Electrodeposited Cu–Pd bimetallic catalysts for the selective electroreduction of CO2 to ethylene
Cu–Pd bimetallic catalysts were fabricated on carbon paper (CP) by the electrodeposition method via a dynamic hydrogen bubble template approach. At a potential of −1.2 V vs. RHE, the Faradaic efficiency (FE) of C2H4 could reach 45.2% with a current density of 17.4 mA cm−2 in an H-type electrolytic c...
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Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2020-01, Vol.22 (21), p.7560-7565 |
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container_title | Green chemistry : an international journal and green chemistry resource : GC |
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creator | Feng, Ruting Zhu, Qinggong Chu, Mengen Jia, Shuaiqiang Zhai, Jianxin Wu, Haihong Wu, Peng Han, Buxing |
description | Cu–Pd bimetallic catalysts were fabricated on carbon paper (CP) by the electrodeposition method via a dynamic hydrogen bubble template approach. At a potential of −1.2 V vs. RHE, the Faradaic efficiency (FE) of C2H4 could reach 45.2% with a current density of 17.4 mA cm−2 in an H-type electrolytic cell. Detailed studies suggest that the enhanced performance of Cu–Pd/CP was attributed mainly to the synergistic effect, low interfacial charge transfer resistance, and the 3D architecture of the catalysts. |
doi_str_mv | 10.1039/d0gc03051a |
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At a potential of −1.2 V vs. RHE, the Faradaic efficiency (FE) of C2H4 could reach 45.2% with a current density of 17.4 mA cm−2 in an H-type electrolytic cell. 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Detailed studies suggest that the enhanced performance of Cu–Pd/CP was attributed mainly to the synergistic effect, low interfacial charge transfer resistance, and the 3D architecture of the catalysts.</description><subject>Bimetals</subject><subject>Carbon dioxide</subject><subject>Catalysts</subject><subject>Charge transfer</subject><subject>Electrolytic cells</subject><subject>Green chemistry</subject><subject>Synergistic effect</subject><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNo9jcFKAzEURYMoWKsbvyDgejQvySQzSxmqFQp1oesy8_LSThkndZIRuvMf_EO_xErF1T1cOPcydg3iFoQq75xYo1Aih_qETUAblZXSitN_NvKcXcS4FQLAGj1hOOsI0xAc7UJsEzlejd-fX8-ON-0bpbrrWuRYH2AfU-Q-DDxtiEf61doP4nT0B3LjoQg9D55XS8lT4JQ2-456umRnvu4iXf3llL0-zF6qebZYPj5V94tsDYVJmUbnwOZYGNQeS8gFOW-NaAySlIpK58nV1DSykFQ7ZY3yqIUHrRCsk2rKbo67uyG8jxTTahvGoT9crqTOjTJgrVQ_mXhZ3A</recordid><startdate>20200101</startdate><enddate>20200101</enddate><creator>Feng, Ruting</creator><creator>Zhu, Qinggong</creator><creator>Chu, Mengen</creator><creator>Jia, Shuaiqiang</creator><creator>Zhai, Jianxin</creator><creator>Wu, Haihong</creator><creator>Wu, Peng</creator><creator>Han, Buxing</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7ST</scope><scope>7U6</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope></search><sort><creationdate>20200101</creationdate><title>Electrodeposited Cu–Pd bimetallic catalysts for the selective electroreduction of CO2 to ethylene</title><author>Feng, Ruting ; Zhu, Qinggong ; Chu, Mengen ; Jia, Shuaiqiang ; Zhai, Jianxin ; Wu, Haihong ; Wu, Peng ; Han, Buxing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g186t-4cdd175c86c4fc9150edf760b6ce223e9dfedaebb282ead3763fc40f143c17d23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Bimetals</topic><topic>Carbon dioxide</topic><topic>Catalysts</topic><topic>Charge transfer</topic><topic>Electrolytic cells</topic><topic>Green chemistry</topic><topic>Synergistic effect</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Feng, Ruting</creatorcontrib><creatorcontrib>Zhu, Qinggong</creatorcontrib><creatorcontrib>Chu, Mengen</creatorcontrib><creatorcontrib>Jia, Shuaiqiang</creatorcontrib><creatorcontrib>Zhai, Jianxin</creatorcontrib><creatorcontrib>Wu, Haihong</creatorcontrib><creatorcontrib>Wu, Peng</creatorcontrib><creatorcontrib>Han, Buxing</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Feng, Ruting</au><au>Zhu, Qinggong</au><au>Chu, Mengen</au><au>Jia, Shuaiqiang</au><au>Zhai, Jianxin</au><au>Wu, Haihong</au><au>Wu, Peng</au><au>Han, Buxing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrodeposited Cu–Pd bimetallic catalysts for the selective electroreduction of CO2 to ethylene</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><date>2020-01-01</date><risdate>2020</risdate><volume>22</volume><issue>21</issue><spage>7560</spage><epage>7565</epage><pages>7560-7565</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>Cu–Pd bimetallic catalysts were fabricated on carbon paper (CP) by the electrodeposition method via a dynamic hydrogen bubble template approach. At a potential of −1.2 V vs. RHE, the Faradaic efficiency (FE) of C2H4 could reach 45.2% with a current density of 17.4 mA cm−2 in an H-type electrolytic cell. Detailed studies suggest that the enhanced performance of Cu–Pd/CP was attributed mainly to the synergistic effect, low interfacial charge transfer resistance, and the 3D architecture of the catalysts.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d0gc03051a</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Bimetals Carbon dioxide Catalysts Charge transfer Electrolytic cells Green chemistry Synergistic effect |
title | Electrodeposited Cu–Pd bimetallic catalysts for the selective electroreduction of CO2 to ethylene |
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