Poly(3-hexylthiophene) Crystalline Cubes: A Facile Preparation of Polymer Particles Featuring Long-range Ordering

Poly(3-hexylthiophene) Crystalline Cubes: A Facile Preparation of Polymer Particles Featuring Long-range Ordering

Conjugated polymer crystals enable us to realize an ideal platform for the highest density-of-state of electrons in valence and conduction bands. Herein we report a facile protocol to prepare crystalline particles (P3HT-CP) of poly(3-hexylthiophene) (P3HT) with clear cubic shapes. Long-range orderin...

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Veröffentlicht in:Chemistry letters 2020-12, Vol.49 (12), p.1494-1496
Hauptverfasser: Cha, Won-Young, Lee, Jae-yeon, Park, Jinwoo, Koo, Yun Hee, Park, Juhyun, Seki, Shu, Kim, Won-Suk, Park, JaeHong
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Sprache:eng
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Absorption spectra
Conduction bands
Crystal structure
Crystallinity
Cubes
Polymers
Thin films
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container_end_page 1496
container_issue 12
container_start_page 1494
container_title Chemistry letters
container_volume 49
creator Cha, Won-Young
Lee, Jae-yeon
Park, Jinwoo
Koo, Yun Hee
Park, Juhyun
Seki, Shu
Kim, Won-Suk
Park, JaeHong
description Conjugated polymer crystals enable us to realize an ideal platform for the highest density-of-state of electrons in valence and conduction bands. Herein we report a facile protocol to prepare crystalline particles (P3HT-CP) of poly(3-hexylthiophene) (P3HT) with clear cubic shapes. Long-range ordering of P3HT has been confirmed by microscopic techniques, suggesting extremely small contribution from amorphous domains in the cubic structures. The comparable electronic absorption spectra of P3HT-CP dispersion and the thin-film of P3HT-CP suggest the suppression of additional structural evolution during solvent evaporation and stable dispersion.
doi_str_mv 10.1246/cl.200597
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source Oxford University Press Journals All Titles (1996-Current)
subjects Absorption spectra
Conduction bands
Crystal structure
Crystallinity
Cubes
Polymers
Thin films
title Poly(3-hexylthiophene) Crystalline Cubes: A Facile Preparation of Polymer Particles Featuring Long-range Ordering
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