Microwave-assisted synthesis of CuO/MnO2 nanocomposites for supercapacitor application

Copper oxide/manganese dioxide (CuO/MnO2) nanocomposites were prepared by a facile microwave-assisted synthesis method in an ordinary household microwave oven and used for electrochemical supercapacitor. The nanocomposites were characterised by scanning electron microscopy, transmission electron mic...

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Veröffentlicht in:Micro & nano letters 2020-11, Vol.15 (13), p.938-942
Hauptverfasser: Zhang, Pengjiao, Li, Wei
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description Copper oxide/manganese dioxide (CuO/MnO2) nanocomposites were prepared by a facile microwave-assisted synthesis method in an ordinary household microwave oven and used for electrochemical supercapacitor. The nanocomposites were characterised by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction. Electrochemical results demonstrate that CuO/MnO2 nanocomposites have better capacitance performance than pure CuO material. The CuO/MnO2 nanocomposites have a high specific capacitance of 499.0 F/g at a current density of 0.5 A/g in 6 M KOH electrolyte. In addition, an asymmetric supercapacitor with activated carbon as a negative electrode and CuO/MnO2 nanocomposite as a positive electrode was also successfully prepared. This asymmetric device exhibits a high energy density of 32.07 Wh/kg at a power density of 375.02 W/kg and fairly good cycling stability.
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The nanocomposites were characterised by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction. Electrochemical results demonstrate that CuO/MnO2 nanocomposites have better capacitance performance than pure CuO material. The CuO/MnO2 nanocomposites have a high specific capacitance of 499.0 F/g at a current density of 0.5 A/g in 6 M KOH electrolyte. In addition, an asymmetric supercapacitor with activated carbon as a negative electrode and CuO/MnO2 nanocomposite as a positive electrode was also successfully prepared. This asymmetric device exhibits a high energy density of 32.07 Wh/kg at a power density of 375.02 W/kg and fairly good cycling stability.</description><identifier>ISSN: 1750-0443</identifier><identifier>EISSN: 1750-0443</identifier><identifier>DOI: 10.1049/mnl.2020.0400</identifier><language>eng</language><publisher>Stevenage: The Institution of Engineering and Technology</publisher><subject>Activated carbon ; Asymmetry ; Capacitance ; copper compounds ; Copper oxides ; copper oxide‐manganese dioxide ; CuO‐MnO2 ; CuO‐MnO2 nanocomposites ; current density ; cycling stability ; electrochemical electrodes ; electrochemical supercapacitor ; Electrodes ; electrolytes ; Electron microscopes ; Electron microscopy ; energy density ; Flux density ; KOH electrolyte ; manganese compounds ; Manganese dioxide ; Microscopy ; microwave materials processing ; microwave oven ; microwave ovens ; Microwaves ; microwave‐assisted synthesis ; Nanocomposites ; nanofabrication ; negative electrode ; Photoelectrons ; power density ; scanning electron microscopy ; semiconductor growth ; semiconductor materials ; specific capacitance ; supercapacitor ; Supercapacitors ; Synthesis ; transmission electron microscopy ; X‐ray diffraction ; X‐ray photoelectron spectra ; X‐ray photoelectron spectroscopy</subject><ispartof>Micro &amp; nano letters, 2020-11, Vol.15 (13), p.938-942</ispartof><rights>The Institution of Engineering and Technology</rights><rights>2020 The Institution of Engineering and Technology</rights><rights>Copyright The Institution of Engineering &amp; Technology Nov 18, 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1049%2Fmnl.2020.0400$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1049%2Fmnl.2020.0400$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,11541,27901,27902,45550,45551,46027,46451</link.rule.ids><linktorsrc>$$Uhttps://onlinelibrary.wiley.com/doi/abs/10.1049%2Fmnl.2020.0400$$EView_record_in_Wiley-Blackwell$$FView_record_in_$$GWiley-Blackwell</linktorsrc></links><search><creatorcontrib>Zhang, Pengjiao</creatorcontrib><creatorcontrib>Li, Wei</creatorcontrib><title>Microwave-assisted synthesis of CuO/MnO2 nanocomposites for supercapacitor application</title><title>Micro &amp; nano letters</title><description>Copper oxide/manganese dioxide (CuO/MnO2) nanocomposites were prepared by a facile microwave-assisted synthesis method in an ordinary household microwave oven and used for electrochemical supercapacitor. The nanocomposites were characterised by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction. Electrochemical results demonstrate that CuO/MnO2 nanocomposites have better capacitance performance than pure CuO material. The CuO/MnO2 nanocomposites have a high specific capacitance of 499.0 F/g at a current density of 0.5 A/g in 6 M KOH electrolyte. In addition, an asymmetric supercapacitor with activated carbon as a negative electrode and CuO/MnO2 nanocomposite as a positive electrode was also successfully prepared. This asymmetric device exhibits a high energy density of 32.07 Wh/kg at a power density of 375.02 W/kg and fairly good cycling stability.</description><subject>Activated carbon</subject><subject>Asymmetry</subject><subject>Capacitance</subject><subject>copper compounds</subject><subject>Copper oxides</subject><subject>copper oxide‐manganese dioxide</subject><subject>CuO‐MnO2</subject><subject>CuO‐MnO2 nanocomposites</subject><subject>current density</subject><subject>cycling stability</subject><subject>electrochemical electrodes</subject><subject>electrochemical supercapacitor</subject><subject>Electrodes</subject><subject>electrolytes</subject><subject>Electron microscopes</subject><subject>Electron microscopy</subject><subject>energy density</subject><subject>Flux density</subject><subject>KOH electrolyte</subject><subject>manganese compounds</subject><subject>Manganese dioxide</subject><subject>Microscopy</subject><subject>microwave materials processing</subject><subject>microwave oven</subject><subject>microwave ovens</subject><subject>Microwaves</subject><subject>microwave‐assisted synthesis</subject><subject>Nanocomposites</subject><subject>nanofabrication</subject><subject>negative electrode</subject><subject>Photoelectrons</subject><subject>power density</subject><subject>scanning electron microscopy</subject><subject>semiconductor growth</subject><subject>semiconductor materials</subject><subject>specific capacitance</subject><subject>supercapacitor</subject><subject>Supercapacitors</subject><subject>Synthesis</subject><subject>transmission electron microscopy</subject><subject>X‐ray diffraction</subject><subject>X‐ray photoelectron spectra</subject><subject>X‐ray photoelectron spectroscopy</subject><issn>1750-0443</issn><issn>1750-0443</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNptkD1PwzAQhi0EEqUwskdCDAxpzx9x4rFUFJCadgFWy3Uc4SqNTZxQ9d-TqgwZOt2d9LzvSQ9C9xgmGJiY7upqQoDABBjABRrhNIEYGKOXg_0a3YSwBWApScUIfeVWN26vfk2sQrChNUUUDnX7bfojcmU079bTvF6TqFa1027nXbCtCVHpmih03jRaeaVt25_K-8pq1VpX36KrUlXB3P3PMfpcvHzM3-Ll-vV9PlvGlgiWxUZzStUGjGFYbJKNIFilnBagNDUsYQrKJONaZakBQWlSZlwxIUAD55CZgo7Rw6nXN-6nM6GVW9c1df9SEsYpF5iLtKf4idrbyhykb-xONQeJQR69yd6bPHqTR28yX83I8wKwoFkffDwFrRk056vlgPdF2XNPZ7iz_fQPxZ59IA</recordid><startdate>20201118</startdate><enddate>20201118</enddate><creator>Zhang, Pengjiao</creator><creator>Li, Wei</creator><general>The Institution of Engineering and Technology</general><general>John Wiley &amp; 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Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology &amp; Engineering</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Micro &amp; nano letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Zhang, Pengjiao</au><au>Li, Wei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Microwave-assisted synthesis of CuO/MnO2 nanocomposites for supercapacitor application</atitle><jtitle>Micro &amp; nano letters</jtitle><date>2020-11-18</date><risdate>2020</risdate><volume>15</volume><issue>13</issue><spage>938</spage><epage>942</epage><pages>938-942</pages><issn>1750-0443</issn><eissn>1750-0443</eissn><abstract>Copper oxide/manganese dioxide (CuO/MnO2) nanocomposites were prepared by a facile microwave-assisted synthesis method in an ordinary household microwave oven and used for electrochemical supercapacitor. The nanocomposites were characterised by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction. Electrochemical results demonstrate that CuO/MnO2 nanocomposites have better capacitance performance than pure CuO material. The CuO/MnO2 nanocomposites have a high specific capacitance of 499.0 F/g at a current density of 0.5 A/g in 6 M KOH electrolyte. In addition, an asymmetric supercapacitor with activated carbon as a negative electrode and CuO/MnO2 nanocomposite as a positive electrode was also successfully prepared. This asymmetric device exhibits a high energy density of 32.07 Wh/kg at a power density of 375.02 W/kg and fairly good cycling stability.</abstract><cop>Stevenage</cop><pub>The Institution of Engineering and Technology</pub><doi>10.1049/mnl.2020.0400</doi><tpages>5</tpages></addata></record>
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subjects Activated carbon
Asymmetry
Capacitance
copper compounds
Copper oxides
copper oxide‐manganese dioxide
CuO‐MnO2
CuO‐MnO2 nanocomposites
current density
cycling stability
electrochemical electrodes
electrochemical supercapacitor
Electrodes
electrolytes
Electron microscopes
Electron microscopy
energy density
Flux density
KOH electrolyte
manganese compounds
Manganese dioxide
Microscopy
microwave materials processing
microwave oven
microwave ovens
Microwaves
microwave‐assisted synthesis
Nanocomposites
nanofabrication
negative electrode
Photoelectrons
power density
scanning electron microscopy
semiconductor growth
semiconductor materials
specific capacitance
supercapacitor
Supercapacitors
Synthesis
transmission electron microscopy
X‐ray diffraction
X‐ray photoelectron spectra
X‐ray photoelectron spectroscopy
title Microwave-assisted synthesis of CuO/MnO2 nanocomposites for supercapacitor application
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