Metal‐Free Decarboxylation of Alkynoic Acids for the Synthesis of Terminal Alkynes

Terminal alkynes were readily obtained via the reaction of alkynoic acids with N,N,N’,N’‐teramethylethylenediamine (TMEDA) in DMSO at 65 °C for 12 h. This method gave good yields and showed high functional group tolerance. In addition, deuterated terminal alkynes were formed in good yields when alky...

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Veröffentlicht in:	Asian journal of organic chemistry 2020-11, Vol.9 (11), p.1774-1777
Hauptverfasser:	Seo, Eunkyeong, Oh, Jonghoon, Lee, Sunwoo
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes alkynoic aicd Decarboxylation Deuteration Functional groups metal-free conditions Organic chemistry terminal alkyne
Online-Zugang:	Volltext
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