject><subject>Fatty acids</subject><subject>Flash point</subject><subject>Gas chromatography</subject><subject>Methanol</subject><subject>Oils & fats</subject><subject>Optimization</subject><subject>Prosopis</subject><subject>Prosopis julifera; Acid Esterification; Transesterification; Process optimization</subject><subject>Reaction time</subject><subject>Response surface methodology</subject><subject>Semi arid areas</subject><subject>Semiarid zones</subject><subject>Solvent extraction</subject><subject>Sulfuric acid</subject><subject>Transesterification</subject><issn>1735-3572</issn><issn>1735-3645</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><sourceid>DOA</sourceid><recordid>eNo9UctOAjEUnRhNJMgHuGviGuztYzpdIhHBkOBCVy6aTh9QMlBshxj9egdQV_d1cs7JPUVxC3hEJOHkfqP9dgQwwjAiFaXlRdEDQfmQloxf_vVckOtikHOoMWOCUSpkr3hf7tuwDd-6DXGH9M6ihxBtcNk16CVFezCng09xe5xz3IeMng9N8C5ptAwN-gztGs3Cao2myTk01W37hcYm2HxTXHndZDf4rf3ibfr4OpkNF8un-WS8GBoiRTnUWgpnvSmx11UF4GpumTdSYq4l4xQq2bnFrnKCeE5qBnVZSu4JEdJKAbRfzM-8NuqN2qew1elLRR3UaRHTSunUBtM4VdpaYkaqGmNgtISqIkwSqrnXFBvDOq67M9c-xY-Dy63axEPadfYVYUIQQSnQDgVnlOlekpPz_6qA1SkSdYxEASgM6hQJ_QHAmX2G</recordid><startdate>20180101</startdate><enddate>20180101</enddate><creator>Rajeshwaran, M.</creator><creator>Ganeshan, P.</creator><creator>Raja, K.</creator><general>Isfahan University of Technology</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7TB</scope><scope>7U5</scope><scope>7UA</scope><scope>8FD</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>H8D</scope><scope>KR7</scope><scope>L7M</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>DOA</scope></search><sort><creationdate>20180101</creationdate><title>Optimization and Biodiesel Production from Prosopis Julifera Oil with High Free Fatty Acids</title><author>Rajeshwaran, M. ; Ganeshan, P. ; Raja, K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2976-aa97edfc60fa8811eb5d4fc9905a94531897430e8e72f52b41b6695f2279d9713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Arid regions</topic><topic>Arid zones</topic><topic>Biodiesel fuels</topic><topic>Biofuels</topic><topic>Catalysts</topic><topic>Cetane number</topic><topic>Diesel</topic><topic>Esterification</topic><topic>Esters</topic><topic>Fatty acid methyl esters</topic><topic>Fatty acids</topic><topic>Flash point</topic><topic>Gas chromatography</topic><topic>Methanol</topic><topic>Oils & fats</topic><topic>Optimization</topic><topic>Prosopis</topic><topic>Prosopis julifera; Acid Esterification; Transesterification; Process optimization</topic><topic>Reaction time</topic><topic>Response surface methodology</topic><topic>Semi arid areas</topic><topic>Semiarid zones</topic><topic>Solvent extraction</topic><topic>Sulfuric acid</topic><topic>Transesterification</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rajeshwaran, M.</creatorcontrib><creatorcontrib>Ganeshan, P.</creatorcontrib><creatorcontrib>Raja, K.</creatorcontrib><creatorcontrib>Department of Mechanical Engineering, Anna University, University college of Engineering, Dindigul - 624005, Tamil Nadu, India</creatorcontrib><creatorcontrib>Department of Mechanical Engineering, VSB Engineering College, Karur - 639 111, Tamil Nadu, India</creatorcontrib><creatorcontrib>Department of Mechanical Engineering, Mohamed Sathak Engineering College, Ramanathapuram – 623 806, Tamil Nadu, India</creatorcontrib><collection>CrossRef</collection><collection>Aqualine</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Journal of Applied Fluid Mechanics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rajeshwaran, M.</au><au>Ganeshan, P.</au><au>Raja, K.</au><aucorp>Department of Mechanical Engineering, Anna University, University college of Engineering, Dindigul - 624005, Tamil Nadu, India</aucorp><aucorp>Department of Mechanical Engineering, VSB Engineering College, Karur - 639 111, Tamil Nadu, India</aucorp><aucorp>Department of Mechanical Engineering, Mohamed Sathak Engineering College, Ramanathapuram – 623 806, Tamil Nadu, India</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Optimization and Biodiesel Production from Prosopis Julifera Oil with High Free Fatty Acids</atitle><jtitle>Journal of Applied Fluid Mechanics</jtitle><date>2018-01-01</date><risdate>2018</risdate><volume>11</volume><issue>1</issue><spage>257</spage><epage>270</epage><pages>257-270</pages><issn>1735-3572</issn><eissn>1735-3645</eissn><abstract>Prosopis julifera is a non-edible feedstock found in the arid and semi-arid regions was used for the production of biodiesel. Solvent extraction technique was used for oil extraction from Prosopis julifera .The present work mainly concentrates on the three step process of biodiesel production from Prosopis julifera oil .The acid value of Prosopis julifera oil was reduced below 1% using acid catalyst 1% v/v H2SO4 followed by esterification process using alkaline catalyst (KOH).Transesterification reaction is found to be affected by the reaction variables namely methanol to oil molar ratio, amount of catalyst used, reaction time and reaction temperature. Gas chromatography was used to analyse the Fatty acid methyl esters. The methyl ester obtained from the previous step was refined to produce biodiesel. The fuel properties of Prosopis julifera methyl ester (PJME) such as viscosity, cetane number, flash point, acid value, etc were determined and compared according to the ASTM standards. The optimum reaction conditions of Methanol/oil molar ratio of 9:1v/v, reaction temperature of 550C, reaction time of 2 hrs and 0.75% w/v of KOH usage were determined. Response surface Methodology (RSM) technique was used to optimize the maximum yield of Prosopis julifera methyl ester.</abstract><cop>Isfahan</cop><pub>Isfahan University of Technology</pub><doi>10.29252/jafm.11.01.28336</doi><tpages>14</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Arid regions Arid zones Biodiesel fuels Biofuels Catalysts Cetane number Diesel Esterification Esters Fatty acid methyl esters Fatty acids Flash point Gas chromatography Methanol Oils & fats Optimization Prosopis Prosopis julifera Acid Esterification Transesterification Process optimization Reaction time Response surface methodology Semi arid areas Semiarid zones Solvent extraction Sulfuric acid Transesterification |
title | Optimization and Biodiesel Production from Prosopis Julifera Oil with High Free Fatty Acids |
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