Investigating the effect of electrolyte types with various ionic liquids on the electrochromic performance of PEDOT:PSS based LbL multilayers
The objective of the study is to investigate the electrochromic performances of layer-by-layer (LbL) multilayered thin film electrode prepared from linear polyethylene imine (LPEI) and poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) on PET-ITO substrate in the presence of differen...
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| Veröffentlicht in: | Microelectronic engineering 2020-10, Vol.234, p.111454, Article 111454 |
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| container_title | Microelectronic engineering |
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| creator | Okutan, Merve Evecan, Dilek Yıldırım, Saffettin Özkan Zayim, Esra Deligöz, Hüseyin |
| description | The objective of the study is to investigate the electrochromic performances of layer-by-layer (LbL) multilayered thin film electrode prepared from linear polyethylene imine (LPEI) and poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) on PET-ITO substrate in the presence of different types of electrolytes. For this purpose, the electrochromic behaviors of (LPEI/PEDOT:PSS)10 is performed in LiClO4/propylene carbonate (PC) and two different ionic liquids (IL) namely N-methylimidazolium tetrafluoroborate (Melm-BF4) and 2-hydroxy ethyl ammonium formate (2-HEAF), as a function of IL content and scanning rate. The optical contrast value of (LPEI/PEDOT:PSS)10 film is determined as 58.4% in the existence of 10 wt% of 2-HEAF as the electrolyte. The coloration efficiency of this film is determined as 606.7 cm2/C, which this value was greater approximately four times than 1 M LiClO4/PC. According to the obtained results, 2-HEAF has been evaluated as a suitable electrolyte alternative for (LPEI/PEDOT:PSS)10 film due to its better optical contrast and coloration efficiency compared to other electrolytes.
[Display omitted]
•The electrochromic properties of (LPEI/PEDOT:PSS)10 film were studied.•ILs as electrolyte were improved the coloration behavior of (LPEI/PEDOT:PSS)10 film.•2-HEAF was a good alternative as an electrolyte for LbL electrochromic electrode.•10 wt% 2-HEAF was ensured with high optical contrast as 58.4%. |
| doi_str_mv | 10.1016/j.mee.2020.111454 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2470034058</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0167931720302422</els_id><sourcerecordid>2470034058</sourcerecordid><originalsourceid>FETCH-LOGICAL-c325t-7d9a1a1ccbf272cc54b20fc4139b37287a2c83fc9335cd0bf0fd179b0ff761513</originalsourceid><addsrcrecordid>eNp9kMtOwzAQRS0EEuXxAewssU7xI6kTWCEoD6kSlQpry3HG1FUSF9sp6kfwz7gKa1b2yPfMeA5CV5RMKaGzm820A5gywlJNaV7kR2hCS8GzopiVx2iSMiKrOBWn6CyEDUl1TsoJ-nntdxCi_VTR9p84rgGDMaAjdgZDmy7etfsIOO63EPC3jWu8U966IWDreqtxa78G2wTs-pEeGb32rkuvW_DG-U71Gg4dl_PHt_fb5WqFaxWgwYt6gbuhjbZVe_DhAp0Y1Qa4_DvP0cfT_P3hJVu8Pb8-3C8yzVkRM9FUiiqqdW2YYFoXec2I0TnlVc0FK4ViuuRGV5wXuiG1IaahoqqJMWJGC8rP0fXYd-vd15D2lxs3-D6NlCwXhPCcFGVK0TGlvQvBg5Fbbzvl95ISebAuNzJZlwfrcrSemLuRgfT9nQUvg7aQtm-sT2Jk4-w_9C9hnoyH</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2470034058</pqid></control><display><type>article</type><title>Investigating the effect of electrolyte types with various ionic liquids on the electrochromic performance of PEDOT:PSS based LbL multilayers</title><source>Access via ScienceDirect (Elsevier)</source><creator>Okutan, Merve ; Evecan, Dilek ; Yıldırım, Saffettin ; Özkan Zayim, Esra ; Deligöz, Hüseyin</creator><creatorcontrib>Okutan, Merve ; Evecan, Dilek ; Yıldırım, Saffettin ; Özkan Zayim, Esra ; Deligöz, Hüseyin</creatorcontrib><description>The objective of the study is to investigate the electrochromic performances of layer-by-layer (LbL) multilayered thin film electrode prepared from linear polyethylene imine (LPEI) and poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) on PET-ITO substrate in the presence of different types of electrolytes. For this purpose, the electrochromic behaviors of (LPEI/PEDOT:PSS)10 is performed in LiClO4/propylene carbonate (PC) and two different ionic liquids (IL) namely N-methylimidazolium tetrafluoroborate (Melm-BF4) and 2-hydroxy ethyl ammonium formate (2-HEAF), as a function of IL content and scanning rate. The optical contrast value of (LPEI/PEDOT:PSS)10 film is determined as 58.4% in the existence of 10 wt% of 2-HEAF as the electrolyte. The coloration efficiency of this film is determined as 606.7 cm2/C, which this value was greater approximately four times than 1 M LiClO4/PC. According to the obtained results, 2-HEAF has been evaluated as a suitable electrolyte alternative for (LPEI/PEDOT:PSS)10 film due to its better optical contrast and coloration efficiency compared to other electrolytes.
[Display omitted]
•The electrochromic properties of (LPEI/PEDOT:PSS)10 film were studied.•ILs as electrolyte were improved the coloration behavior of (LPEI/PEDOT:PSS)10 film.•2-HEAF was a good alternative as an electrolyte for LbL electrochromic electrode.•10 wt% 2-HEAF was ensured with high optical contrast as 58.4%.</description><identifier>ISSN: 0167-9317</identifier><identifier>EISSN: 1873-5568</identifier><identifier>DOI: 10.1016/j.mee.2020.111454</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>2-hydroxy ethyl ammonium formate ; Electrochromism ; Electrodes ; Electrolytes ; Ionic liquids ; LbL technique ; Lithium perchlorates ; Multilayers ; PEDOT:PSS ; PET-ITO ; Polyethylene ; Polyethylene terephthalate ; Polymers ; Polystyrene resins ; Propylene ; Substrates ; Thin films</subject><ispartof>Microelectronic engineering, 2020-10, Vol.234, p.111454, Article 111454</ispartof><rights>2020 Elsevier B.V.</rights><rights>Copyright Elsevier BV Oct 15, 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c325t-7d9a1a1ccbf272cc54b20fc4139b37287a2c83fc9335cd0bf0fd179b0ff761513</citedby><cites>FETCH-LOGICAL-c325t-7d9a1a1ccbf272cc54b20fc4139b37287a2c83fc9335cd0bf0fd179b0ff761513</cites><orcidid>0000-0002-3110-0675 ; 0000-0001-5887-0293 ; 0000-0002-0915-2911</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.mee.2020.111454$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Okutan, Merve</creatorcontrib><creatorcontrib>Evecan, Dilek</creatorcontrib><creatorcontrib>Yıldırım, Saffettin</creatorcontrib><creatorcontrib>Özkan Zayim, Esra</creatorcontrib><creatorcontrib>Deligöz, Hüseyin</creatorcontrib><title>Investigating the effect of electrolyte types with various ionic liquids on the electrochromic performance of PEDOT:PSS based LbL multilayers</title><title>Microelectronic engineering</title><description>The objective of the study is to investigate the electrochromic performances of layer-by-layer (LbL) multilayered thin film electrode prepared from linear polyethylene imine (LPEI) and poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) on PET-ITO substrate in the presence of different types of electrolytes. For this purpose, the electrochromic behaviors of (LPEI/PEDOT:PSS)10 is performed in LiClO4/propylene carbonate (PC) and two different ionic liquids (IL) namely N-methylimidazolium tetrafluoroborate (Melm-BF4) and 2-hydroxy ethyl ammonium formate (2-HEAF), as a function of IL content and scanning rate. The optical contrast value of (LPEI/PEDOT:PSS)10 film is determined as 58.4% in the existence of 10 wt% of 2-HEAF as the electrolyte. The coloration efficiency of this film is determined as 606.7 cm2/C, which this value was greater approximately four times than 1 M LiClO4/PC. According to the obtained results, 2-HEAF has been evaluated as a suitable electrolyte alternative for (LPEI/PEDOT:PSS)10 film due to its better optical contrast and coloration efficiency compared to other electrolytes.
[Display omitted]
•The electrochromic properties of (LPEI/PEDOT:PSS)10 film were studied.•ILs as electrolyte were improved the coloration behavior of (LPEI/PEDOT:PSS)10 film.•2-HEAF was a good alternative as an electrolyte for LbL electrochromic electrode.•10 wt% 2-HEAF was ensured with high optical contrast as 58.4%.</description><subject>2-hydroxy ethyl ammonium formate</subject><subject>Electrochromism</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Ionic liquids</subject><subject>LbL technique</subject><subject>Lithium perchlorates</subject><subject>Multilayers</subject><subject>PEDOT:PSS</subject><subject>PET-ITO</subject><subject>Polyethylene</subject><subject>Polyethylene terephthalate</subject><subject>Polymers</subject><subject>Polystyrene resins</subject><subject>Propylene</subject><subject>Substrates</subject><subject>Thin films</subject><issn>0167-9317</issn><issn>1873-5568</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EEuXxAewssU7xI6kTWCEoD6kSlQpry3HG1FUSF9sp6kfwz7gKa1b2yPfMeA5CV5RMKaGzm820A5gywlJNaV7kR2hCS8GzopiVx2iSMiKrOBWn6CyEDUl1TsoJ-nntdxCi_VTR9p84rgGDMaAjdgZDmy7etfsIOO63EPC3jWu8U966IWDreqtxa78G2wTs-pEeGb32rkuvW_DG-U71Gg4dl_PHt_fb5WqFaxWgwYt6gbuhjbZVe_DhAp0Y1Qa4_DvP0cfT_P3hJVu8Pb8-3C8yzVkRM9FUiiqqdW2YYFoXec2I0TnlVc0FK4ViuuRGV5wXuiG1IaahoqqJMWJGC8rP0fXYd-vd15D2lxs3-D6NlCwXhPCcFGVK0TGlvQvBg5Fbbzvl95ISebAuNzJZlwfrcrSemLuRgfT9nQUvg7aQtm-sT2Jk4-w_9C9hnoyH</recordid><startdate>20201015</startdate><enddate>20201015</enddate><creator>Okutan, Merve</creator><creator>Evecan, Dilek</creator><creator>Yıldırım, Saffettin</creator><creator>Özkan Zayim, Esra</creator><creator>Deligöz, Hüseyin</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-3110-0675</orcidid><orcidid>https://orcid.org/0000-0001-5887-0293</orcidid><orcidid>https://orcid.org/0000-0002-0915-2911</orcidid></search><sort><creationdate>20201015</creationdate><title>Investigating the effect of electrolyte types with various ionic liquids on the electrochromic performance of PEDOT:PSS based LbL multilayers</title><author>Okutan, Merve ; Evecan, Dilek ; Yıldırım, Saffettin ; Özkan Zayim, Esra ; Deligöz, Hüseyin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c325t-7d9a1a1ccbf272cc54b20fc4139b37287a2c83fc9335cd0bf0fd179b0ff761513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>2-hydroxy ethyl ammonium formate</topic><topic>Electrochromism</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Ionic liquids</topic><topic>LbL technique</topic><topic>Lithium perchlorates</topic><topic>Multilayers</topic><topic>PEDOT:PSS</topic><topic>PET-ITO</topic><topic>Polyethylene</topic><topic>Polyethylene terephthalate</topic><topic>Polymers</topic><topic>Polystyrene resins</topic><topic>Propylene</topic><topic>Substrates</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Okutan, Merve</creatorcontrib><creatorcontrib>Evecan, Dilek</creatorcontrib><creatorcontrib>Yıldırım, Saffettin</creatorcontrib><creatorcontrib>Özkan Zayim, Esra</creatorcontrib><creatorcontrib>Deligöz, Hüseyin</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Microelectronic engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Okutan, Merve</au><au>Evecan, Dilek</au><au>Yıldırım, Saffettin</au><au>Özkan Zayim, Esra</au><au>Deligöz, Hüseyin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigating the effect of electrolyte types with various ionic liquids on the electrochromic performance of PEDOT:PSS based LbL multilayers</atitle><jtitle>Microelectronic engineering</jtitle><date>2020-10-15</date><risdate>2020</risdate><volume>234</volume><spage>111454</spage><pages>111454-</pages><artnum>111454</artnum><issn>0167-9317</issn><eissn>1873-5568</eissn><abstract>The objective of the study is to investigate the electrochromic performances of layer-by-layer (LbL) multilayered thin film electrode prepared from linear polyethylene imine (LPEI) and poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) on PET-ITO substrate in the presence of different types of electrolytes. For this purpose, the electrochromic behaviors of (LPEI/PEDOT:PSS)10 is performed in LiClO4/propylene carbonate (PC) and two different ionic liquids (IL) namely N-methylimidazolium tetrafluoroborate (Melm-BF4) and 2-hydroxy ethyl ammonium formate (2-HEAF), as a function of IL content and scanning rate. The optical contrast value of (LPEI/PEDOT:PSS)10 film is determined as 58.4% in the existence of 10 wt% of 2-HEAF as the electrolyte. The coloration efficiency of this film is determined as 606.7 cm2/C, which this value was greater approximately four times than 1 M LiClO4/PC. According to the obtained results, 2-HEAF has been evaluated as a suitable electrolyte alternative for (LPEI/PEDOT:PSS)10 film due to its better optical contrast and coloration efficiency compared to other electrolytes.
[Display omitted]
•The electrochromic properties of (LPEI/PEDOT:PSS)10 film were studied.•ILs as electrolyte were improved the coloration behavior of (LPEI/PEDOT:PSS)10 film.•2-HEAF was a good alternative as an electrolyte for LbL electrochromic electrode.•10 wt% 2-HEAF was ensured with high optical contrast as 58.4%.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.mee.2020.111454</doi><orcidid>https://orcid.org/0000-0002-3110-0675</orcidid><orcidid>https://orcid.org/0000-0001-5887-0293</orcidid><orcidid>https://orcid.org/0000-0002-0915-2911</orcidid></addata></record> |
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| subjects | 2-hydroxy ethyl ammonium formate Electrochromism Electrodes Electrolytes Ionic liquids LbL technique Lithium perchlorates Multilayers PEDOT:PSS PET-ITO Polyethylene Polyethylene terephthalate Polymers Polystyrene resins Propylene Substrates Thin films |
| title | Investigating the effect of electrolyte types with various ionic liquids on the electrochromic performance of PEDOT:PSS based LbL multilayers |
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