$Entropic-Based Separation of Diastereomers: Size-Exclusion Chromatography with Online Viscometry and Refractometry Detection for Analysis of Blends of Mannose and Galactose Methyl-α-pyranosides at “Ideal” Size-Exclusion Conditions$

Entropic-Based Separation of Diastereomers: Size-Exclusion Chromatography with Online Viscometry and Refractometry Detection for Analysis of Blends of Mannose and Galactose Methyl-α-pyranosides at “Ideal” Size-Exclusion Conditions

The separation of carbohydrate diastereomers by an ideal size-exclusion mechanism, i.e., in the absence of enthalpic contributions to the separation, can be considered one of the grand challenges in chromatography: Can a difference in the location of a single axial hydroxy group on a pyranose ring (...

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Veröffentlicht in:	Chromatographia 2021, Vol.84 (1), p.37-45
Hauptverfasser:	Striegel, André M., Trainoff, Steven P.
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical Chemistry Aqueous solutions Carbohydrates Carbon Chemistry Chemistry and Materials Science Chromatography Entropy of solution Galactose Laboratory Medicine Mannose Monosaccharides Original Pharmacy Proteomics Separation Size exclusion chromatography Sugar Viscometers Viscometry
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