First- and second-order phase transitions in Fe-(17-19)at.%Ga alloys

[Display omitted] •Time-Temperature-Transformation diagrams are built for the Fe-17.5 Ga and 19.5 Ga alloys.•In situ neutron diffraction with different cooling rates is used to control phase transitions.•Long-term annealing demonstrates inadequacy of existing phase diagrams. The structure of the Fe-...

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Veröffentlicht in:Materials letters 2020-11, Vol.279, p.128508, Article 128508
Hauptverfasser: Mohamed, A.K., Cheverikin, V.V., Medvedeva, S.V., Bobrikov, I.A., Balagurov, A.M., Golovin, I.S.
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container_end_page
container_issue
container_start_page 128508
container_title Materials letters
container_volume 279
creator Mohamed, A.K.
Cheverikin, V.V.
Medvedeva, S.V.
Bobrikov, I.A.
Balagurov, A.M.
Golovin, I.S.
description [Display omitted] •Time-Temperature-Transformation diagrams are built for the Fe-17.5 Ga and 19.5 Ga alloys.•In situ neutron diffraction with different cooling rates is used to control phase transitions.•Long-term annealing demonstrates inadequacy of existing phase diagrams. The structure of the Fe-(17.5–19.5)at.%Ga alloys in as-cast and nearly equilibrium states is studied using XRD, ND, and EBSD. In disagreement with the existing phase diagrams, the long-term isothermally annealed at 450–500 °C Fe-17.5%Ga alloy has a two-phase structure with two co-existing ferromagnetic phases: bcc-originated A2(D03) as a matrix and a fcc-originated A1(L12) needle-shaped precipitates. The phase transitions during cooling of 17.5 and 19.5%Ga alloys from the A2 range of the phase diagram with different cooling rates were used to plot, at least partly, Time-Temperature-Transformation (TTT) diagrams. The critical cooling rates for starting first- and second-order transitions are determined for the Fe-19.5%Ga alloy. The effect of long-term annealing on magnetostriction is reported.
doi_str_mv 10.1016/j.matlet.2020.128508
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The structure of the Fe-(17.5–19.5)at.%Ga alloys in as-cast and nearly equilibrium states is studied using XRD, ND, and EBSD. In disagreement with the existing phase diagrams, the long-term isothermally annealed at 450–500 °C Fe-17.5%Ga alloy has a two-phase structure with two co-existing ferromagnetic phases: bcc-originated A2(D03) as a matrix and a fcc-originated A1(L12) needle-shaped precipitates. The phase transitions during cooling of 17.5 and 19.5%Ga alloys from the A2 range of the phase diagram with different cooling rates were used to plot, at least partly, Time-Temperature-Transformation (TTT) diagrams. The critical cooling rates for starting first- and second-order transitions are determined for the Fe-19.5%Ga alloy. 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The structure of the Fe-(17.5–19.5)at.%Ga alloys in as-cast and nearly equilibrium states is studied using XRD, ND, and EBSD. In disagreement with the existing phase diagrams, the long-term isothermally annealed at 450–500 °C Fe-17.5%Ga alloy has a two-phase structure with two co-existing ferromagnetic phases: bcc-originated A2(D03) as a matrix and a fcc-originated A1(L12) needle-shaped precipitates. The phase transitions during cooling of 17.5 and 19.5%Ga alloys from the A2 range of the phase diagram with different cooling rates were used to plot, at least partly, Time-Temperature-Transformation (TTT) diagrams. The critical cooling rates for starting first- and second-order transitions are determined for the Fe-19.5%Ga alloy. 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The structure of the Fe-(17.5–19.5)at.%Ga alloys in as-cast and nearly equilibrium states is studied using XRD, ND, and EBSD. In disagreement with the existing phase diagrams, the long-term isothermally annealed at 450–500 °C Fe-17.5%Ga alloy has a two-phase structure with two co-existing ferromagnetic phases: bcc-originated A2(D03) as a matrix and a fcc-originated A1(L12) needle-shaped precipitates. The phase transitions during cooling of 17.5 and 19.5%Ga alloys from the A2 range of the phase diagram with different cooling rates were used to plot, at least partly, Time-Temperature-Transformation (TTT) diagrams. The critical cooling rates for starting first- and second-order transitions are determined for the Fe-19.5%Ga alloy. The effect of long-term annealing on magnetostriction is reported.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.matlet.2020.128508</doi><orcidid>https://orcid.org/0000-0001-5364-1440</orcidid></addata></record>
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subjects Alloys
Annealing
Cooling
Cooling rate
Cooling rates
Diffusion
Fe-Ga
Ferromagnetic phases
Ferromagnetism
Gallium base alloys
Grain boundaries
Magnetostriction
Materials science
Phase diagrams
Phase transformations
Phase transitions
Precipitates
Solid phases
TTT diagram
title First- and second-order phase transitions in Fe-(17-19)at.%Ga alloys
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