Polydopamine coated poly(m-phenylene isophthalamid) membrane as heat-tolerant separator for lithium-ion batteries
Poly(m-phenylene isophthalamide) (PMIA) membranes are promising heat-tolerant separator candidates of lithium-ion batteries (LIBs), while their wettability toward carbonate electrolyte and corresponding batteries performance are not desirable. Herein, PMIA membranes coated with ultrathin mussel-insp...
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| Veröffentlicht in: | Ionics 2020-11, Vol.26 (11), p.5471-5480 |
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| container_title | Ionics |
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| creator | Pan, Fusheng Qiao, Lina Yuan, Biao Duan, Cuijia Wang, Jianjie Wu, Wei Lin, Quanfan Shi, Yake Chen, Zan Jiang, Zhongyi |
| description | Poly(m-phenylene isophthalamide) (PMIA) membranes are promising heat-tolerant separator candidates of lithium-ion batteries (LIBs), while their wettability toward carbonate electrolyte and corresponding batteries performance are not desirable. Herein, PMIA membranes coated with ultrathin mussel-inspired polydopamine (PDA) layer were fabricated as separators in LIBs. The introduced amino, quinonyl, and catechol groups in PDA coating could enhance the wettability of the resultant PMIA-PDA separator toward electrolyte. The PMIA-PDA separator had excellent thermal stability, showing a thermal shrinkage of 5.2% at 200 °C. The contact angle of the thermal-treated PMIA-PDA separator could maintain at 26.1°, which decreased by 42.7% compared with the pristine PMIA separator. The PMIA-PDA separator also displayed a high ionic conductivity (0.86 mS cm
−1
) and a low interfacial electric resistance (62.4 Ω). Consequently, the assembled LiCoO
2
/PMIA-PDA/Li battery achieved good cyclic stability with the capacity retention of 84.3% (121.1 mAh g
−1
) after 100 cycles under 30 °C. More significantly, the relevant capacity retention remained at 89.0% (127.5 mAh g
−1
) under 60 °C, which implied a great potential of PMIA-PDA membranes as separators of high-safety LIBs. |
| doi_str_mv | 10.1007/s11581-020-03699-y |
| format | Article |
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−1
) and a low interfacial electric resistance (62.4 Ω). Consequently, the assembled LiCoO
2
/PMIA-PDA/Li battery achieved good cyclic stability with the capacity retention of 84.3% (121.1 mAh g
−1
) after 100 cycles under 30 °C. More significantly, the relevant capacity retention remained at 89.0% (127.5 mAh g
−1
) under 60 °C, which implied a great potential of PMIA-PDA membranes as separators of high-safety LIBs.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-020-03699-y</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Catechol ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Contact angle ; Electric contacts ; Electrochemistry ; Electrolytes ; Energy Storage ; Ion currents ; Lithium ; Lithium-ion batteries ; Membranes ; Optical and Electronic Materials ; Original Paper ; Rechargeable batteries ; Renewable and Green Energy ; Separators ; Thermal stability ; Wettability</subject><ispartof>Ionics, 2020-11, Vol.26 (11), p.5471-5480</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-edadffa64bd088c12fa2c801b74621c05de5677f26a4423e284490b35da945983</citedby><cites>FETCH-LOGICAL-c319t-edadffa64bd088c12fa2c801b74621c05de5677f26a4423e284490b35da945983</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-020-03699-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-020-03699-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27915,27916,41479,42548,51310</link.rule.ids></links><search><creatorcontrib>Pan, Fusheng</creatorcontrib><creatorcontrib>Qiao, Lina</creatorcontrib><creatorcontrib>Yuan, Biao</creatorcontrib><creatorcontrib>Duan, Cuijia</creatorcontrib><creatorcontrib>Wang, Jianjie</creatorcontrib><creatorcontrib>Wu, Wei</creatorcontrib><creatorcontrib>Lin, Quanfan</creatorcontrib><creatorcontrib>Shi, Yake</creatorcontrib><creatorcontrib>Chen, Zan</creatorcontrib><creatorcontrib>Jiang, Zhongyi</creatorcontrib><title>Polydopamine coated poly(m-phenylene isophthalamid) membrane as heat-tolerant separator for lithium-ion batteries</title><title>Ionics</title><addtitle>Ionics</addtitle><description>Poly(m-phenylene isophthalamide) (PMIA) membranes are promising heat-tolerant separator candidates of lithium-ion batteries (LIBs), while their wettability toward carbonate electrolyte and corresponding batteries performance are not desirable. Herein, PMIA membranes coated with ultrathin mussel-inspired polydopamine (PDA) layer were fabricated as separators in LIBs. The introduced amino, quinonyl, and catechol groups in PDA coating could enhance the wettability of the resultant PMIA-PDA separator toward electrolyte. The PMIA-PDA separator had excellent thermal stability, showing a thermal shrinkage of 5.2% at 200 °C. The contact angle of the thermal-treated PMIA-PDA separator could maintain at 26.1°, which decreased by 42.7% compared with the pristine PMIA separator. The PMIA-PDA separator also displayed a high ionic conductivity (0.86 mS cm
−1
) and a low interfacial electric resistance (62.4 Ω). Consequently, the assembled LiCoO
2
/PMIA-PDA/Li battery achieved good cyclic stability with the capacity retention of 84.3% (121.1 mAh g
−1
) after 100 cycles under 30 °C. More significantly, the relevant capacity retention remained at 89.0% (127.5 mAh g
−1
) under 60 °C, which implied a great potential of PMIA-PDA membranes as separators of high-safety LIBs.</description><subject>Catechol</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Contact angle</subject><subject>Electric contacts</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Energy Storage</subject><subject>Ion currents</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Membranes</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Rechargeable batteries</subject><subject>Renewable and Green Energy</subject><subject>Separators</subject><subject>Thermal stability</subject><subject>Wettability</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouK7-AU8FL3qITtI0aY-y-AULetBzSNup7dI23SR76L83WsGbh2Hg5Xln4CHkksEtA1B3nrEsZxQ4UEhlUdD5iKxYLjkFJeGYrKAQiioQ6pSceb8DkJJxtSL7N9vPtZ3M0I2YVNYErJMpZtcDnVoc5x5j3nk7taE1fcTqm2TAoXQm5sYnLZpAg-0xBiHxOBlngnVJE6fvQtsdBtrZMSlNCOg69OfkpDG9x4vfvSYfjw_vm2e6fX162dxvaZWyIlCsTd00RoqyhjyvGG8Mr3JgpRKSswqyGjOpVMOlEYKnyHMhCijTrDaFyIo8XZOr5e7k7P6APuidPbgxvtRcZKByzoSMFF-oylnvHTZ6ct1g3KwZ6G-1elGro1r9o1bPsZQuJR_h8RPd3-l_Wl__wH7b</recordid><startdate>20201101</startdate><enddate>20201101</enddate><creator>Pan, Fusheng</creator><creator>Qiao, Lina</creator><creator>Yuan, Biao</creator><creator>Duan, Cuijia</creator><creator>Wang, Jianjie</creator><creator>Wu, Wei</creator><creator>Lin, Quanfan</creator><creator>Shi, Yake</creator><creator>Chen, Zan</creator><creator>Jiang, Zhongyi</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20201101</creationdate><title>Polydopamine coated poly(m-phenylene isophthalamid) membrane as heat-tolerant separator for lithium-ion batteries</title><author>Pan, Fusheng ; Qiao, Lina ; Yuan, Biao ; Duan, Cuijia ; Wang, Jianjie ; Wu, Wei ; Lin, Quanfan ; Shi, Yake ; Chen, Zan ; Jiang, Zhongyi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-edadffa64bd088c12fa2c801b74621c05de5677f26a4423e284490b35da945983</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Catechol</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Contact angle</topic><topic>Electric contacts</topic><topic>Electrochemistry</topic><topic>Electrolytes</topic><topic>Energy Storage</topic><topic>Ion currents</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Membranes</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Rechargeable batteries</topic><topic>Renewable and Green Energy</topic><topic>Separators</topic><topic>Thermal stability</topic><topic>Wettability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pan, Fusheng</creatorcontrib><creatorcontrib>Qiao, Lina</creatorcontrib><creatorcontrib>Yuan, Biao</creatorcontrib><creatorcontrib>Duan, Cuijia</creatorcontrib><creatorcontrib>Wang, Jianjie</creatorcontrib><creatorcontrib>Wu, Wei</creatorcontrib><creatorcontrib>Lin, Quanfan</creatorcontrib><creatorcontrib>Shi, Yake</creatorcontrib><creatorcontrib>Chen, Zan</creatorcontrib><creatorcontrib>Jiang, Zhongyi</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pan, Fusheng</au><au>Qiao, Lina</au><au>Yuan, Biao</au><au>Duan, Cuijia</au><au>Wang, Jianjie</au><au>Wu, Wei</au><au>Lin, Quanfan</au><au>Shi, Yake</au><au>Chen, Zan</au><au>Jiang, Zhongyi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polydopamine coated poly(m-phenylene isophthalamid) membrane as heat-tolerant separator for lithium-ion batteries</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2020-11-01</date><risdate>2020</risdate><volume>26</volume><issue>11</issue><spage>5471</spage><epage>5480</epage><pages>5471-5480</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>Poly(m-phenylene isophthalamide) (PMIA) membranes are promising heat-tolerant separator candidates of lithium-ion batteries (LIBs), while their wettability toward carbonate electrolyte and corresponding batteries performance are not desirable. Herein, PMIA membranes coated with ultrathin mussel-inspired polydopamine (PDA) layer were fabricated as separators in LIBs. The introduced amino, quinonyl, and catechol groups in PDA coating could enhance the wettability of the resultant PMIA-PDA separator toward electrolyte. The PMIA-PDA separator had excellent thermal stability, showing a thermal shrinkage of 5.2% at 200 °C. The contact angle of the thermal-treated PMIA-PDA separator could maintain at 26.1°, which decreased by 42.7% compared with the pristine PMIA separator. The PMIA-PDA separator also displayed a high ionic conductivity (0.86 mS cm
−1
) and a low interfacial electric resistance (62.4 Ω). Consequently, the assembled LiCoO
2
/PMIA-PDA/Li battery achieved good cyclic stability with the capacity retention of 84.3% (121.1 mAh g
−1
) after 100 cycles under 30 °C. More significantly, the relevant capacity retention remained at 89.0% (127.5 mAh g
−1
) under 60 °C, which implied a great potential of PMIA-PDA membranes as separators of high-safety LIBs.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-020-03699-y</doi><tpages>10</tpages></addata></record> |
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| subjects | Catechol Chemistry Chemistry and Materials Science Condensed Matter Physics Contact angle Electric contacts Electrochemistry Electrolytes Energy Storage Ion currents Lithium Lithium-ion batteries Membranes Optical and Electronic Materials Original Paper Rechargeable batteries Renewable and Green Energy Separators Thermal stability Wettability |
| title | Polydopamine coated poly(m-phenylene isophthalamid) membrane as heat-tolerant separator for lithium-ion batteries |
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