Effect of dissolution pathways of polyacrylonitrile on the solution homogeneity: Thermodynamic- or kinetic-controlled dissolution

Dissolution behavior of polyacrylontrile (PAN) in N,N-dimethylformamide (DMF) and dimethylsulfoxide (DMSO) is investigated in terms of dipole-dipole interactions at polymer-solvent interface. Fourier-transformed infrared (FTIR) imaging of polymer-solvent interface under static dissolution condition...

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Veröffentlicht in:	Polymer (Guilford) 2020-09, Vol.205, p.122697, Article 122697
Hauptverfasser:	Eom, Youngho, Ju, Hyejin, Park, Yeonju, Chae, Dong Wook, Jung, Young Mee, Kim, Byoung Chul, Chae, Han Gi
Format:	Artikel
Sprache:	eng
Schlagworte:	Correlation analysis Dimethylformamide Dipole interactions Dissolution Enthalpy Homogeneity Huggins constant Infrared imaging Infrared spectroscopy Polyacrylonitrile Polymers Rheological properties Rheology Solvents Stirring Thermodynamics and kinetics Two dimensional analysis
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