On the temperature-dependent diffusion growth of ϕ-Mg5Al2Zn2 ternary intermetallic compound in the Mg–Al–Zn system
The study on the temperature-dependent kinetic behavior of intermetallic compounds (IMCs) in Mg–Al–Zn (AZ) series alloy system is important since its close interrelation with the microstructure evolution under various alloying conditions as well as the T-dependent performance. However, there is a ve...
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| Veröffentlicht in: | Journal of materials science 2021-02, Vol.56 (4), p.3488-3497 |
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| creator | Cheng, Kaiming Sun, Jiaxing Xu, Huixia Wang, Jin Zhou, Jixue Tang, Shouqiu Wang, Xitao Zhang, Lijun Du, Yong |
| description | The study on the temperature-dependent kinetic behavior of intermetallic compounds (IMCs) in Mg–Al–Zn (AZ) series alloy system is important since its close interrelation with the microstructure evolution under various alloying conditions as well as the T-dependent performance. However, there is a very lack of experimental study on the diffusion kinetics of the ternary IMCs in the AZ series alloy systems. The current work combines the diffusion couple technique and numerical inverse method to investigate the T-dependent kinetic coefficients, i.e., the parabolic growth constant (PGC) and interdiffusion coefficients, for ϕ
-
Mg
5
Al
2
Zn
2
ternary IMC in the Mg–Al–Zn alloy system. The Arrhenius formula of both PGC and main interdiffusivities is obtained, i.e.,
ϕ
k
p
=
5.48
×
10
-
5
exp
120010
RT
m
2
/s,
ϕ
D
~
MgMg
Al
=
3.48
×
10
-
10
exp
50420
RT
m
2
/s and
ϕ
D
~
ZnZn
Al
=
2.87
×
10
-
7
exp
91440
RT
m
2
/s, based on which a numerical reproduction of the experimentally determined IMC growth is performed for verification. By comparing the current experimental and calculation results, the rate-controlling factor of the temperature-dependent diffusion growth of ϕ ternary IMC in the Mg–Al–Zn system is further discussed. |
| doi_str_mv | 10.1007/s10853-020-05439-z |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2471685886</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2471685886</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-fe8d2491ed7ccd2ebbc630da3ea38080280c819cb41c1280f8468cd25ebe533a3</originalsourceid><addsrcrecordid>eNp9UEtOwzAQtRBIlMIFWFlibRjb-bjLquInteoGNt1YiTNpU6VOsBNVZcUdEOfiDpwE0yKxYzM_vfdm5hFyyeGaA6Q3noOKJQMBDOJIjtjrERnwOJUsUiCPyQBACCaihJ-SM-_XABCngg_Idm5pt0La4aZFl3W9Q1Zgi7ZA29GiKsveV42lS9dsuxVtSvr5wWbLeFyLhRWB5mzmdrSyodpgl9V1ZahpNm3T2yKM9-Kz5dfb-7gOYWGp3_mw7JyclFnt8eI3D8nz3e3T5IFN5_ePk_GUGclHHStRFSIacSxSYwqBeW4SCUUmMZMKFAgFRvGRySNueGhKFSUqAGPMMZYyk0NyddBtXfPSo-_0uunDzbXXIkp5omKlkoASB5RxjfcOS926ahMe0xz0j8H6YLAOBuu9wfo1kOSB5APYLtH9Sf_D-gbHUoLB</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2471685886</pqid></control><display><type>article</type><title>On the temperature-dependent diffusion growth of ϕ-Mg5Al2Zn2 ternary intermetallic compound in the Mg–Al–Zn system</title><source>Springer Nature - Complete Springer Journals</source><creator>Cheng, Kaiming ; Sun, Jiaxing ; Xu, Huixia ; Wang, Jin ; Zhou, Jixue ; Tang, Shouqiu ; Wang, Xitao ; Zhang, Lijun ; Du, Yong</creator><creatorcontrib>Cheng, Kaiming ; Sun, Jiaxing ; Xu, Huixia ; Wang, Jin ; Zhou, Jixue ; Tang, Shouqiu ; Wang, Xitao ; Zhang, Lijun ; Du, Yong</creatorcontrib><description>The study on the temperature-dependent kinetic behavior of intermetallic compounds (IMCs) in Mg–Al–Zn (AZ) series alloy system is important since its close interrelation with the microstructure evolution under various alloying conditions as well as the T-dependent performance. However, there is a very lack of experimental study on the diffusion kinetics of the ternary IMCs in the AZ series alloy systems. The current work combines the diffusion couple technique and numerical inverse method to investigate the T-dependent kinetic coefficients, i.e., the parabolic growth constant (PGC) and interdiffusion coefficients, for ϕ
-
Mg
5
Al
2
Zn
2
ternary IMC in the Mg–Al–Zn alloy system. The Arrhenius formula of both PGC and main interdiffusivities is obtained, i.e.,
ϕ
k
p
=
5.48
×
10
-
5
exp
120010
RT
m
2
/s,
ϕ
D
~
MgMg
Al
=
3.48
×
10
-
10
exp
50420
RT
m
2
/s and
ϕ
D
~
ZnZn
Al
=
2.87
×
10
-
7
exp
91440
RT
m
2
/s, based on which a numerical reproduction of the experimentally determined IMC growth is performed for verification. By comparing the current experimental and calculation results, the rate-controlling factor of the temperature-dependent diffusion growth of ϕ ternary IMC in the Mg–Al–Zn system is further discussed.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-020-05439-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Alloy systems ; Aluminum base alloys ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Crystallography and Scattering Methods ; Diffusion rate ; Interdiffusion ; Intermetallic compounds ; Inverse method ; Kinetic coefficients ; Magnesium ; Materials Science ; Metals & Corrosion ; Polymer Sciences ; Solid Mechanics ; Temperature dependence ; Zinc</subject><ispartof>Journal of materials science, 2021-02, Vol.56 (4), p.3488-3497</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-fe8d2491ed7ccd2ebbc630da3ea38080280c819cb41c1280f8468cd25ebe533a3</citedby><cites>FETCH-LOGICAL-c319t-fe8d2491ed7ccd2ebbc630da3ea38080280c819cb41c1280f8468cd25ebe533a3</cites><orcidid>0000-0002-3866-2320</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-020-05439-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-020-05439-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Cheng, Kaiming</creatorcontrib><creatorcontrib>Sun, Jiaxing</creatorcontrib><creatorcontrib>Xu, Huixia</creatorcontrib><creatorcontrib>Wang, Jin</creatorcontrib><creatorcontrib>Zhou, Jixue</creatorcontrib><creatorcontrib>Tang, Shouqiu</creatorcontrib><creatorcontrib>Wang, Xitao</creatorcontrib><creatorcontrib>Zhang, Lijun</creatorcontrib><creatorcontrib>Du, Yong</creatorcontrib><title>On the temperature-dependent diffusion growth of ϕ-Mg5Al2Zn2 ternary intermetallic compound in the Mg–Al–Zn system</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>The study on the temperature-dependent kinetic behavior of intermetallic compounds (IMCs) in Mg–Al–Zn (AZ) series alloy system is important since its close interrelation with the microstructure evolution under various alloying conditions as well as the T-dependent performance. However, there is a very lack of experimental study on the diffusion kinetics of the ternary IMCs in the AZ series alloy systems. The current work combines the diffusion couple technique and numerical inverse method to investigate the T-dependent kinetic coefficients, i.e., the parabolic growth constant (PGC) and interdiffusion coefficients, for ϕ
-
Mg
5
Al
2
Zn
2
ternary IMC in the Mg–Al–Zn alloy system. The Arrhenius formula of both PGC and main interdiffusivities is obtained, i.e.,
ϕ
k
p
=
5.48
×
10
-
5
exp
120010
RT
m
2
/s,
ϕ
D
~
MgMg
Al
=
3.48
×
10
-
10
exp
50420
RT
m
2
/s and
ϕ
D
~
ZnZn
Al
=
2.87
×
10
-
7
exp
91440
RT
m
2
/s, based on which a numerical reproduction of the experimentally determined IMC growth is performed for verification. By comparing the current experimental and calculation results, the rate-controlling factor of the temperature-dependent diffusion growth of ϕ ternary IMC in the Mg–Al–Zn system is further discussed.</description><subject>Alloy systems</subject><subject>Aluminum base alloys</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crystallography and Scattering Methods</subject><subject>Diffusion rate</subject><subject>Interdiffusion</subject><subject>Intermetallic compounds</subject><subject>Inverse method</subject><subject>Kinetic coefficients</subject><subject>Magnesium</subject><subject>Materials Science</subject><subject>Metals & Corrosion</subject><subject>Polymer Sciences</subject><subject>Solid Mechanics</subject><subject>Temperature dependence</subject><subject>Zinc</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9UEtOwzAQtRBIlMIFWFlibRjb-bjLquInteoGNt1YiTNpU6VOsBNVZcUdEOfiDpwE0yKxYzM_vfdm5hFyyeGaA6Q3noOKJQMBDOJIjtjrERnwOJUsUiCPyQBACCaihJ-SM-_XABCngg_Idm5pt0La4aZFl3W9Q1Zgi7ZA29GiKsveV42lS9dsuxVtSvr5wWbLeFyLhRWB5mzmdrSyodpgl9V1ZahpNm3T2yKM9-Kz5dfb-7gOYWGp3_mw7JyclFnt8eI3D8nz3e3T5IFN5_ePk_GUGclHHStRFSIacSxSYwqBeW4SCUUmMZMKFAgFRvGRySNueGhKFSUqAGPMMZYyk0NyddBtXfPSo-_0uunDzbXXIkp5omKlkoASB5RxjfcOS926ahMe0xz0j8H6YLAOBuu9wfo1kOSB5APYLtH9Sf_D-gbHUoLB</recordid><startdate>20210201</startdate><enddate>20210201</enddate><creator>Cheng, Kaiming</creator><creator>Sun, Jiaxing</creator><creator>Xu, Huixia</creator><creator>Wang, Jin</creator><creator>Zhou, Jixue</creator><creator>Tang, Shouqiu</creator><creator>Wang, Xitao</creator><creator>Zhang, Lijun</creator><creator>Du, Yong</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-3866-2320</orcidid></search><sort><creationdate>20210201</creationdate><title>On the temperature-dependent diffusion growth of ϕ-Mg5Al2Zn2 ternary intermetallic compound in the Mg–Al–Zn system</title><author>Cheng, Kaiming ; Sun, Jiaxing ; Xu, Huixia ; Wang, Jin ; Zhou, Jixue ; Tang, Shouqiu ; Wang, Xitao ; Zhang, Lijun ; Du, Yong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-fe8d2491ed7ccd2ebbc630da3ea38080280c819cb41c1280f8468cd25ebe533a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Alloy systems</topic><topic>Aluminum base alloys</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crystallography and Scattering Methods</topic><topic>Diffusion rate</topic><topic>Interdiffusion</topic><topic>Intermetallic compounds</topic><topic>Inverse method</topic><topic>Kinetic coefficients</topic><topic>Magnesium</topic><topic>Materials Science</topic><topic>Metals & Corrosion</topic><topic>Polymer Sciences</topic><topic>Solid Mechanics</topic><topic>Temperature dependence</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cheng, Kaiming</creatorcontrib><creatorcontrib>Sun, Jiaxing</creatorcontrib><creatorcontrib>Xu, Huixia</creatorcontrib><creatorcontrib>Wang, Jin</creatorcontrib><creatorcontrib>Zhou, Jixue</creatorcontrib><creatorcontrib>Tang, Shouqiu</creatorcontrib><creatorcontrib>Wang, Xitao</creatorcontrib><creatorcontrib>Zhang, Lijun</creatorcontrib><creatorcontrib>Du, Yong</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cheng, Kaiming</au><au>Sun, Jiaxing</au><au>Xu, Huixia</au><au>Wang, Jin</au><au>Zhou, Jixue</au><au>Tang, Shouqiu</au><au>Wang, Xitao</au><au>Zhang, Lijun</au><au>Du, Yong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>On the temperature-dependent diffusion growth of ϕ-Mg5Al2Zn2 ternary intermetallic compound in the Mg–Al–Zn system</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2021-02-01</date><risdate>2021</risdate><volume>56</volume><issue>4</issue><spage>3488</spage><epage>3497</epage><pages>3488-3497</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>The study on the temperature-dependent kinetic behavior of intermetallic compounds (IMCs) in Mg–Al–Zn (AZ) series alloy system is important since its close interrelation with the microstructure evolution under various alloying conditions as well as the T-dependent performance. However, there is a very lack of experimental study on the diffusion kinetics of the ternary IMCs in the AZ series alloy systems. The current work combines the diffusion couple technique and numerical inverse method to investigate the T-dependent kinetic coefficients, i.e., the parabolic growth constant (PGC) and interdiffusion coefficients, for ϕ
-
Mg
5
Al
2
Zn
2
ternary IMC in the Mg–Al–Zn alloy system. The Arrhenius formula of both PGC and main interdiffusivities is obtained, i.e.,
ϕ
k
p
=
5.48
×
10
-
5
exp
120010
RT
m
2
/s,
ϕ
D
~
MgMg
Al
=
3.48
×
10
-
10
exp
50420
RT
m
2
/s and
ϕ
D
~
ZnZn
Al
=
2.87
×
10
-
7
exp
91440
RT
m
2
/s, based on which a numerical reproduction of the experimentally determined IMC growth is performed for verification. By comparing the current experimental and calculation results, the rate-controlling factor of the temperature-dependent diffusion growth of ϕ ternary IMC in the Mg–Al–Zn system is further discussed.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-020-05439-z</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-3866-2320</orcidid></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Alloy systems Aluminum base alloys Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Diffusion rate Interdiffusion Intermetallic compounds Inverse method Kinetic coefficients Magnesium Materials Science Metals & Corrosion Polymer Sciences Solid Mechanics Temperature dependence Zinc |
| title | On the temperature-dependent diffusion growth of ϕ-Mg5Al2Zn2 ternary intermetallic compound in the Mg–Al–Zn system |
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