Structure-direction towards the new large pore zeolite NUD-3
The new zeolite NUD-3 possesses a three-dimensional system of large pore channels that is topologically identical to those of ITQ-21 and PKU-14. However, the three zeolites have distinctly different frameworks: a particular single 4-membered ring inside the denser portion of the zeolite is missing i...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-01, Vol.57 (2), p.191-194 |
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| creator | Chen, Fei-Jian Gao, Zihao Rei Li, Jian Gómez-Hortigüela, Luis Lin, Cong Xu, Le Du, Hong-Bin Márquez-Álvarez, Carlos Sun, Junliang Camblor, Miguel A |
| description | The new zeolite NUD-3 possesses a three-dimensional system of large pore channels that is topologically identical to those of ITQ-21 and PKU-14. However, the three zeolites have distinctly different frameworks: a particular single 4-membered ring inside the denser portion of the zeolite is missing in PKU-14, disordered in ITQ-21 and fully ordered in NUD-3. We document these differences and use molecular simulations to unravel the mechanism by which a particular structure directing agent dication, 1,1′-(1,2-phenylenebis(methylene))bis(3-methylimidazolium), is able to orient this inner ring.
A subtle structure-direction allows the crystallization of the ordered and fully connected zeolite NUD-3 instead of disordered or interrupted versions. |
| doi_str_mv | 10.1039/d0cc07333d |
| format | Article |
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A subtle structure-direction allows the crystallization of the ordered and fully connected zeolite NUD-3 instead of disordered or interrupted versions.</description><subject>Crystallography</subject><subject>Zeolites</subject><issn>1359-7345</issn><issn>1364-548X</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>D8T</sourceid><recordid>eNpd0c9LwzAUB_AgipvTi3el4EXEatI0TQtexuovGHrQibeQJq-z0i0zaRn615vZOcFcEsiHx3vvi9AhwRcE0-xSY6Uwp5TqLdQnNIlDFqev26s3y0JOY9ZDe869Y38IS3dRj9IoYzRO-ujqqbGtaloLoa4sqKYy86AxS2m1C5o3COawDGpppxAsjIXgC0xdNRA8TPKQ7qOdUtYODtb3AE1urp9Hd-H48fZ-NByHKia4CYnK4rIoIx0RzihWHDguaCF1GqVcKg2ccxWXDFiZyUIxPwLDaQqZxECwJnSAzru6bgmLthALW82k_RRGViKvXobC2KlwrSAZ4RH2_LTjC2s-WnCNmFVOQV3LOZjWiShO0iRJGI08PflH301r534YrzhLk4xh6tVZp5Q1zlkoNx0QLFYRiByPRj8R5B4fr0u2xQz0hv7u3IOjDlinNr9_GdJvsdiJOw</recordid><startdate>20210107</startdate><enddate>20210107</enddate><creator>Chen, Fei-Jian</creator><creator>Gao, Zihao Rei</creator><creator>Li, Jian</creator><creator>Gómez-Hortigüela, Luis</creator><creator>Lin, Cong</creator><creator>Xu, Le</creator><creator>Du, Hong-Bin</creator><creator>Márquez-Álvarez, Carlos</creator><creator>Sun, Junliang</creator><creator>Camblor, Miguel A</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><scope>ABAVF</scope><scope>ADTPV</scope><scope>AOWAS</scope><scope>D8T</scope><scope>DG7</scope><scope>ZZAVC</scope><orcidid>https://orcid.org/0000-0001-9591-3432</orcidid><orcidid>https://orcid.org/0000-0003-4074-0962</orcidid><orcidid>https://orcid.org/0000-0003-0331-3515</orcidid><orcidid>https://orcid.org/0000-0001-9345-9459</orcidid><orcidid>https://orcid.org/0000-0003-0021-5055</orcidid><orcidid>https://orcid.org/0000-0003-2749-4269</orcidid><orcidid>https://orcid.org/0000-0002-5293-2323</orcidid><orcidid>https://orcid.org/0000-0003-2221-2285</orcidid><orcidid>https://orcid.org/0000-0002-4960-8709</orcidid><orcidid>https://orcid.org/0000-0002-9727-7713</orcidid></search><sort><creationdate>20210107</creationdate><title>Structure-direction towards the new large pore zeolite NUD-3</title><author>Chen, Fei-Jian ; Gao, Zihao Rei ; Li, Jian ; Gómez-Hortigüela, Luis ; Lin, Cong ; Xu, Le ; Du, Hong-Bin ; Márquez-Álvarez, Carlos ; Sun, Junliang ; Camblor, Miguel A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c410t-1c94fbf2d217530c7e70b3bad8287acde777c4f5e5f9abc51365088e9a0e10d13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Crystallography</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Fei-Jian</creatorcontrib><creatorcontrib>Gao, Zihao Rei</creatorcontrib><creatorcontrib>Li, Jian</creatorcontrib><creatorcontrib>Gómez-Hortigüela, Luis</creatorcontrib><creatorcontrib>Lin, Cong</creatorcontrib><creatorcontrib>Xu, Le</creatorcontrib><creatorcontrib>Du, Hong-Bin</creatorcontrib><creatorcontrib>Márquez-Álvarez, Carlos</creatorcontrib><creatorcontrib>Sun, Junliang</creatorcontrib><creatorcontrib>Camblor, Miguel A</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><collection>SWEPUB Stockholms universitet full text</collection><collection>SwePub</collection><collection>SwePub Articles</collection><collection>SWEPUB Freely available online</collection><collection>SWEPUB Stockholms universitet</collection><collection>SwePub Articles full text</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Fei-Jian</au><au>Gao, Zihao Rei</au><au>Li, Jian</au><au>Gómez-Hortigüela, Luis</au><au>Lin, Cong</au><au>Xu, Le</au><au>Du, Hong-Bin</au><au>Márquez-Álvarez, Carlos</au><au>Sun, Junliang</au><au>Camblor, Miguel A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure-direction towards the new large pore zeolite NUD-3</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2021-01-07</date><risdate>2021</risdate><volume>57</volume><issue>2</issue><spage>191</spage><epage>194</epage><pages>191-194</pages><issn>1359-7345</issn><issn>1364-548X</issn><eissn>1364-548X</eissn><abstract>The new zeolite NUD-3 possesses a three-dimensional system of large pore channels that is topologically identical to those of ITQ-21 and PKU-14. However, the three zeolites have distinctly different frameworks: a particular single 4-membered ring inside the denser portion of the zeolite is missing in PKU-14, disordered in ITQ-21 and fully ordered in NUD-3. We document these differences and use molecular simulations to unravel the mechanism by which a particular structure directing agent dication, 1,1′-(1,2-phenylenebis(methylene))bis(3-methylimidazolium), is able to orient this inner ring.
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| subjects | Crystallography Zeolites |
| title | Structure-direction towards the new large pore zeolite NUD-3 |
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