The mechanism studies of catalytic chemoselective conjugate addition of amino alcohols to α,β-unsaturated ester

The competing mechanisms of silver-/aminolithium-catalyzed hydrofunctionalization of α , β -unsaturated ester with an amino alcohol have been systematically studied with the DFT methods. Here, the acidity of a weaker nucleophile OH group of an amino alcohol is significantly higher than that of NH 2...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Theoretical chemistry accounts 2021, Vol.140 (1), Article 6
Hauptverfasser:	Han, Peilin, Han, Huijuan, Zhang, Xiaowei, Hou, Xiaoxiao, Wang, Hui, Liu, Chunhui
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Amines Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Esters Inorganic Chemistry Lewis acid Organic Chemistry Physical Chemistry Regular Article Silver Theoretical and Computational Chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!