Discovering positively charged Pt for enhanced hydrogenolysis of glycerol to 1,3-propanediol
Atomically-dispersed Pt supported on WO x -modified tantalum oxide was developed as a highly active catalyst for selective hydrogenolysis of glycerol, with the productivity of 30.80 g g Pt −1 h −1 toward 1,3-propanediol. The WO x species pre-deposited on T -Ta 2 O 5 were found to assist the atomic d...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2020-12, Vol.22 (23), p.8254-8259 |
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| container_title | Green chemistry : an international journal and green chemistry resource : GC |
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| creator | Zhao, Binbin Liang, Yu Liu, Lei He, Qian Dong, Jinxiang |
| description | Atomically-dispersed Pt supported on WO
x
-modified tantalum oxide was developed as a highly active catalyst for selective hydrogenolysis of glycerol, with the productivity of 30.80 g g
Pt
−1
h
−1
toward 1,3-propanediol. The WO
x
species pre-deposited on
T
-Ta
2
O
5
were found to assist the atomic dispersion of platinum. The WO
x
-stabilized Pt
δ
+
species adsorb hydrogen easily and facilitate the hydrogen heterolytic dissociation, which significantly enhances the capability of
in situ
generated Brønsted acid sites and the hydrogenation activity. This provides a new strategy for developing bi-functional catalysts for a broad range of hydrogen and acid-involved reaction.
WO
x
-stabilized Pt
δ
+
species in atomic-level dispersion on tantalum oxide exhibiting a remarkable catalytic performance for glycerol hydrogenolysis to 1,3-PDO. |
| doi_str_mv | 10.1039/d0gc03364b |
| format | Article |
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x
-modified tantalum oxide was developed as a highly active catalyst for selective hydrogenolysis of glycerol, with the productivity of 30.80 g g
Pt
−1
h
−1
toward 1,3-propanediol. The WO
x
species pre-deposited on
T
-Ta
2
O
5
were found to assist the atomic dispersion of platinum. The WO
x
-stabilized Pt
δ
+
species adsorb hydrogen easily and facilitate the hydrogen heterolytic dissociation, which significantly enhances the capability of
in situ
generated Brønsted acid sites and the hydrogenation activity. This provides a new strategy for developing bi-functional catalysts for a broad range of hydrogen and acid-involved reaction.
WO
x
-stabilized Pt
δ
+
species in atomic-level dispersion on tantalum oxide exhibiting a remarkable catalytic performance for glycerol hydrogenolysis to 1,3-PDO.</description><identifier>ISSN: 1463-9262</identifier><identifier>EISSN: 1463-9270</identifier><identifier>DOI: 10.1039/d0gc03364b</identifier><language>eng</language><publisher>CAMBRIDGE: Royal Soc Chemistry</publisher><subject>1,3-Propanediol ; Catalysts ; Chemistry ; Chemistry, Multidisciplinary ; Dispersion ; Glycerol ; Green & Sustainable Science & Technology ; Green chemistry ; Hydrogen ; Hydrogen storage ; Hydrogenolysis ; Physical Sciences ; Platinum ; Science & Technology ; Science & Technology - Other Topics ; Tantalum ; Tantalum oxides</subject><ispartof>Green chemistry : an international journal and green chemistry resource : GC, 2020-12, Vol.22 (23), p.8254-8259</ispartof><rights>Copyright Royal Society of Chemistry 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>34</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000599653300012</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c384t-b3badfa2a7327c1a5126ae0f39f2ac278e1d76777a9a2d9e3ee414b8bcb563343</citedby><cites>FETCH-LOGICAL-c384t-b3badfa2a7327c1a5126ae0f39f2ac278e1d76777a9a2d9e3ee414b8bcb563343</cites><orcidid>0000-0001-5623-3514 ; 0000-0003-4891-3581 ; 0000-0003-2027-4271</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,782,786,27933,27934,28257</link.rule.ids></links><search><creatorcontrib>Zhao, Binbin</creatorcontrib><creatorcontrib>Liang, Yu</creatorcontrib><creatorcontrib>Liu, Lei</creatorcontrib><creatorcontrib>He, Qian</creatorcontrib><creatorcontrib>Dong, Jinxiang</creatorcontrib><title>Discovering positively charged Pt for enhanced hydrogenolysis of glycerol to 1,3-propanediol</title><title>Green chemistry : an international journal and green chemistry resource : GC</title><addtitle>GREEN CHEM</addtitle><description>Atomically-dispersed Pt supported on WO
x
-modified tantalum oxide was developed as a highly active catalyst for selective hydrogenolysis of glycerol, with the productivity of 30.80 g g
Pt
−1
h
−1
toward 1,3-propanediol. The WO
x
species pre-deposited on
T
-Ta
2
O
5
were found to assist the atomic dispersion of platinum. The WO
x
-stabilized Pt
δ
+
species adsorb hydrogen easily and facilitate the hydrogen heterolytic dissociation, which significantly enhances the capability of
in situ
generated Brønsted acid sites and the hydrogenation activity. This provides a new strategy for developing bi-functional catalysts for a broad range of hydrogen and acid-involved reaction.
WO
x
-stabilized Pt
δ
+
species in atomic-level dispersion on tantalum oxide exhibiting a remarkable catalytic performance for glycerol hydrogenolysis to 1,3-PDO.</description><subject>1,3-Propanediol</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry, Multidisciplinary</subject><subject>Dispersion</subject><subject>Glycerol</subject><subject>Green & Sustainable Science & Technology</subject><subject>Green chemistry</subject><subject>Hydrogen</subject><subject>Hydrogen storage</subject><subject>Hydrogenolysis</subject><subject>Physical Sciences</subject><subject>Platinum</subject><subject>Science & Technology</subject><subject>Science & Technology - Other Topics</subject><subject>Tantalum</subject><subject>Tantalum oxides</subject><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNkUFLxDAQhYsouK5evAsBb2o1yXST9qhdXYUFPehNKGk67UZqsybdlf57oyvr1dO8ge_NMG-i6JjRS0Yhu6pooymASMqdaMQSAXHGJd3dasH3owPv3yhlTIpkFL1Ojdd2jc50DVlab3qzxnYgeqFcgxV56kltHcFuoTod-sVQOdtgZ9vBG09sTZp20OhsS3pL2AXES2eXqsPK2PYw2qtV6_Hot46jl7vb5_w-nj_OHvLreawhTfq4hFJVteJKApeaqQnjQiGtIau50lymyCoppJQqU7zKEBATlpRpqcuJAEhgHJ1u5obdHyv0ffFmV64LKwueiBRoyAACdbahtLPeO6yLpTPvyg0Fo8V3esWUzvKf9G4CnG7gTyxt7bXBcP7WQCmdZJmYAATFeG561Rvb5XbV9cF6_n9roE82tPN6C_29Eb4A2VuNag</recordid><startdate>20201207</startdate><enddate>20201207</enddate><creator>Zhao, Binbin</creator><creator>Liang, Yu</creator><creator>Liu, Lei</creator><creator>He, Qian</creator><creator>Dong, Jinxiang</creator><general>Royal Soc Chemistry</general><general>Royal Society of Chemistry</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7ST</scope><scope>7U6</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-5623-3514</orcidid><orcidid>https://orcid.org/0000-0003-4891-3581</orcidid><orcidid>https://orcid.org/0000-0003-2027-4271</orcidid></search><sort><creationdate>20201207</creationdate><title>Discovering positively charged Pt for enhanced hydrogenolysis of glycerol to 1,3-propanediol</title><author>Zhao, Binbin ; Liang, Yu ; Liu, Lei ; He, Qian ; Dong, Jinxiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c384t-b3badfa2a7327c1a5126ae0f39f2ac278e1d76777a9a2d9e3ee414b8bcb563343</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>1,3-Propanediol</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry, Multidisciplinary</topic><topic>Dispersion</topic><topic>Glycerol</topic><topic>Green & Sustainable Science & Technology</topic><topic>Green chemistry</topic><topic>Hydrogen</topic><topic>Hydrogen storage</topic><topic>Hydrogenolysis</topic><topic>Physical Sciences</topic><topic>Platinum</topic><topic>Science & Technology</topic><topic>Science & Technology - Other Topics</topic><topic>Tantalum</topic><topic>Tantalum oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Binbin</creatorcontrib><creatorcontrib>Liang, Yu</creatorcontrib><creatorcontrib>Liu, Lei</creatorcontrib><creatorcontrib>He, Qian</creatorcontrib><creatorcontrib>Dong, Jinxiang</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Binbin</au><au>Liang, Yu</au><au>Liu, Lei</au><au>He, Qian</au><au>Dong, Jinxiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Discovering positively charged Pt for enhanced hydrogenolysis of glycerol to 1,3-propanediol</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><stitle>GREEN CHEM</stitle><date>2020-12-07</date><risdate>2020</risdate><volume>22</volume><issue>23</issue><spage>8254</spage><epage>8259</epage><pages>8254-8259</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>Atomically-dispersed Pt supported on WO
x
-modified tantalum oxide was developed as a highly active catalyst for selective hydrogenolysis of glycerol, with the productivity of 30.80 g g
Pt
−1
h
−1
toward 1,3-propanediol. The WO
x
species pre-deposited on
T
-Ta
2
O
5
were found to assist the atomic dispersion of platinum. The WO
x
-stabilized Pt
δ
+
species adsorb hydrogen easily and facilitate the hydrogen heterolytic dissociation, which significantly enhances the capability of
in situ
generated Brønsted acid sites and the hydrogenation activity. This provides a new strategy for developing bi-functional catalysts for a broad range of hydrogen and acid-involved reaction.
WO
x
-stabilized Pt
δ
+
species in atomic-level dispersion on tantalum oxide exhibiting a remarkable catalytic performance for glycerol hydrogenolysis to 1,3-PDO.</abstract><cop>CAMBRIDGE</cop><pub>Royal Soc Chemistry</pub><doi>10.1039/d0gc03364b</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-5623-3514</orcidid><orcidid>https://orcid.org/0000-0003-4891-3581</orcidid><orcidid>https://orcid.org/0000-0003-2027-4271</orcidid></addata></record> |
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| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2020-12, Vol.22 (23), p.8254-8259 |
| issn | 1463-9262 1463-9270 |
| language | eng |
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| source | Royal Society Of Chemistry Journals; Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" />; Alma/SFX Local Collection |
| subjects | 1,3-Propanediol Catalysts Chemistry Chemistry, Multidisciplinary Dispersion Glycerol Green & Sustainable Science & Technology Green chemistry Hydrogen Hydrogen storage Hydrogenolysis Physical Sciences Platinum Science & Technology Science & Technology - Other Topics Tantalum Tantalum oxides |
| title | Discovering positively charged Pt for enhanced hydrogenolysis of glycerol to 1,3-propanediol |
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