Asymmetric Fluorination Reactions promoted by Chiral Hydrogen Bonding‐based Organocatalysts
Fluorinated compounds can exhibit interesting biological properties. The importance of these species has made that the chemistry of fluorine has experienced a great development. On this review, the recent advances on asymmetric fluorination reactions promoted by chiral hydrogen bonding‐based organoc...
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| Veröffentlicht in: | Advanced synthesis & catalysis 2020-12, Vol.362 (23), p.5275-5300 |
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| container_title | Advanced synthesis & catalysis |
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| creator | Auria‐Luna, Fernando Mohammadi, Somayeh Divar, Masoumeh Gimeno, M. Concepción Herrera, Raquel P. |
| description | Fluorinated compounds can exhibit interesting biological properties. The importance of these species has made that the chemistry of fluorine has experienced a great development. On this review, the recent advances on asymmetric fluorination reactions promoted by chiral hydrogen bonding‐based organocatalysts are discussed. Hence, examples using phosphoric acid, carboxylic acid, (thio)urea and squaramide derivatives are illustrated. The growth of this field is amazing. We have only considered pivotal works in which direct fluorination takes place using a fluorinating agent, leaving aside the reactions where a fluorine atom is incorporated from the beginning as part of other reactants. Herein, the scarce existing examples on this field of research have been compiled. |
| doi_str_mv | 10.1002/adsc.202000848 |
| format | Article |
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| subjects | (thio)urea Asymmetry Biological properties Carboxylic acids Chemical bonds Fluorination Fluorine Hydrogen bonding hydrogen-bond organocatalysis Phosphoric acid squaramide |
| title | Asymmetric Fluorination Reactions promoted by Chiral Hydrogen Bonding‐based Organocatalysts |
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