Ferromagnetically Coupled S=1 Chains in Crystals of Verdazyl‐Nitronyl Nitroxide Diradicals

Thermally stable organic diradicals with a triplet ground state along with large singlet‐triplet energy gap have significant potential for advanced technological applications. A series of phenylene‐bridged diradicals with oxoverdazyl and nitronyl nitroxide units were synthesized via a palladium‐cata...

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Veröffentlicht in:	Angewandte Chemie 2020-11, Vol.132 (46), p.20885-20891
Hauptverfasser:	Tretyakov, Evgeny V., Zhivetyeva, Svetlana I., Petunin, Pavel V., Gorbunov, Dmitry E., Gritsan, Nina P., Bagryanskaya, Irina Yu, Bogomyakov, Artem S., Postnikov, Pavel S., Kazantsev, Maxim S., Trusova, Marina E., Shundrina, Inna K., Zaytseva, Elena V., Parkhomenko, Dmitriy A., Bagryanskaya, Elena G., Ovcharenko, Victor I.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chains Chemical synthesis Chemistry Cross coupling Crystallization Crystals Energy gap Exchanging ferromagnetically coupled chain Ferromagnetism Ground state high-spin molecules Inert atmospheres Nitroxide nitroxides Palladium Thermal stability triplet diradicals verdazyl radicals
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