From Disposal to Reuse: Production of Sustainable Fatty Acid Alkyl Esters Derived from Residual Oil Using a Biphasic Magnetic Catalyst
The development of technologies to promote residual oil reuse has been encouraged, aiming to reduce the environmental impact and promote sustainability. In this study, a biphasic magnetic catalyst with composition equal to ZnO-Ni0.5Zn0.5Fe2O4 was synthesized and applied to the fatty acid alkyl ester...
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| Veröffentlicht in: | Sustainability 2020-12, Vol.12 (23), p.10159 |
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| creator | da Silva, Adriano Lima Luna, Carlos Bruno Barreto de Farias, Ana Flávia Félix de Medeiros, Suelen Alves Silva Lucena Meneghetti, Simoni Margareti Plentz Rodrigues, Alisson Mendes Costa, Ana Cristina Figueiredo de Melo |
| description | The development of technologies to promote residual oil reuse has been encouraged, aiming to reduce the environmental impact and promote sustainability. In this study, a biphasic magnetic catalyst with composition equal to ZnO-Ni0.5Zn0.5Fe2O4 was synthesized and applied to the fatty acid alkyl ester (FAAE) production from residual oil. The ZnO-Ni0.5Zn0.5Fe2O4 catalyst was synthesized by combustion reaction and characterized by X-ray diffraction (XRD), textural analysis, Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, thermogravimetry, particle size distribution, scanning electron microscopy, magnetic measurements, quantification of acidic sites by TPD-NH3, and catalytic tests. The efficiency of catalyst synthesis was evaluated by XRD, FTIR, and Raman spectroscopy experiments. Granulometric analysis and SEM images confirmed the presence of the agglomerates and particles with a wide size range. The catalyst presented soft magnetic behavior, with high saturation magnetization. Additionally, the catalytic activity of the ZnO-Ni0.5Zn0.5Fe2O4 system showed an average conversion of 73% for the methyl route. The results indicate that the reuse of residual oil is feasible for FAAE production, contributing to sustainable fuel development. Moreover, it allows the reintroduction of waste oil into the biodiesel production chain, reducing cost after process optimization. |
| doi_str_mv | 10.3390/su122310159 |
| format | Article |
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In this study, a biphasic magnetic catalyst with composition equal to ZnO-Ni0.5Zn0.5Fe2O4 was synthesized and applied to the fatty acid alkyl ester (FAAE) production from residual oil. The ZnO-Ni0.5Zn0.5Fe2O4 catalyst was synthesized by combustion reaction and characterized by X-ray diffraction (XRD), textural analysis, Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, thermogravimetry, particle size distribution, scanning electron microscopy, magnetic measurements, quantification of acidic sites by TPD-NH3, and catalytic tests. The efficiency of catalyst synthesis was evaluated by XRD, FTIR, and Raman spectroscopy experiments. Granulometric analysis and SEM images confirmed the presence of the agglomerates and particles with a wide size range. The catalyst presented soft magnetic behavior, with high saturation magnetization. Additionally, the catalytic activity of the ZnO-Ni0.5Zn0.5Fe2O4 system showed an average conversion of 73% for the methyl route. The results indicate that the reuse of residual oil is feasible for FAAE production, contributing to sustainable fuel development. Moreover, it allows the reintroduction of waste oil into the biodiesel production chain, reducing cost after process optimization.</description><identifier>ISSN: 2071-1050</identifier><identifier>EISSN: 2071-1050</identifier><identifier>DOI: 10.3390/su122310159</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Alcohol ; Ammonia ; Biodiesel fuels ; Biofuels ; Catalysts ; Catalytic activity ; Catalytic converters ; Esters ; Fatty acids ; Fourier analysis ; Fourier transforms ; Infrared analysis ; Infrared spectroscopy ; Magnetic measurement ; Magnetic properties ; Magnetic saturation ; Nitrates ; Oil wastes ; Optimization ; Particle size distribution ; Production capacity ; Raman spectroscopy ; Raw materials ; Reagents ; Reintroduction ; Scanning electron microscopy ; Size distribution ; Spectroscopic analysis ; Sustainability ; Sustainable development ; Thermogravimetry ; Vegetable oils ; Waste disposal ; X-ray diffraction ; Zinc oxide</subject><ispartof>Sustainability, 2020-12, Vol.12 (23), p.10159</ispartof><rights>2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). 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The results indicate that the reuse of residual oil is feasible for FAAE production, contributing to sustainable fuel development. Moreover, it allows the reintroduction of waste oil into the biodiesel production chain, reducing cost after process optimization.</description><subject>Alcohol</subject><subject>Ammonia</subject><subject>Biodiesel fuels</subject><subject>Biofuels</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Catalytic converters</subject><subject>Esters</subject><subject>Fatty acids</subject><subject>Fourier analysis</subject><subject>Fourier transforms</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Magnetic measurement</subject><subject>Magnetic properties</subject><subject>Magnetic saturation</subject><subject>Nitrates</subject><subject>Oil wastes</subject><subject>Optimization</subject><subject>Particle size distribution</subject><subject>Production capacity</subject><subject>Raman spectroscopy</subject><subject>Raw materials</subject><subject>Reagents</subject><subject>Reintroduction</subject><subject>Scanning electron microscopy</subject><subject>Size distribution</subject><subject>Spectroscopic analysis</subject><subject>Sustainability</subject><subject>Sustainable development</subject><subject>Thermogravimetry</subject><subject>Vegetable oils</subject><subject>Waste disposal</subject><subject>X-ray diffraction</subject><subject>Zinc oxide</subject><issn>2071-1050</issn><issn>2071-1050</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpNkE1Lw0AYhIMoWGpP_oEFjxLdj2Sz8Vb7oUKlUu05bJM3dWuajftuhPwBf7cp9dC5zByGZ2CC4JrROyFSeo8t41wwyuL0LBhwmrCQ0Zien-TLYIS4o72EYCmTg-B37uyeTA02FnVFvCUraBEeyJuzRZt7Y2tiS_Leotem1psKyFx735Fxbgoyrr66iszQg0MyBWd-oCDlgbgCNEXbE5emIms09ZZo8miaT40mJ696W4Pvw0R7XXXor4KLUlcIo38fBuv57GPyHC6WTy-T8SLMeap8qAUvKItiAVTJEmQRi4iWhWQRExFPBE2kgqRUIDmojRYlVxFsIgVC0ijRUgyDmyO3cfa7BfTZzrau7iczHklFVdyD-9btsZU7i-igzBpn9tp1GaPZ4evs5GvxB0bCcJk</recordid><startdate>20201201</startdate><enddate>20201201</enddate><creator>da Silva, Adriano Lima</creator><creator>Luna, Carlos Bruno Barreto</creator><creator>de Farias, Ana Flávia Félix</creator><creator>de Medeiros, Suelen Alves Silva Lucena</creator><creator>Meneghetti, Simoni Margareti Plentz</creator><creator>Rodrigues, Alisson Mendes</creator><creator>Costa, Ana Cristina Figueiredo de Melo</creator><general>MDPI AG</general><scope>AAYXX</scope><scope>CITATION</scope><scope>4U-</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0001-6623-8183</orcidid><orcidid>https://orcid.org/0000-0003-0449-9219</orcidid><orcidid>https://orcid.org/0000-0002-2441-7439</orcidid><orcidid>https://orcid.org/0000-0003-3485-7769</orcidid><orcidid>https://orcid.org/0000-0003-3841-2839</orcidid></search><sort><creationdate>20201201</creationdate><title>From Disposal to Reuse: Production of Sustainable Fatty Acid Alkyl Esters Derived from Residual Oil Using a Biphasic Magnetic Catalyst</title><author>da Silva, Adriano Lima ; Luna, Carlos Bruno Barreto ; de Farias, Ana Flávia Félix ; de Medeiros, Suelen Alves Silva Lucena ; Meneghetti, Simoni Margareti Plentz ; Rodrigues, Alisson Mendes ; Costa, Ana Cristina Figueiredo de Melo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c298t-a32d01453e086fe6d5340fd6141342730768e7f8e62e8ba3f284eb48e36047a63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Alcohol</topic><topic>Ammonia</topic><topic>Biodiesel fuels</topic><topic>Biofuels</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Catalytic converters</topic><topic>Esters</topic><topic>Fatty acids</topic><topic>Fourier analysis</topic><topic>Fourier transforms</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Magnetic measurement</topic><topic>Magnetic properties</topic><topic>Magnetic saturation</topic><topic>Nitrates</topic><topic>Oil wastes</topic><topic>Optimization</topic><topic>Particle size distribution</topic><topic>Production capacity</topic><topic>Raman spectroscopy</topic><topic>Raw materials</topic><topic>Reagents</topic><topic>Reintroduction</topic><topic>Scanning electron microscopy</topic><topic>Size distribution</topic><topic>Spectroscopic analysis</topic><topic>Sustainability</topic><topic>Sustainable development</topic><topic>Thermogravimetry</topic><topic>Vegetable oils</topic><topic>Waste disposal</topic><topic>X-ray diffraction</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>da Silva, Adriano Lima</creatorcontrib><creatorcontrib>Luna, Carlos Bruno Barreto</creatorcontrib><creatorcontrib>de Farias, Ana Flávia Félix</creatorcontrib><creatorcontrib>de Medeiros, Suelen Alves Silva Lucena</creatorcontrib><creatorcontrib>Meneghetti, Simoni Margareti Plentz</creatorcontrib><creatorcontrib>Rodrigues, Alisson Mendes</creatorcontrib><creatorcontrib>Costa, Ana Cristina Figueiredo de Melo</creatorcontrib><collection>CrossRef</collection><collection>University Readers</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>da Silva, Adriano Lima</au><au>Luna, Carlos Bruno Barreto</au><au>de Farias, Ana Flávia Félix</au><au>de Medeiros, Suelen Alves Silva Lucena</au><au>Meneghetti, Simoni Margareti Plentz</au><au>Rodrigues, Alisson Mendes</au><au>Costa, Ana Cristina Figueiredo de Melo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>From Disposal to Reuse: Production of Sustainable Fatty Acid Alkyl Esters Derived from Residual Oil Using a Biphasic Magnetic Catalyst</atitle><jtitle>Sustainability</jtitle><date>2020-12-01</date><risdate>2020</risdate><volume>12</volume><issue>23</issue><spage>10159</spage><pages>10159-</pages><issn>2071-1050</issn><eissn>2071-1050</eissn><abstract>The development of technologies to promote residual oil reuse has been encouraged, aiming to reduce the environmental impact and promote sustainability. In this study, a biphasic magnetic catalyst with composition equal to ZnO-Ni0.5Zn0.5Fe2O4 was synthesized and applied to the fatty acid alkyl ester (FAAE) production from residual oil. The ZnO-Ni0.5Zn0.5Fe2O4 catalyst was synthesized by combustion reaction and characterized by X-ray diffraction (XRD), textural analysis, Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, thermogravimetry, particle size distribution, scanning electron microscopy, magnetic measurements, quantification of acidic sites by TPD-NH3, and catalytic tests. The efficiency of catalyst synthesis was evaluated by XRD, FTIR, and Raman spectroscopy experiments. Granulometric analysis and SEM images confirmed the presence of the agglomerates and particles with a wide size range. The catalyst presented soft magnetic behavior, with high saturation magnetization. Additionally, the catalytic activity of the ZnO-Ni0.5Zn0.5Fe2O4 system showed an average conversion of 73% for the methyl route. The results indicate that the reuse of residual oil is feasible for FAAE production, contributing to sustainable fuel development. Moreover, it allows the reintroduction of waste oil into the biodiesel production chain, reducing cost after process optimization.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/su122310159</doi><orcidid>https://orcid.org/0000-0001-6623-8183</orcidid><orcidid>https://orcid.org/0000-0003-0449-9219</orcidid><orcidid>https://orcid.org/0000-0002-2441-7439</orcidid><orcidid>https://orcid.org/0000-0003-3485-7769</orcidid><orcidid>https://orcid.org/0000-0003-3841-2839</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; MDPI - Multidisciplinary Digital Publishing Institute |
| subjects | Alcohol Ammonia Biodiesel fuels Biofuels Catalysts Catalytic activity Catalytic converters Esters Fatty acids Fourier analysis Fourier transforms Infrared analysis Infrared spectroscopy Magnetic measurement Magnetic properties Magnetic saturation Nitrates Oil wastes Optimization Particle size distribution Production capacity Raman spectroscopy Raw materials Reagents Reintroduction Scanning electron microscopy Size distribution Spectroscopic analysis Sustainability Sustainable development Thermogravimetry Vegetable oils Waste disposal X-ray diffraction Zinc oxide |
| title | From Disposal to Reuse: Production of Sustainable Fatty Acid Alkyl Esters Derived from Residual Oil Using a Biphasic Magnetic Catalyst |
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