Miscibility, morphology, and properties of poly(butylene succinate)/poly(vinyl acetate) blends
Poly(butylene succinate) (PBS)/poly(vinyl acetate) (PVAc) blends were prepared by melt mixing. The miscibility, morphology, non-isothermal and isothermal crystallization, and rheological and mechanical properties of PBS/PVAc blends were investigated. The blends were a partial miscible two-phase syst...
Gespeichert in:
| Veröffentlicht in: | Colloid and polymer science 2021, Vol.299 (1), p.105-116 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 116 |
|---|---|
| container_issue | 1 |
| container_start_page | 105 |
| container_title | Colloid and polymer science |
| container_volume | 299 |
| creator | Li, Yi Han, Changyu Xiao, Liguang Yu, Yancun Zhou, Guangbin Xu, Mingzhi |
| description | Poly(butylene succinate) (PBS)/poly(vinyl acetate) (PVAc) blends were prepared by melt mixing. The miscibility, morphology, non-isothermal and isothermal crystallization, and rheological and mechanical properties of PBS/PVAc blends were investigated. The blends were a partial miscible two-phase system with PVAc evenly dispersed in the PBS matrix. The incorporation of PVAc accelerated the crystallization rate of PBS due to the heterogeneous nucleation, but decreased the degree of crystallinity. The rheological properties of PBS were greatly improved by the incorporation of PVAc, because of the high viscosity of PVAc in melt state. The most intriguing result was that the stiffness, strength, and toughness could be improved simultaneously by the addition of PVAc. The modulus, breaking strength, and elongation at break of PBS containing 10 wt% PVAc increased by 3.5%, 15.7%, and 43.4%, respectively. The synergetic improvement in the crystallization, rheological, and mechanical properties may be of much importance for widening the application of PBS. |
| doi_str_mv | 10.1007/s00396-020-04773-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2475201563</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2475201563</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-a3568a11d92ddc2370c5b628ecc1c9384a96e4e5b5cbc9c8523c1d8e20afea273</originalsourceid><addsrcrecordid>eNp9kE1LxDAQhoMouK7-AU8FLwrGnSRN2h5l8QtWvCh4MqRpumbpNjVphf57s1vBm5eZYeadd4YHoXMCNwQgWwQAVggMFDCkWcZwdoBmJGUcE87EIZoBA4ZToO_H6CSEDQCkhRAz9PFsg7albWw_Xidb57tP17h1rFVbJZ13nfG9NSFxddK5Zrwsh35sTGuSMGhtW9Wbq8V-8G3bsUmUNv2ul5RRVIVTdFSrJpiz3zxHb_d3r8tHvHp5eFrerrBmXPRYxZgrQqqCVpWmLAPNS0FzozXRBctTVQiTGl5yXepC55wyTarcUFC1UTRjc3Qx-caPvwYTerlxg2_jSUnTjFMgXLCoopNKexeCN7XsvN0qP0oCcsdRThxl5Cj3HOXOmk1LIYrbtfF_1v9s_QCE53cg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2475201563</pqid></control><display><type>article</type><title>Miscibility, morphology, and properties of poly(butylene succinate)/poly(vinyl acetate) blends</title><source>SpringerLink Journals - AutoHoldings</source><creator>Li, Yi ; Han, Changyu ; Xiao, Liguang ; Yu, Yancun ; Zhou, Guangbin ; Xu, Mingzhi</creator><creatorcontrib>Li, Yi ; Han, Changyu ; Xiao, Liguang ; Yu, Yancun ; Zhou, Guangbin ; Xu, Mingzhi</creatorcontrib><description>Poly(butylene succinate) (PBS)/poly(vinyl acetate) (PVAc) blends were prepared by melt mixing. The miscibility, morphology, non-isothermal and isothermal crystallization, and rheological and mechanical properties of PBS/PVAc blends were investigated. The blends were a partial miscible two-phase system with PVAc evenly dispersed in the PBS matrix. The incorporation of PVAc accelerated the crystallization rate of PBS due to the heterogeneous nucleation, but decreased the degree of crystallinity. The rheological properties of PBS were greatly improved by the incorporation of PVAc, because of the high viscosity of PVAc in melt state. The most intriguing result was that the stiffness, strength, and toughness could be improved simultaneously by the addition of PVAc. The modulus, breaking strength, and elongation at break of PBS containing 10 wt% PVAc increased by 3.5%, 15.7%, and 43.4%, respectively. The synergetic improvement in the crystallization, rheological, and mechanical properties may be of much importance for widening the application of PBS.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-020-04773-7</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Binary systems ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Crystallization ; Degree of crystallinity ; Elongation ; Food Science ; Mechanical properties ; Miscibility ; Morphology ; Nanotechnology and Microengineering ; Nucleation ; Original Contribution ; Physical Chemistry ; Polymer blends ; Polymer Sciences ; Polyvinyl acetates ; Rheological properties ; Rheology ; Soft and Granular Matter ; Stiffness ; Vinyl acetate</subject><ispartof>Colloid and polymer science, 2021, Vol.299 (1), p.105-116</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-a3568a11d92ddc2370c5b628ecc1c9384a96e4e5b5cbc9c8523c1d8e20afea273</citedby><cites>FETCH-LOGICAL-c356t-a3568a11d92ddc2370c5b628ecc1c9384a96e4e5b5cbc9c8523c1d8e20afea273</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-020-04773-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-020-04773-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Li, Yi</creatorcontrib><creatorcontrib>Han, Changyu</creatorcontrib><creatorcontrib>Xiao, Liguang</creatorcontrib><creatorcontrib>Yu, Yancun</creatorcontrib><creatorcontrib>Zhou, Guangbin</creatorcontrib><creatorcontrib>Xu, Mingzhi</creatorcontrib><title>Miscibility, morphology, and properties of poly(butylene succinate)/poly(vinyl acetate) blends</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>Poly(butylene succinate) (PBS)/poly(vinyl acetate) (PVAc) blends were prepared by melt mixing. The miscibility, morphology, non-isothermal and isothermal crystallization, and rheological and mechanical properties of PBS/PVAc blends were investigated. The blends were a partial miscible two-phase system with PVAc evenly dispersed in the PBS matrix. The incorporation of PVAc accelerated the crystallization rate of PBS due to the heterogeneous nucleation, but decreased the degree of crystallinity. The rheological properties of PBS were greatly improved by the incorporation of PVAc, because of the high viscosity of PVAc in melt state. The most intriguing result was that the stiffness, strength, and toughness could be improved simultaneously by the addition of PVAc. The modulus, breaking strength, and elongation at break of PBS containing 10 wt% PVAc increased by 3.5%, 15.7%, and 43.4%, respectively. The synergetic improvement in the crystallization, rheological, and mechanical properties may be of much importance for widening the application of PBS.</description><subject>Binary systems</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Crystallization</subject><subject>Degree of crystallinity</subject><subject>Elongation</subject><subject>Food Science</subject><subject>Mechanical properties</subject><subject>Miscibility</subject><subject>Morphology</subject><subject>Nanotechnology and Microengineering</subject><subject>Nucleation</subject><subject>Original Contribution</subject><subject>Physical Chemistry</subject><subject>Polymer blends</subject><subject>Polymer Sciences</subject><subject>Polyvinyl acetates</subject><subject>Rheological properties</subject><subject>Rheology</subject><subject>Soft and Granular Matter</subject><subject>Stiffness</subject><subject>Vinyl acetate</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1LxDAQhoMouK7-AU8FLwrGnSRN2h5l8QtWvCh4MqRpumbpNjVphf57s1vBm5eZYeadd4YHoXMCNwQgWwQAVggMFDCkWcZwdoBmJGUcE87EIZoBA4ZToO_H6CSEDQCkhRAz9PFsg7albWw_Xidb57tP17h1rFVbJZ13nfG9NSFxddK5Zrwsh35sTGuSMGhtW9Wbq8V-8G3bsUmUNv2ul5RRVIVTdFSrJpiz3zxHb_d3r8tHvHp5eFrerrBmXPRYxZgrQqqCVpWmLAPNS0FzozXRBctTVQiTGl5yXepC55wyTarcUFC1UTRjc3Qx-caPvwYTerlxg2_jSUnTjFMgXLCoopNKexeCN7XsvN0qP0oCcsdRThxl5Cj3HOXOmk1LIYrbtfF_1v9s_QCE53cg</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Li, Yi</creator><creator>Han, Changyu</creator><creator>Xiao, Liguang</creator><creator>Yu, Yancun</creator><creator>Zhou, Guangbin</creator><creator>Xu, Mingzhi</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>2021</creationdate><title>Miscibility, morphology, and properties of poly(butylene succinate)/poly(vinyl acetate) blends</title><author>Li, Yi ; Han, Changyu ; Xiao, Liguang ; Yu, Yancun ; Zhou, Guangbin ; Xu, Mingzhi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-a3568a11d92ddc2370c5b628ecc1c9384a96e4e5b5cbc9c8523c1d8e20afea273</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Binary systems</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Crystallization</topic><topic>Degree of crystallinity</topic><topic>Elongation</topic><topic>Food Science</topic><topic>Mechanical properties</topic><topic>Miscibility</topic><topic>Morphology</topic><topic>Nanotechnology and Microengineering</topic><topic>Nucleation</topic><topic>Original Contribution</topic><topic>Physical Chemistry</topic><topic>Polymer blends</topic><topic>Polymer Sciences</topic><topic>Polyvinyl acetates</topic><topic>Rheological properties</topic><topic>Rheology</topic><topic>Soft and Granular Matter</topic><topic>Stiffness</topic><topic>Vinyl acetate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Yi</creatorcontrib><creatorcontrib>Han, Changyu</creatorcontrib><creatorcontrib>Xiao, Liguang</creatorcontrib><creatorcontrib>Yu, Yancun</creatorcontrib><creatorcontrib>Zhou, Guangbin</creatorcontrib><creatorcontrib>Xu, Mingzhi</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Yi</au><au>Han, Changyu</au><au>Xiao, Liguang</au><au>Yu, Yancun</au><au>Zhou, Guangbin</au><au>Xu, Mingzhi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Miscibility, morphology, and properties of poly(butylene succinate)/poly(vinyl acetate) blends</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2021</date><risdate>2021</risdate><volume>299</volume><issue>1</issue><spage>105</spage><epage>116</epage><pages>105-116</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><abstract>Poly(butylene succinate) (PBS)/poly(vinyl acetate) (PVAc) blends were prepared by melt mixing. The miscibility, morphology, non-isothermal and isothermal crystallization, and rheological and mechanical properties of PBS/PVAc blends were investigated. The blends were a partial miscible two-phase system with PVAc evenly dispersed in the PBS matrix. The incorporation of PVAc accelerated the crystallization rate of PBS due to the heterogeneous nucleation, but decreased the degree of crystallinity. The rheological properties of PBS were greatly improved by the incorporation of PVAc, because of the high viscosity of PVAc in melt state. The most intriguing result was that the stiffness, strength, and toughness could be improved simultaneously by the addition of PVAc. The modulus, breaking strength, and elongation at break of PBS containing 10 wt% PVAc increased by 3.5%, 15.7%, and 43.4%, respectively. The synergetic improvement in the crystallization, rheological, and mechanical properties may be of much importance for widening the application of PBS.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00396-020-04773-7</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0303-402X |
| ispartof | Colloid and polymer science, 2021, Vol.299 (1), p.105-116 |
| issn | 0303-402X 1435-1536 |
| language | eng |
| recordid | cdi_proquest_journals_2475201563 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Binary systems Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Crystallization Degree of crystallinity Elongation Food Science Mechanical properties Miscibility Morphology Nanotechnology and Microengineering Nucleation Original Contribution Physical Chemistry Polymer blends Polymer Sciences Polyvinyl acetates Rheological properties Rheology Soft and Granular Matter Stiffness Vinyl acetate |
| title | Miscibility, morphology, and properties of poly(butylene succinate)/poly(vinyl acetate) blends |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T00%3A57%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Miscibility,%20morphology,%20and%20properties%20of%20poly(butylene%20succinate)/poly(vinyl%20acetate)%20blends&rft.jtitle=Colloid%20and%20polymer%20science&rft.au=Li,%20Yi&rft.date=2021&rft.volume=299&rft.issue=1&rft.spage=105&rft.epage=116&rft.pages=105-116&rft.issn=0303-402X&rft.eissn=1435-1536&rft_id=info:doi/10.1007/s00396-020-04773-7&rft_dat=%3Cproquest_cross%3E2475201563%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2475201563&rft_id=info:pmid/&rfr_iscdi=true |