Ligand effects on electronic structure and bonding in U() coordination complexes: a combined MCD, EPR and computational study

The trivalent oxidation state of uranium has been shown to undergo unique reactivity, from its ability to activate a variety of small molecules to its role in the catalytic reduction of ethene to ethane amongst others. Central to this unique reactivity and ability to rationally design ligands for is...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2020-10, Vol.49 (41), p.1441-1441
Hauptverfasser:	Wolford, Nikki J, Yu, Xiaojuan, Bart, Suzanne C, Autschbach, Jochen, Neidig, Michael L
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical reduction Coordination compounds Density functional theory Electronic structure Ethane Ethylene Isotope separation Ligands Oxidation Perturbation Reactivity Uranium Valence Wave functions
Online-Zugang:	Volltext
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