Acetylacetonate and Acetate Complexes of Nickel(II) Catalyse the Air Oxidation of Phosphines

The polymeric complex trans‐[Ni(acac)2(µ2‐dppe)]n·2MeCN {1a, dppe = 1,2‐ethylenebis(diphenylphosphine)} is sometimes transiently deposited from the reaction of [Ni(acac)2] with dppe in MeCN prior to its facile onwards air oxidation to final crystallization of a doubly‐oxygenated relative, cis‐[Ni(ac...

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Veröffentlicht in:	European journal of inorganic chemistry 2020-11, Vol.2020 (44), p.4163-4169
Hauptverfasser:	Hansen, Line Sofie, Jakobsen, Vibe Boel, McKee, Vickie, McKenzie, Christine J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetate Crystallization Inorganic chemistry Nickel Oxidation Oxygen activation Phosphine oxidation Phosphines Toluene β‐Diketonate
Online-Zugang:	Volltext
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