Stretchable Freestanding Films of 3D Nanocrystalline Blue Phase Elastomer and Their Tunable Applications
Given that it is a potential medium for 3D manipulation of photons in the forward‐looking technology of quantum optics, nonlinear optics, electronics, nanomaterials, and bionics, 3D photonic crystal (PhC) is a promising material of strategic significance and has great impact on scientific developmen...
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Veröffentlicht in: | Advanced optical materials 2021-01, Vol.9 (1), p.n/a |
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description | Given that it is a potential medium for 3D manipulation of photons in the forward‐looking technology of quantum optics, nonlinear optics, electronics, nanomaterials, and bionics, 3D photonic crystal (PhC) is a promising material of strategic significance and has great impact on scientific development. Blue phase (BP), a liquid crystalline mesophase with unique nanoscaled 3D PhC features, has been shown to contain significant potential values in fundamental studies and technological applications. However, thus far, the environmental stability of BP devices remains a puzzling issue of material exploitation. Therefore, in this study, stretching‐tunable BP elastomer (BPE) photonic bandgap (PBG) free‐standing films are fabricated via full photopolymerization. The BPE films exhibit benefit‐specific features, including sharp PBG with high reflectivity and flexible tunability in the visible region, high thermal stability, and good mechanical ductility and resistance in chemicals. These properties are attributed to the pre‐developed, fully‐reactive mesogenic materials employed, which show BP states in a wide temperature range, including room temperature. Additionally, mirrorless laser applications with flexible tunability are also realized in this study. The freestanding BPE film can be used as a prototype instrumentality to promote the future development of multifunctional intelligent applications in lasers, sensors, displays, intelligent lightings, lidars, micro‐robots and antennas.
A flexible and stretching‐tunable blue phase elastomer (BPE) photonic bandgap (PBG) freestanding film and a mirrorless laser are made by fully reactive mesogenic materials at room temperature. The BPE film with a well‐defined 3D nanocrystalline superstructure formed by self‐assembly shows sharp PBG, high reflectivity and tunability in the visible region, high thermal stability, good mechanical ductility, and high chemical resistance. |
doi_str_mv | 10.1002/adom.202001427 |
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A flexible and stretching‐tunable blue phase elastomer (BPE) photonic bandgap (PBG) freestanding film and a mirrorless laser are made by fully reactive mesogenic materials at room temperature. The BPE film with a well‐defined 3D nanocrystalline superstructure formed by self‐assembly shows sharp PBG, high reflectivity and tunability in the visible region, high thermal stability, good mechanical ductility, and high chemical resistance.</description><identifier>ISSN: 2195-1071</identifier><identifier>EISSN: 2195-1071</identifier><identifier>DOI: 10.1002/adom.202001427</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>3D photonic crystals ; Bionics ; blue phase liquid crystals ; Elastomers ; Laser applications ; liquid crystal elastomers ; Liquid crystals ; Materials science ; mirrorless lasers ; Nanomaterials ; Nonlinear optics ; Optics ; Photonic band gaps ; Photonic crystals ; Photopolymerization ; Quantum optics ; Room temperature ; self‐assembly ; Thermal stability</subject><ispartof>Advanced optical materials, 2021-01, Vol.9 (1), p.n/a</ispartof><rights>2020 Wiley‐VCH GmbH</rights><rights>2021 Wiley‐VCH GmbH</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3177-e634212f6a296bf16ec2666457fd55dee395fd0509713f616b6efcbe951b4c583</citedby><cites>FETCH-LOGICAL-c3177-e634212f6a296bf16ec2666457fd55dee395fd0509713f616b6efcbe951b4c583</cites><orcidid>0000-0002-7917-7583</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadom.202001427$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadom.202001427$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Zhang, Yan‐Song</creatorcontrib><creatorcontrib>Jiang, Shun‐An</creatorcontrib><creatorcontrib>Lin, Jia‐De</creatorcontrib><creatorcontrib>Yang, Po‐Chih</creatorcontrib><creatorcontrib>Lee, Chia‐Rong</creatorcontrib><title>Stretchable Freestanding Films of 3D Nanocrystalline Blue Phase Elastomer and Their Tunable Applications</title><title>Advanced optical materials</title><description>Given that it is a potential medium for 3D manipulation of photons in the forward‐looking technology of quantum optics, nonlinear optics, electronics, nanomaterials, and bionics, 3D photonic crystal (PhC) is a promising material of strategic significance and has great impact on scientific development. Blue phase (BP), a liquid crystalline mesophase with unique nanoscaled 3D PhC features, has been shown to contain significant potential values in fundamental studies and technological applications. However, thus far, the environmental stability of BP devices remains a puzzling issue of material exploitation. Therefore, in this study, stretching‐tunable BP elastomer (BPE) photonic bandgap (PBG) free‐standing films are fabricated via full photopolymerization. The BPE films exhibit benefit‐specific features, including sharp PBG with high reflectivity and flexible tunability in the visible region, high thermal stability, and good mechanical ductility and resistance in chemicals. These properties are attributed to the pre‐developed, fully‐reactive mesogenic materials employed, which show BP states in a wide temperature range, including room temperature. Additionally, mirrorless laser applications with flexible tunability are also realized in this study. The freestanding BPE film can be used as a prototype instrumentality to promote the future development of multifunctional intelligent applications in lasers, sensors, displays, intelligent lightings, lidars, micro‐robots and antennas.
A flexible and stretching‐tunable blue phase elastomer (BPE) photonic bandgap (PBG) freestanding film and a mirrorless laser are made by fully reactive mesogenic materials at room temperature. The BPE film with a well‐defined 3D nanocrystalline superstructure formed by self‐assembly shows sharp PBG, high reflectivity and tunability in the visible region, high thermal stability, good mechanical ductility, and high chemical resistance.</description><subject>3D photonic crystals</subject><subject>Bionics</subject><subject>blue phase liquid crystals</subject><subject>Elastomers</subject><subject>Laser applications</subject><subject>liquid crystal elastomers</subject><subject>Liquid crystals</subject><subject>Materials science</subject><subject>mirrorless lasers</subject><subject>Nanomaterials</subject><subject>Nonlinear optics</subject><subject>Optics</subject><subject>Photonic band gaps</subject><subject>Photonic crystals</subject><subject>Photopolymerization</subject><subject>Quantum optics</subject><subject>Room temperature</subject><subject>self‐assembly</subject><subject>Thermal stability</subject><issn>2195-1071</issn><issn>2195-1071</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkE1PwzAMhisEEtPYlXMkzh1J2iTkOPYBSIMhMc5V2jo0U9qUpBXav6djCLhxsiU_jy2_UXRJ8JRgTK9V6eopxRRjklJxEo0okSwmWJDTP_15NAlhhwcIi0SmYhRVL52HrqhUbgGtPEDoVFOa5g2tjK0DcholC_SkGlf4_TCz1jSAbm0P6LlSAdDSqtC5GjwaPLStwHi07ZuvfbO2taZQnXFNuIjOtLIBJt91HL2ultv5fbze3D3MZ-u4SIgQMfAkpYRqrqjkuSYcCso5T5nQJWMlQCKZLjHDUpBEc8JzDrrIQTKSpwW7ScbR1XFv6917P7yT7Vzvm-FkRlORCpFQyQZqeqQK70LwoLPWm1r5fUZwdgg0OwSa_QQ6CPIofBgL-3_obLbYPP66n8gwebM</recordid><startdate>20210101</startdate><enddate>20210101</enddate><creator>Zhang, Yan‐Song</creator><creator>Jiang, Shun‐An</creator><creator>Lin, Jia‐De</creator><creator>Yang, Po‐Chih</creator><creator>Lee, Chia‐Rong</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-7917-7583</orcidid></search><sort><creationdate>20210101</creationdate><title>Stretchable Freestanding Films of 3D Nanocrystalline Blue Phase Elastomer and Their Tunable Applications</title><author>Zhang, Yan‐Song ; Jiang, Shun‐An ; Lin, Jia‐De ; Yang, Po‐Chih ; Lee, Chia‐Rong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3177-e634212f6a296bf16ec2666457fd55dee395fd0509713f616b6efcbe951b4c583</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>3D photonic crystals</topic><topic>Bionics</topic><topic>blue phase liquid crystals</topic><topic>Elastomers</topic><topic>Laser applications</topic><topic>liquid crystal elastomers</topic><topic>Liquid crystals</topic><topic>Materials science</topic><topic>mirrorless lasers</topic><topic>Nanomaterials</topic><topic>Nonlinear optics</topic><topic>Optics</topic><topic>Photonic band gaps</topic><topic>Photonic crystals</topic><topic>Photopolymerization</topic><topic>Quantum optics</topic><topic>Room temperature</topic><topic>self‐assembly</topic><topic>Thermal stability</topic><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yan‐Song</creatorcontrib><creatorcontrib>Jiang, Shun‐An</creatorcontrib><creatorcontrib>Lin, Jia‐De</creatorcontrib><creatorcontrib>Yang, Po‐Chih</creatorcontrib><creatorcontrib>Lee, Chia‐Rong</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced optical materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Yan‐Song</au><au>Jiang, Shun‐An</au><au>Lin, Jia‐De</au><au>Yang, Po‐Chih</au><au>Lee, Chia‐Rong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Stretchable Freestanding Films of 3D Nanocrystalline Blue Phase Elastomer and Their Tunable Applications</atitle><jtitle>Advanced optical materials</jtitle><date>2021-01-01</date><risdate>2021</risdate><volume>9</volume><issue>1</issue><epage>n/a</epage><issn>2195-1071</issn><eissn>2195-1071</eissn><abstract>Given that it is a potential medium for 3D manipulation of photons in the forward‐looking technology of quantum optics, nonlinear optics, electronics, nanomaterials, and bionics, 3D photonic crystal (PhC) is a promising material of strategic significance and has great impact on scientific development. Blue phase (BP), a liquid crystalline mesophase with unique nanoscaled 3D PhC features, has been shown to contain significant potential values in fundamental studies and technological applications. However, thus far, the environmental stability of BP devices remains a puzzling issue of material exploitation. Therefore, in this study, stretching‐tunable BP elastomer (BPE) photonic bandgap (PBG) free‐standing films are fabricated via full photopolymerization. The BPE films exhibit benefit‐specific features, including sharp PBG with high reflectivity and flexible tunability in the visible region, high thermal stability, and good mechanical ductility and resistance in chemicals. These properties are attributed to the pre‐developed, fully‐reactive mesogenic materials employed, which show BP states in a wide temperature range, including room temperature. Additionally, mirrorless laser applications with flexible tunability are also realized in this study. The freestanding BPE film can be used as a prototype instrumentality to promote the future development of multifunctional intelligent applications in lasers, sensors, displays, intelligent lightings, lidars, micro‐robots and antennas.
A flexible and stretching‐tunable blue phase elastomer (BPE) photonic bandgap (PBG) freestanding film and a mirrorless laser are made by fully reactive mesogenic materials at room temperature. The BPE film with a well‐defined 3D nanocrystalline superstructure formed by self‐assembly shows sharp PBG, high reflectivity and tunability in the visible region, high thermal stability, good mechanical ductility, and high chemical resistance.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adom.202001427</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-7917-7583</orcidid></addata></record> |
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subjects | 3D photonic crystals Bionics blue phase liquid crystals Elastomers Laser applications liquid crystal elastomers Liquid crystals Materials science mirrorless lasers Nanomaterials Nonlinear optics Optics Photonic band gaps Photonic crystals Photopolymerization Quantum optics Room temperature self‐assembly Thermal stability |
title | Stretchable Freestanding Films of 3D Nanocrystalline Blue Phase Elastomer and Their Tunable Applications |
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