Design and Application of Indole‐Based Allylic Donors for Pd‐Catalyzed Decarboxylative Allylation Reactions
Summary of main observation and conclusion A new class of indole‐based allylic donors have been designed and developed for palladium‐catalyzed decarboxylative allylations. In addition, the first application of these indole‐based allylic donors in palladium‐catalyzed decarboxylative [3+2] cycloadditi...
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| Veröffentlicht in: | Chinese journal of chemistry 2020-12, Vol.38 (12), p.1612-1618 |
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| container_issue | 12 |
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| container_title | Chinese journal of chemistry |
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| creator | Hang, Qing‐Qing Liu, Si‐Jia Yu, Lei Sun, Ting‐Ting Zhang, Yu‐Chen Mei, Guang‐Jian Shi, Feng |
| description | Summary of main observation and conclusion
A new class of indole‐based allylic donors have been designed and developed for palladium‐catalyzed decarboxylative allylations. In addition, the first application of these indole‐based allylic donors in palladium‐catalyzed decarboxylative [3+2] cycloaddition and allylic amination has been achieved by reacting with isocyanates and sulfonyl amines, respectively. This approach represents the first design of indole‐based allylic donors, which is helpful for settling the challenge of designing and developing new class of heterocycle‐based allylic donors for Pd‐catalyzed decarboxylative allylation reactions. Moreover, the application of this new class of allylic donors in cycloadditions and substitutions will add new contents to the research field of decarboxylative allylation.
A new class of indole‐based allylic donors have been designed and applied in palladium‐catalyzed decarboxylative [3+2] cycloaddition and allylic amination. |
| doi_str_mv | 10.1002/cjoc.202000104 |
| format | Article |
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A new class of indole‐based allylic donors have been designed and developed for palladium‐catalyzed decarboxylative allylations. In addition, the first application of these indole‐based allylic donors in palladium‐catalyzed decarboxylative [3+2] cycloaddition and allylic amination has been achieved by reacting with isocyanates and sulfonyl amines, respectively. This approach represents the first design of indole‐based allylic donors, which is helpful for settling the challenge of designing and developing new class of heterocycle‐based allylic donors for Pd‐catalyzed decarboxylative allylation reactions. Moreover, the application of this new class of allylic donors in cycloadditions and substitutions will add new contents to the research field of decarboxylative allylation.
A new class of indole‐based allylic donors have been designed and applied in palladium‐catalyzed decarboxylative [3+2] cycloaddition and allylic amination.</description><identifier>ISSN: 1001-604X</identifier><identifier>EISSN: 1614-7065</identifier><identifier>DOI: 10.1002/cjoc.202000104</identifier><language>eng</language><publisher>Weinheim: WILEY‐VCH Verlag GmbH & Co. KGaA</publisher><subject>Allyl compounds ; Allylation ; Allylic compounds ; Amination ; Amines ; Chemical reactions ; Cycloaddition ; Indole ; Indoles ; Isocyanates ; Palladium ; Substitution</subject><ispartof>Chinese journal of chemistry, 2020-12, Vol.38 (12), p.1612-1618</ispartof><rights>2020 SIOC, CAS, Shanghai and Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3544-3802b1e093798e26148d2e9275d682d41c0c5554dcebf4d71d6da487a7aeae73</citedby><cites>FETCH-LOGICAL-c3544-3802b1e093798e26148d2e9275d682d41c0c5554dcebf4d71d6da487a7aeae73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcjoc.202000104$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcjoc.202000104$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27922,27923,45572,45573</link.rule.ids></links><search><creatorcontrib>Hang, Qing‐Qing</creatorcontrib><creatorcontrib>Liu, Si‐Jia</creatorcontrib><creatorcontrib>Yu, Lei</creatorcontrib><creatorcontrib>Sun, Ting‐Ting</creatorcontrib><creatorcontrib>Zhang, Yu‐Chen</creatorcontrib><creatorcontrib>Mei, Guang‐Jian</creatorcontrib><creatorcontrib>Shi, Feng</creatorcontrib><title>Design and Application of Indole‐Based Allylic Donors for Pd‐Catalyzed Decarboxylative Allylation Reactions</title><title>Chinese journal of chemistry</title><description>Summary of main observation and conclusion
A new class of indole‐based allylic donors have been designed and developed for palladium‐catalyzed decarboxylative allylations. In addition, the first application of these indole‐based allylic donors in palladium‐catalyzed decarboxylative [3+2] cycloaddition and allylic amination has been achieved by reacting with isocyanates and sulfonyl amines, respectively. This approach represents the first design of indole‐based allylic donors, which is helpful for settling the challenge of designing and developing new class of heterocycle‐based allylic donors for Pd‐catalyzed decarboxylative allylation reactions. Moreover, the application of this new class of allylic donors in cycloadditions and substitutions will add new contents to the research field of decarboxylative allylation.
A new class of indole‐based allylic donors have been designed and applied in palladium‐catalyzed decarboxylative [3+2] cycloaddition and allylic amination.</description><subject>Allyl compounds</subject><subject>Allylation</subject><subject>Allylic compounds</subject><subject>Amination</subject><subject>Amines</subject><subject>Chemical reactions</subject><subject>Cycloaddition</subject><subject>Indole</subject><subject>Indoles</subject><subject>Isocyanates</subject><subject>Palladium</subject><subject>Substitution</subject><issn>1001-604X</issn><issn>1614-7065</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkL1OwzAUhS0EEqWwMkdiTrEdJ07GkvJTVKkIdWCzXPsGpTJxsFsgTDwCz8iT4CgIRiZf-XznXN2D0CnBE4IxPVcbqyYUU4wxwWwPjUhGWMxxlu6HOXzGGWYPh-jI-03gOafZCNkZ-PqxiWSjo2nbmlrJbW2byFbRvNHWwNfH54X0EFRjuiBHM9tY56PKuuhOB7WUW2m690DMQEm3tm-dCRkvMDiGuHuQqh_8MTqopPFw8vOO0erqclXexIvl9bycLmKVpIzFSY7pmgAuEl7kQMMhuaZQUJ7qLKeaEYVVmqZMK1hXTHOiMy1ZziWXIIEnY3Q2xLbOPu_Ab8XG7lwTNgrKMkbC8ZQFajJQylnvHVSidfWTdJ0gWPSdir5T8dtpMBSD4bU20P1Di_J2Wf55vwHYQH2N</recordid><startdate>202012</startdate><enddate>202012</enddate><creator>Hang, Qing‐Qing</creator><creator>Liu, Si‐Jia</creator><creator>Yu, Lei</creator><creator>Sun, Ting‐Ting</creator><creator>Zhang, Yu‐Chen</creator><creator>Mei, Guang‐Jian</creator><creator>Shi, Feng</creator><general>WILEY‐VCH Verlag GmbH & Co. KGaA</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>202012</creationdate><title>Design and Application of Indole‐Based Allylic Donors for Pd‐Catalyzed Decarboxylative Allylation Reactions</title><author>Hang, Qing‐Qing ; Liu, Si‐Jia ; Yu, Lei ; Sun, Ting‐Ting ; Zhang, Yu‐Chen ; Mei, Guang‐Jian ; Shi, Feng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3544-3802b1e093798e26148d2e9275d682d41c0c5554dcebf4d71d6da487a7aeae73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Allyl compounds</topic><topic>Allylation</topic><topic>Allylic compounds</topic><topic>Amination</topic><topic>Amines</topic><topic>Chemical reactions</topic><topic>Cycloaddition</topic><topic>Indole</topic><topic>Indoles</topic><topic>Isocyanates</topic><topic>Palladium</topic><topic>Substitution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hang, Qing‐Qing</creatorcontrib><creatorcontrib>Liu, Si‐Jia</creatorcontrib><creatorcontrib>Yu, Lei</creatorcontrib><creatorcontrib>Sun, Ting‐Ting</creatorcontrib><creatorcontrib>Zhang, Yu‐Chen</creatorcontrib><creatorcontrib>Mei, Guang‐Jian</creatorcontrib><creatorcontrib>Shi, Feng</creatorcontrib><collection>CrossRef</collection><jtitle>Chinese journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hang, Qing‐Qing</au><au>Liu, Si‐Jia</au><au>Yu, Lei</au><au>Sun, Ting‐Ting</au><au>Zhang, Yu‐Chen</au><au>Mei, Guang‐Jian</au><au>Shi, Feng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Design and Application of Indole‐Based Allylic Donors for Pd‐Catalyzed Decarboxylative Allylation Reactions</atitle><jtitle>Chinese journal of chemistry</jtitle><date>2020-12</date><risdate>2020</risdate><volume>38</volume><issue>12</issue><spage>1612</spage><epage>1618</epage><pages>1612-1618</pages><issn>1001-604X</issn><eissn>1614-7065</eissn><abstract>Summary of main observation and conclusion
A new class of indole‐based allylic donors have been designed and developed for palladium‐catalyzed decarboxylative allylations. In addition, the first application of these indole‐based allylic donors in palladium‐catalyzed decarboxylative [3+2] cycloaddition and allylic amination has been achieved by reacting with isocyanates and sulfonyl amines, respectively. This approach represents the first design of indole‐based allylic donors, which is helpful for settling the challenge of designing and developing new class of heterocycle‐based allylic donors for Pd‐catalyzed decarboxylative allylation reactions. Moreover, the application of this new class of allylic donors in cycloadditions and substitutions will add new contents to the research field of decarboxylative allylation.
A new class of indole‐based allylic donors have been designed and applied in palladium‐catalyzed decarboxylative [3+2] cycloaddition and allylic amination.</abstract><cop>Weinheim</cop><pub>WILEY‐VCH Verlag GmbH & Co. KGaA</pub><doi>10.1002/cjoc.202000104</doi><tpages>7</tpages></addata></record> |
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| subjects | Allyl compounds Allylation Allylic compounds Amination Amines Chemical reactions Cycloaddition Indole Indoles Isocyanates Palladium Substitution |
| title | Design and Application of Indole‐Based Allylic Donors for Pd‐Catalyzed Decarboxylative Allylation Reactions |
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