Carbenoid‐Mediated Formation and Activation of Element‐Element and Element–Hydrogen Bonds

The application of the silyl‐substituted Li/Cl carbenoid RR'C(Li)Cl (1) [with R = Ph2P(S), R' = SiMe3] in the dehydrocoupling of group 14 element hydrides is reported. While silanes only yield product mixtures, selective E–E bond formation was observed for germanes and stannanes. In case o...

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Veröffentlicht in:	European journal of inorganic chemistry 2020-11, Vol.2020 (43), p.4111-4115
Hauptverfasser:	Dilchert, Katharina, Scherpf, Thorsten, Gessner, Viktoria H.
Format:	Artikel
Sprache:	eng
Schlagworte:	Bond activation Carbenoids Coupling reactions Hydrogen bonds Inorganic chemistry Lithium Silanes Structure elucidation Tin compounds
Online-Zugang:	Volltext
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