Modulation of superhydrophobicity and self-binding strength of cellulose ester-based coating by changing the degree of substitution
Bio-based superhydrophobic coatings have attracted great attention owing to their environmental friendliness and potential applications. Among them, cellulose ester-based coatings show excellent superhydrophobicity. Even so, their rational design and performance modulation have been rarely concerned...
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| Veröffentlicht in: | Journal of materials science 2021-03, Vol.56 (9), p.5924-5935 |
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| creator | Li, Wei Zhang, Song Wang, Wei Zeng, Lintao Wang, Shuangfei Qin, Chengrong Qin, Caiqin |
| description | Bio-based superhydrophobic coatings have attracted great attention owing to their environmental friendliness and potential applications. Among them, cellulose ester-based coatings show excellent superhydrophobicity. Even so, their rational design and performance modulation have been rarely concerned, which is of great importance to their practical applications. Herein, we adjusted the superhydrophobicity and self-binding strength of α-cellulose 10-undecenoyl ester (CUE) coatings (used as a model) by changing the degree of substitution (DS) value. The DS-induced particle size of the CUE played a key role in the cluster formation for the superhydrophobicity and the generation of contact area for the binding force. The CUE size displayed a normal distribution with the increase in DS value, and a low coating amount as well as a high contact area could be realized from a large particle size. The optimum DS value of the CUE coating was 0.44–0.94. This research may provide a new perspective for the design of stable bio-based superhydrophobic coatings.
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| doi_str_mv | 10.1007/s10853-020-05677-1 |
| format | Article |
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Graphical abstract</description><subject>Analysis</subject><subject>Binding</subject><subject>Cellulose</subject><subject>Cellulose esters</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Coatings</subject><subject>Crystallography and Scattering Methods</subject><subject>Hydrophobic surfaces</subject><subject>Hydrophobicity</subject><subject>Materials Science</subject><subject>Modulation</subject><subject>Normal distribution</subject><subject>Particle size</subject><subject>Polymer Sciences</subject><subject>Polymers & Biopolymers</subject><subject>Solid Mechanics</subject><subject>Substitutes</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kUFrFTEQxxex4LP6BTwtePKQOkl2k7fHUrQWKkKt55BNJrsp2-SZZMF37hc3zxWkF8khYfj9Zib8m-YdhQsKID9mCvueE2BAoBdSEvqi2dFectLtgb9sdgCMEdYJ-qp5nfMDAPSS0V3z9DXaddHFx9BG1-b1gGk-2hQPcxy98eXY6mDbjIsjow_Wh6nNJWGYynwSDC7LusSMLeaCiYw6o21NrB0rOR5bM-swnd5lxtbilBC3QWMuvqynwW-aM6eXjG__3ufNj8-f7q--kNtv1zdXl7fE8IEVokfBgTM5DABUGD1qyqjcG2G5GyS1VA5MmPpFZkHzAUanqRXOacft4Bzn5837re8hxZ9r3Vc9xDWFOlKxTgrWU-hEpS42atILKh9cLEmbeiw-ehMDOl_rl6IHMfAO9lX48EyoTMFfZdJrzurm-91zlm2sSTHnhE4dkn_U6agoqFOSaktS1STVnyQVrRLfpFzhMGH6t_d_rN_luKJ5</recordid><startdate>20210301</startdate><enddate>20210301</enddate><creator>Li, Wei</creator><creator>Zhang, Song</creator><creator>Wang, Wei</creator><creator>Zeng, Lintao</creator><creator>Wang, Shuangfei</creator><creator>Qin, Chengrong</creator><creator>Qin, Caiqin</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-9224-4090</orcidid><orcidid>https://orcid.org/0000-0002-4186-2622</orcidid></search><sort><creationdate>20210301</creationdate><title>Modulation of superhydrophobicity and self-binding strength of cellulose ester-based coating by changing the degree of substitution</title><author>Li, Wei ; Zhang, Song ; Wang, Wei ; Zeng, Lintao ; Wang, Shuangfei ; Qin, Chengrong ; Qin, Caiqin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c392t-ab630327990016caba12178c6d3f971d17926c4612d0a390bfa1d6ffaf3d9ff33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Analysis</topic><topic>Binding</topic><topic>Cellulose</topic><topic>Cellulose esters</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Coatings</topic><topic>Crystallography and Scattering Methods</topic><topic>Hydrophobic surfaces</topic><topic>Hydrophobicity</topic><topic>Materials Science</topic><topic>Modulation</topic><topic>Normal distribution</topic><topic>Particle size</topic><topic>Polymer Sciences</topic><topic>Polymers & Biopolymers</topic><topic>Solid Mechanics</topic><topic>Substitutes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Wei</creatorcontrib><creatorcontrib>Zhang, Song</creatorcontrib><creatorcontrib>Wang, Wei</creatorcontrib><creatorcontrib>Zeng, Lintao</creatorcontrib><creatorcontrib>Wang, Shuangfei</creatorcontrib><creatorcontrib>Qin, Chengrong</creatorcontrib><creatorcontrib>Qin, Caiqin</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Wei</au><au>Zhang, Song</au><au>Wang, Wei</au><au>Zeng, Lintao</au><au>Wang, Shuangfei</au><au>Qin, Chengrong</au><au>Qin, Caiqin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Modulation of superhydrophobicity and self-binding strength of cellulose ester-based coating by changing the degree of substitution</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2021-03-01</date><risdate>2021</risdate><volume>56</volume><issue>9</issue><spage>5924</spage><epage>5935</epage><pages>5924-5935</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Bio-based superhydrophobic coatings have attracted great attention owing to their environmental friendliness and potential applications. Among them, cellulose ester-based coatings show excellent superhydrophobicity. Even so, their rational design and performance modulation have been rarely concerned, which is of great importance to their practical applications. Herein, we adjusted the superhydrophobicity and self-binding strength of α-cellulose 10-undecenoyl ester (CUE) coatings (used as a model) by changing the degree of substitution (DS) value. The DS-induced particle size of the CUE played a key role in the cluster formation for the superhydrophobicity and the generation of contact area for the binding force. The CUE size displayed a normal distribution with the increase in DS value, and a low coating amount as well as a high contact area could be realized from a large particle size. The optimum DS value of the CUE coating was 0.44–0.94. This research may provide a new perspective for the design of stable bio-based superhydrophobic coatings.
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| subjects | Analysis Binding Cellulose Cellulose esters Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Coatings Crystallography and Scattering Methods Hydrophobic surfaces Hydrophobicity Materials Science Modulation Normal distribution Particle size Polymer Sciences Polymers & Biopolymers Solid Mechanics Substitutes |
| title | Modulation of superhydrophobicity and self-binding strength of cellulose ester-based coating by changing the degree of substitution |
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