Tris(dicyclohexylamido) Group 4 Metal Allyl and Phenylacetylide Complexes – Synthesis and Characterization
The synthesis and characterization of organyl complexes derived from group 4 metal dicyclohexylamido complexes (Cy2N)3MCl (Cy: Cyclohexyl, M = Ti, Zr, Hf 1‐M) is presented. The allyl Grignard reagent is used to obtain the corresponding group 4 allyl complexes 2‐M, and lithium phenylacetylide is used...
Gespeichert in:
| Veröffentlicht in: | European journal of inorganic chemistry 2020-12, Vol.2020 (45), p.4247-4253 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4253 |
|---|---|
| container_issue | 45 |
| container_start_page | 4247 |
| container_title | European journal of inorganic chemistry |
| container_volume | 2020 |
| creator | Frerichs, Nils Lukas, Lenard Schmidtmann, Marc Beckhaus, Rüdiger |
| description | The synthesis and characterization of organyl complexes derived from group 4 metal dicyclohexylamido complexes (Cy2N)3MCl (Cy: Cyclohexyl, M = Ti, Zr, Hf 1‐M) is presented. The allyl Grignard reagent is used to obtain the corresponding group 4 allyl complexes 2‐M, and lithium phenylacetylide is used to obtain the phenylacetylide complexes 3‐M. The thermal stability of complexes 2‐M and 3‐M is investigated. All complexes are characterized by NMR spectroscopy and single‐crystal X‐ray diffraction. Their molecular structures in solution and in the solid state are discussed.
The syntheses of two series of tris(dicyclohexylamido) group 4 metal organyl complexes is presented. The flexible structural behavior of allyl complexes as well as the high thermal stability, even at higher temperatures, of phenylacetylide complexes is shown. |
| doi_str_mv | 10.1002/ejic.202000682 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2467534438</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2467534438</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3122-36ea0d48e7354d00d499cb1d7b706ba179a0c561e7883a588ed9b5b38c5318593</originalsourceid><addsrcrecordid>eNqFkLFOwzAURSMEEqWwMltigSHFjp3EHquolKIikChz5Diviis3DnYqGib-gT_kS0gpgpHp3eGc-6QbBOcEjwjG0TWstBpFOMIYJzw6CAYECxHu8mGfGWUhEYwfByfer3qGYpoMArNw2l-WWnXK2Aq2nZFrXdorNHV20yCG7qGVBo2N6QySdYkeK6h7SEHbGV0Cyuy6MbAFjz7fP9BTV7cVeO2_2aySTqoWnH6Trbb1aXC0lMbD2c8dBs83k0V2G84fprNsPA8VJVEU0gQkLhmHlMasxH0UQhWkTIsUJ4UkqZBYxQmBlHMqY86hFEVcUK5iSngs6DC42Pc2zr5swLf5ym5c3b_MI5akMWWM8p4a7SnlrPcOlnnj9Fq6Lic43y2a7xbNfxftBbEXXrWB7h86n9zNsj_3C089e3U</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2467534438</pqid></control><display><type>article</type><title>Tris(dicyclohexylamido) Group 4 Metal Allyl and Phenylacetylide Complexes – Synthesis and Characterization</title><source>Access via Wiley Online Library</source><creator>Frerichs, Nils ; Lukas, Lenard ; Schmidtmann, Marc ; Beckhaus, Rüdiger</creator><creatorcontrib>Frerichs, Nils ; Lukas, Lenard ; Schmidtmann, Marc ; Beckhaus, Rüdiger</creatorcontrib><description>The synthesis and characterization of organyl complexes derived from group 4 metal dicyclohexylamido complexes (Cy2N)3MCl (Cy: Cyclohexyl, M = Ti, Zr, Hf 1‐M) is presented. The allyl Grignard reagent is used to obtain the corresponding group 4 allyl complexes 2‐M, and lithium phenylacetylide is used to obtain the phenylacetylide complexes 3‐M. The thermal stability of complexes 2‐M and 3‐M is investigated. All complexes are characterized by NMR spectroscopy and single‐crystal X‐ray diffraction. Their molecular structures in solution and in the solid state are discussed.
The syntheses of two series of tris(dicyclohexylamido) group 4 metal organyl complexes is presented. The flexible structural behavior of allyl complexes as well as the high thermal stability, even at higher temperatures, of phenylacetylide complexes is shown.</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.202000682</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Allyl ligands ; Amides ; Coordination compounds ; Crystal structure ; C–H activation ; Group 4 metals ; Inorganic chemistry ; Lithium ; Molecular structure ; NMR spectroscopy ; Phenylacetylide ligands ; Reagents ; Synthesis ; Thermal stability ; Titanium ; Zirconium</subject><ispartof>European journal of inorganic chemistry, 2020-12, Vol.2020 (45), p.4247-4253</ispartof><rights>2020 The Authors. Published by Wiley‐VCH GmbH</rights><rights>2020. This article is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c3122-36ea0d48e7354d00d499cb1d7b706ba179a0c561e7883a588ed9b5b38c5318593</cites><orcidid>0000-0003-0053-6449 ; 0000-0003-3546-5820 ; 0000-0003-3697-0378 ; 0000-0001-8026-7271</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejic.202000682$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejic.202000682$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Frerichs, Nils</creatorcontrib><creatorcontrib>Lukas, Lenard</creatorcontrib><creatorcontrib>Schmidtmann, Marc</creatorcontrib><creatorcontrib>Beckhaus, Rüdiger</creatorcontrib><title>Tris(dicyclohexylamido) Group 4 Metal Allyl and Phenylacetylide Complexes – Synthesis and Characterization</title><title>European journal of inorganic chemistry</title><description>The synthesis and characterization of organyl complexes derived from group 4 metal dicyclohexylamido complexes (Cy2N)3MCl (Cy: Cyclohexyl, M = Ti, Zr, Hf 1‐M) is presented. The allyl Grignard reagent is used to obtain the corresponding group 4 allyl complexes 2‐M, and lithium phenylacetylide is used to obtain the phenylacetylide complexes 3‐M. The thermal stability of complexes 2‐M and 3‐M is investigated. All complexes are characterized by NMR spectroscopy and single‐crystal X‐ray diffraction. Their molecular structures in solution and in the solid state are discussed.
The syntheses of two series of tris(dicyclohexylamido) group 4 metal organyl complexes is presented. The flexible structural behavior of allyl complexes as well as the high thermal stability, even at higher temperatures, of phenylacetylide complexes is shown.</description><subject>Allyl ligands</subject><subject>Amides</subject><subject>Coordination compounds</subject><subject>Crystal structure</subject><subject>C–H activation</subject><subject>Group 4 metals</subject><subject>Inorganic chemistry</subject><subject>Lithium</subject><subject>Molecular structure</subject><subject>NMR spectroscopy</subject><subject>Phenylacetylide ligands</subject><subject>Reagents</subject><subject>Synthesis</subject><subject>Thermal stability</subject><subject>Titanium</subject><subject>Zirconium</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNqFkLFOwzAURSMEEqWwMltigSHFjp3EHquolKIikChz5Diviis3DnYqGib-gT_kS0gpgpHp3eGc-6QbBOcEjwjG0TWstBpFOMIYJzw6CAYECxHu8mGfGWUhEYwfByfer3qGYpoMArNw2l-WWnXK2Aq2nZFrXdorNHV20yCG7qGVBo2N6QySdYkeK6h7SEHbGV0Cyuy6MbAFjz7fP9BTV7cVeO2_2aySTqoWnH6Trbb1aXC0lMbD2c8dBs83k0V2G84fprNsPA8VJVEU0gQkLhmHlMasxH0UQhWkTIsUJ4UkqZBYxQmBlHMqY86hFEVcUK5iSngs6DC42Pc2zr5swLf5ym5c3b_MI5akMWWM8p4a7SnlrPcOlnnj9Fq6Lic43y2a7xbNfxftBbEXXrWB7h86n9zNsj_3C089e3U</recordid><startdate>20201207</startdate><enddate>20201207</enddate><creator>Frerichs, Nils</creator><creator>Lukas, Lenard</creator><creator>Schmidtmann, Marc</creator><creator>Beckhaus, Rüdiger</creator><general>Wiley Subscription Services, Inc</general><scope>24P</scope><scope>WIN</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-0053-6449</orcidid><orcidid>https://orcid.org/0000-0003-3546-5820</orcidid><orcidid>https://orcid.org/0000-0003-3697-0378</orcidid><orcidid>https://orcid.org/0000-0001-8026-7271</orcidid></search><sort><creationdate>20201207</creationdate><title>Tris(dicyclohexylamido) Group 4 Metal Allyl and Phenylacetylide Complexes – Synthesis and Characterization</title><author>Frerichs, Nils ; Lukas, Lenard ; Schmidtmann, Marc ; Beckhaus, Rüdiger</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3122-36ea0d48e7354d00d499cb1d7b706ba179a0c561e7883a588ed9b5b38c5318593</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Allyl ligands</topic><topic>Amides</topic><topic>Coordination compounds</topic><topic>Crystal structure</topic><topic>C–H activation</topic><topic>Group 4 metals</topic><topic>Inorganic chemistry</topic><topic>Lithium</topic><topic>Molecular structure</topic><topic>NMR spectroscopy</topic><topic>Phenylacetylide ligands</topic><topic>Reagents</topic><topic>Synthesis</topic><topic>Thermal stability</topic><topic>Titanium</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Frerichs, Nils</creatorcontrib><creatorcontrib>Lukas, Lenard</creatorcontrib><creatorcontrib>Schmidtmann, Marc</creatorcontrib><creatorcontrib>Beckhaus, Rüdiger</creatorcontrib><collection>Wiley Online Library Open Access</collection><collection>Wiley Online Library Free Content</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Frerichs, Nils</au><au>Lukas, Lenard</au><au>Schmidtmann, Marc</au><au>Beckhaus, Rüdiger</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tris(dicyclohexylamido) Group 4 Metal Allyl and Phenylacetylide Complexes – Synthesis and Characterization</atitle><jtitle>European journal of inorganic chemistry</jtitle><date>2020-12-07</date><risdate>2020</risdate><volume>2020</volume><issue>45</issue><spage>4247</spage><epage>4253</epage><pages>4247-4253</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>The synthesis and characterization of organyl complexes derived from group 4 metal dicyclohexylamido complexes (Cy2N)3MCl (Cy: Cyclohexyl, M = Ti, Zr, Hf 1‐M) is presented. The allyl Grignard reagent is used to obtain the corresponding group 4 allyl complexes 2‐M, and lithium phenylacetylide is used to obtain the phenylacetylide complexes 3‐M. The thermal stability of complexes 2‐M and 3‐M is investigated. All complexes are characterized by NMR spectroscopy and single‐crystal X‐ray diffraction. Their molecular structures in solution and in the solid state are discussed.
The syntheses of two series of tris(dicyclohexylamido) group 4 metal organyl complexes is presented. The flexible structural behavior of allyl complexes as well as the high thermal stability, even at higher temperatures, of phenylacetylide complexes is shown.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ejic.202000682</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-0053-6449</orcidid><orcidid>https://orcid.org/0000-0003-3546-5820</orcidid><orcidid>https://orcid.org/0000-0003-3697-0378</orcidid><orcidid>https://orcid.org/0000-0001-8026-7271</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1434-1948 |
| ispartof | European journal of inorganic chemistry, 2020-12, Vol.2020 (45), p.4247-4253 |
| issn | 1434-1948 1099-0682 |
| language | eng |
| recordid | cdi_proquest_journals_2467534438 |
| source | Access via Wiley Online Library |
| subjects | Allyl ligands Amides Coordination compounds Crystal structure C–H activation Group 4 metals Inorganic chemistry Lithium Molecular structure NMR spectroscopy Phenylacetylide ligands Reagents Synthesis Thermal stability Titanium Zirconium |
| title | Tris(dicyclohexylamido) Group 4 Metal Allyl and Phenylacetylide Complexes – Synthesis and Characterization |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-30T21%3A12%3A42IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Tris(dicyclohexylamido)%20Group%204%20Metal%20Allyl%20and%20Phenylacetylide%20Complexes%20%E2%80%93%20Synthesis%20and%20Characterization&rft.jtitle=European%20journal%20of%20inorganic%20chemistry&rft.au=Frerichs,%20Nils&rft.date=2020-12-07&rft.volume=2020&rft.issue=45&rft.spage=4247&rft.epage=4253&rft.pages=4247-4253&rft.issn=1434-1948&rft.eissn=1099-0682&rft_id=info:doi/10.1002/ejic.202000682&rft_dat=%3Cproquest_cross%3E2467534438%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2467534438&rft_id=info:pmid/&rfr_iscdi=true |