Voltammetric determination of Auramine O with ZIF-67/Fe2O3/g-C3N4-modified electrode

In the present work, the synthesis of ZIF-67/Fe 2 O 3 / g -C 3 N 4 and its use for voltammetric determination of Auramine O are demonstrated. The resulting materials were characterized by means of X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electro...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2020-11, Vol.31 (22), p.19741-19755
Hauptverfasser: Hoa, Dang Thi Ngoc, Toan, Tran Thanh Tam, Mau, Tran Xuan, Hoan, Nguyen Thi Vuong, Tram, Tran Thi Nhat, Manh, Tran Duc, Nguyen, Vo Thang, Duyen, Vu Thi, Thong, Pham Le Minh, Khieu, Dinh Quang
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container_end_page 19755
container_issue 22
container_start_page 19741
container_title Journal of materials science. Materials in electronics
container_volume 31
creator Hoa, Dang Thi Ngoc
Toan, Tran Thanh Tam
Mau, Tran Xuan
Hoan, Nguyen Thi Vuong
Tram, Tran Thi Nhat
Manh, Tran Duc
Nguyen, Vo Thang
Duyen, Vu Thi
Thong, Pham Le Minh
Khieu, Dinh Quang
description In the present work, the synthesis of ZIF-67/Fe 2 O 3 / g -C 3 N 4 and its use for voltammetric determination of Auramine O are demonstrated. The resulting materials were characterized by means of X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, and nitrogen adsorption/desorption isotherm. The composite composes of polyhedron ZIF-67 particles evenly decorated with flocculent Fe 2 O 3 /g-C 3 N 4 and has a specific surface area of 600 m 2 .g − 1 . Cyclic voltammetry and differential pulse voltammetry were performed to investigate the electrochemical behavior of Auramine O at ZIF-67/Fe 2 O 3 / g -C 3 N 4 -modified electrode. An excellent linear relationship between the anodic peak current and Auramine O concentration was found in the range of 1.9–17 µM under the optimized experimental conditions. The proposed electrochemical method exhibits high repeatability with a low detection limit of 0.65 µM. This method was successfully employed to the determine Auramine O in pickled vegetable samples, showing excellent agreement with the results obtained from HPLC analysis.
doi_str_mv 10.1007/s10854-020-04499-w
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The resulting materials were characterized by means of X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, and nitrogen adsorption/desorption isotherm. The composite composes of polyhedron ZIF-67 particles evenly decorated with flocculent Fe 2 O 3 /g-C 3 N 4 and has a specific surface area of 600 m 2 .g − 1 . Cyclic voltammetry and differential pulse voltammetry were performed to investigate the electrochemical behavior of Auramine O at ZIF-67/Fe 2 O 3 / g -C 3 N 4 -modified electrode. An excellent linear relationship between the anodic peak current and Auramine O concentration was found in the range of 1.9–17 µM under the optimized experimental conditions. The proposed electrochemical method exhibits high repeatability with a low detection limit of 0.65 µM. 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An excellent linear relationship between the anodic peak current and Auramine O concentration was found in the range of 1.9–17 µM under the optimized experimental conditions. The proposed electrochemical method exhibits high repeatability with a low detection limit of 0.65 µM. This method was successfully employed to the determine Auramine O in pickled vegetable samples, showing excellent agreement with the results obtained from HPLC analysis.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-020-04499-w</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0003-3473-6377</orcidid></addata></record>
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subjects Carbon nitride
Characterization and Evaluation of Materials
Chemistry and Materials Science
Electrochemical analysis
Electrodes
Electron microscopy
Electrons
Materials Science
Microscopy
Optical and Electronic Materials
Particulate composites
Photoelectrons
Voltammetry
title Voltammetric determination of Auramine O with ZIF-67/Fe2O3/g-C3N4-modified electrode
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