Synthesis of Block Copolymers of Acrylic Acid and N-Butyl Acrylate under Reversible Chain-Transfer Conditions in a Water-Alcohol Medium
The laws of dispersion polymerization of n -butyl acrylate in an aqueous-alcoholic medium in the presence of a hydrophilic reversible addition-fragmentation chain-transfer poly(acrylic acid)-based polymeric agent with a trithiocarbonate group within the chain are investigated. It is shown that the p...
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| Veröffentlicht in: | Polymer science. Series B 2020-09, Vol.62 (5), p.499-508 |
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| container_title | Polymer science. Series B |
| container_volume | 62 |
| creator | Serkhacheva, N. S. Chernikova, E. V. Prokopov, N. I. Ogai, V. V. Mineeva, K. O. Tselousov, D. S. Plyusnina, I. O. |
| description | The laws of dispersion polymerization of
n
-butyl acrylate in an aqueous-alcoholic medium in the presence of a hydrophilic reversible addition-fragmentation chain-transfer poly(acrylic acid)-based polymeric agent with a trithiocarbonate group within the chain are investigated. It is shown that the portioned introduction of the monomer into the synthesis makes it possible to achieve higher maximum conversions. The resulting block copolymers are characterized by a relatively narrow molecular weight distribution and their number-average molecular weight increases linearly with increasing monomer concentration. The obtained dispersions of triblock copolymer poly(acrylic acid)–
block-
poly(
n-
butyl acrylate)–
block-
poly(acrylic acid) have a unimodal particle size distribution that persists after dialysis against water. It is shown that the synthesized dispersions may be used as a polymer matrix for immobilizing zinc oxide nanoparticles and as a polymer precursor in the process of the seeded polymerization of styrene. |
| doi_str_mv | 10.1134/S1560090420050115 |
| format | Article |
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n
-butyl acrylate in an aqueous-alcoholic medium in the presence of a hydrophilic reversible addition-fragmentation chain-transfer poly(acrylic acid)-based polymeric agent with a trithiocarbonate group within the chain are investigated. It is shown that the portioned introduction of the monomer into the synthesis makes it possible to achieve higher maximum conversions. The resulting block copolymers are characterized by a relatively narrow molecular weight distribution and their number-average molecular weight increases linearly with increasing monomer concentration. The obtained dispersions of triblock copolymer poly(acrylic acid)–
block-
poly(
n-
butyl acrylate)–
block-
poly(acrylic acid) have a unimodal particle size distribution that persists after dialysis against water. It is shown that the synthesized dispersions may be used as a polymer matrix for immobilizing zinc oxide nanoparticles and as a polymer precursor in the process of the seeded polymerization of styrene.</description><identifier>ISSN: 1560-0904</identifier><identifier>EISSN: 1555-6123</identifier><identifier>DOI: 10.1134/S1560090420050115</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Acids ; Acrylics ; Block copolymers ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Dispersions ; Functional Polymers ; Molecular weight ; Molecular weight distribution ; Monomers ; Nanoparticles ; Particle size distribution ; Polyacrylic acid ; Polymer Sciences ; Polymerization ; Prepolymers ; Reagents ; Zinc oxide</subject><ispartof>Polymer science. Series B, 2020-09, Vol.62 (5), p.499-508</ispartof><rights>Pleiades Publishing, Ltd. 2020</rights><rights>Pleiades Publishing, Ltd. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-46633f9ecb078a53029704065c70b0aecb44294176b5bc3773635bec4b4e32b73</citedby><cites>FETCH-LOGICAL-c353t-46633f9ecb078a53029704065c70b0aecb44294176b5bc3773635bec4b4e32b73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1560090420050115$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1560090420050115$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Serkhacheva, N. S.</creatorcontrib><creatorcontrib>Chernikova, E. V.</creatorcontrib><creatorcontrib>Prokopov, N. I.</creatorcontrib><creatorcontrib>Ogai, V. V.</creatorcontrib><creatorcontrib>Mineeva, K. O.</creatorcontrib><creatorcontrib>Tselousov, D. S.</creatorcontrib><creatorcontrib>Plyusnina, I. O.</creatorcontrib><title>Synthesis of Block Copolymers of Acrylic Acid and N-Butyl Acrylate under Reversible Chain-Transfer Conditions in a Water-Alcohol Medium</title><title>Polymer science. Series B</title><addtitle>Polym. Sci. Ser. B</addtitle><description>The laws of dispersion polymerization of
n
-butyl acrylate in an aqueous-alcoholic medium in the presence of a hydrophilic reversible addition-fragmentation chain-transfer poly(acrylic acid)-based polymeric agent with a trithiocarbonate group within the chain are investigated. It is shown that the portioned introduction of the monomer into the synthesis makes it possible to achieve higher maximum conversions. The resulting block copolymers are characterized by a relatively narrow molecular weight distribution and their number-average molecular weight increases linearly with increasing monomer concentration. The obtained dispersions of triblock copolymer poly(acrylic acid)–
block-
poly(
n-
butyl acrylate)–
block-
poly(acrylic acid) have a unimodal particle size distribution that persists after dialysis against water. It is shown that the synthesized dispersions may be used as a polymer matrix for immobilizing zinc oxide nanoparticles and as a polymer precursor in the process of the seeded polymerization of styrene.</description><subject>Acids</subject><subject>Acrylics</subject><subject>Block copolymers</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dispersions</subject><subject>Functional Polymers</subject><subject>Molecular weight</subject><subject>Molecular weight distribution</subject><subject>Monomers</subject><subject>Nanoparticles</subject><subject>Particle size distribution</subject><subject>Polyacrylic acid</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Prepolymers</subject><subject>Reagents</subject><subject>Zinc oxide</subject><issn>1560-0904</issn><issn>1555-6123</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kN1KxDAQhYsouKz7AN4FvK5OOkljL9fiH_gDruJlSdPUjXaTNWmFPoGvbdYVvBDnZoY55zsDkySHFI4pRXayoDwHKIBlABwo5TvJhHLO05xmuLuZc0g3-n4yC-EVYmGBlBaT5HMx2n6pgwnEteSsc-qNlG7tunGl_fdurvzYGRW7aYi0DblLz4Z-7LaC7DUZbKM9edAfkTB1p0m5lMamj17a0EaldLYxvXE2EGOJJM8R8um8U27pOnKrGzOsDpK9VnZBz376NHm6OH8sr9Kb-8vrcn6TKuTYpyzPEdtCqxrEqeQIWSGAQc6VgBpk3DOWFYyKvOa1QiEwR15rxWqmMasFTpOjbe7au_dBh756dYO38WSVMYGiAEQWXXTrUt6F4HVbrb1ZST9WFKrNy6s_L49MtmVC9NoX7X-T_4e-AHRIgdc</recordid><startdate>20200901</startdate><enddate>20200901</enddate><creator>Serkhacheva, N. S.</creator><creator>Chernikova, E. V.</creator><creator>Prokopov, N. I.</creator><creator>Ogai, V. V.</creator><creator>Mineeva, K. O.</creator><creator>Tselousov, D. S.</creator><creator>Plyusnina, I. O.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200901</creationdate><title>Synthesis of Block Copolymers of Acrylic Acid and N-Butyl Acrylate under Reversible Chain-Transfer Conditions in a Water-Alcohol Medium</title><author>Serkhacheva, N. S. ; Chernikova, E. V. ; Prokopov, N. I. ; Ogai, V. V. ; Mineeva, K. O. ; Tselousov, D. S. ; Plyusnina, I. O.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-46633f9ecb078a53029704065c70b0aecb44294176b5bc3773635bec4b4e32b73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Acids</topic><topic>Acrylics</topic><topic>Block copolymers</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dispersions</topic><topic>Functional Polymers</topic><topic>Molecular weight</topic><topic>Molecular weight distribution</topic><topic>Monomers</topic><topic>Nanoparticles</topic><topic>Particle size distribution</topic><topic>Polyacrylic acid</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Prepolymers</topic><topic>Reagents</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Serkhacheva, N. S.</creatorcontrib><creatorcontrib>Chernikova, E. V.</creatorcontrib><creatorcontrib>Prokopov, N. I.</creatorcontrib><creatorcontrib>Ogai, V. V.</creatorcontrib><creatorcontrib>Mineeva, K. O.</creatorcontrib><creatorcontrib>Tselousov, D. S.</creatorcontrib><creatorcontrib>Plyusnina, I. O.</creatorcontrib><collection>CrossRef</collection><jtitle>Polymer science. Series B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Serkhacheva, N. S.</au><au>Chernikova, E. V.</au><au>Prokopov, N. I.</au><au>Ogai, V. V.</au><au>Mineeva, K. O.</au><au>Tselousov, D. S.</au><au>Plyusnina, I. O.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Block Copolymers of Acrylic Acid and N-Butyl Acrylate under Reversible Chain-Transfer Conditions in a Water-Alcohol Medium</atitle><jtitle>Polymer science. Series B</jtitle><stitle>Polym. Sci. Ser. B</stitle><date>2020-09-01</date><risdate>2020</risdate><volume>62</volume><issue>5</issue><spage>499</spage><epage>508</epage><pages>499-508</pages><issn>1560-0904</issn><eissn>1555-6123</eissn><abstract>The laws of dispersion polymerization of
n
-butyl acrylate in an aqueous-alcoholic medium in the presence of a hydrophilic reversible addition-fragmentation chain-transfer poly(acrylic acid)-based polymeric agent with a trithiocarbonate group within the chain are investigated. It is shown that the portioned introduction of the monomer into the synthesis makes it possible to achieve higher maximum conversions. The resulting block copolymers are characterized by a relatively narrow molecular weight distribution and their number-average molecular weight increases linearly with increasing monomer concentration. The obtained dispersions of triblock copolymer poly(acrylic acid)–
block-
poly(
n-
butyl acrylate)–
block-
poly(acrylic acid) have a unimodal particle size distribution that persists after dialysis against water. It is shown that the synthesized dispersions may be used as a polymer matrix for immobilizing zinc oxide nanoparticles and as a polymer precursor in the process of the seeded polymerization of styrene.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1560090420050115</doi><tpages>10</tpages></addata></record> |
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| ispartof | Polymer science. Series B, 2020-09, Vol.62 (5), p.499-508 |
| issn | 1560-0904 1555-6123 |
| language | eng |
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| source | SpringerLink Journals (MCLS) |
| subjects | Acids Acrylics Block copolymers Chemical synthesis Chemistry Chemistry and Materials Science Dispersions Functional Polymers Molecular weight Molecular weight distribution Monomers Nanoparticles Particle size distribution Polyacrylic acid Polymer Sciences Polymerization Prepolymers Reagents Zinc oxide |
| title | Synthesis of Block Copolymers of Acrylic Acid and N-Butyl Acrylate under Reversible Chain-Transfer Conditions in a Water-Alcohol Medium |
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