Exergy and energy analysis of three biogas upgrading processes

•Three biogas upgrading processes have been successfully simulated by Aspen Plus.•Water scrubbing showed the largest exergy efficiency (94.5%).•A new model for membrane separation was successfully developed and integrated.•The exergy analysis allowed to individuate all the waste streams in the proce...

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Veröffentlicht in:Energy conversion and management 2020-11, Vol.224, p.113323, Article 113323
Hauptverfasser: Vilardi, Giorgio, Bassano, Claudia, Deiana, Paolo, Verdone, Nicola
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creator Vilardi, Giorgio
Bassano, Claudia
Deiana, Paolo
Verdone, Nicola
description •Three biogas upgrading processes have been successfully simulated by Aspen Plus.•Water scrubbing showed the largest exergy efficiency (94.5%).•A new model for membrane separation was successfully developed and integrated.•The exergy analysis allowed to individuate all the waste streams in the processes.•Membrane separation showed the highest specific energy consumption 0.94 kWh/m3 STP. The aim of this work was to provide a complete exergy and energy analysis of three biogas upgrading technologies: amine scrubbing, water scrubbing and membrane separation processes. Biogas production and treatment represents a key-process for the application of Circular Economy principles, since allows to reuse/reconvert industrial by-products or agro-industrial waste in a product that can be used in different energy demanding sectors, after proper cleaning and upgrading processes. The three technologies here reported have been implemented in Aspen Plus flowsheets, and were used to upgrade a biogas to biomethane, meeting the UNIT/TS 11537:2019 standards for Biogas to be injected in the gas grid. Each units of all the simulated processes have been analysed calculating total exergy feed, total exergy produced and exergy loss, distinguishing that lost for irreversibility and as waste. Water scrubbing was characterized by the highest values of exergy efficiency (94.5%) and methane recovery (99%), whereas the lowest exergy efficiency belonged to membrane separation (90.8%) that returned also the largest specific energy consumption (0.94 kWh/m3 STP). Conversely, amine scrubbing was characterized by the lowest specific energy consumption value (0.204 kWh/m3 STP) but by an exergy efficiency of 91.1%.
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The aim of this work was to provide a complete exergy and energy analysis of three biogas upgrading technologies: amine scrubbing, water scrubbing and membrane separation processes. Biogas production and treatment represents a key-process for the application of Circular Economy principles, since allows to reuse/reconvert industrial by-products or agro-industrial waste in a product that can be used in different energy demanding sectors, after proper cleaning and upgrading processes. The three technologies here reported have been implemented in Aspen Plus flowsheets, and were used to upgrade a biogas to biomethane, meeting the UNIT/TS 11537:2019 standards for Biogas to be injected in the gas grid. Each units of all the simulated processes have been analysed calculating total exergy feed, total exergy produced and exergy loss, distinguishing that lost for irreversibility and as waste. Water scrubbing was characterized by the highest values of exergy efficiency (94.5%) and methane recovery (99%), whereas the lowest exergy efficiency belonged to membrane separation (90.8%) that returned also the largest specific energy consumption (0.94 kWh/m3 STP). 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subjects Agricultural wastes
Aspen
Biogas
Economic conditions
Efficiency
Energy consumption
Exergy
Exergy-analysis
Industrial wastes
Irreversibility
Membrane separation
Membranes
Plant-design
Separation
Separation processes
Thermodynamics
Upgrading
Washing
title Exergy and energy analysis of three biogas upgrading processes
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