Phosphate functionalized poly(vinyl alcohol)/poly(acrylic acid) (PVA/PAA): an electrospinning nanofiber for uranium separation

With the aim of capturing uranium from water mediums phosphate functionalized poly(vinyl alcohol)/poly(acrylic acid) (PVA/PAA) nanofiber (PVA/PAA-PO 4 ) was firstly fabricated using the electrospinning method of fast process and high efficiency. The as-prepared PVA/PAA-PO 4 showed excellent water st...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2020-10, Vol.326 (1), p.475-486
Hauptverfasser: Xie, Jinhua, Lv, Riwen, Peng, Hong, Fan, Jiali, Tao, Qinqin, Dai, Ying, Zhang, Zhibin, Cao, Xiaohong, Liu, Yunhai
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container_end_page 486
container_issue 1
container_start_page 475
container_title Journal of radioanalytical and nuclear chemistry
container_volume 326
creator Xie, Jinhua
Lv, Riwen
Peng, Hong
Fan, Jiali
Tao, Qinqin
Dai, Ying
Zhang, Zhibin
Cao, Xiaohong
Liu, Yunhai
description With the aim of capturing uranium from water mediums phosphate functionalized poly(vinyl alcohol)/poly(acrylic acid) (PVA/PAA) nanofiber (PVA/PAA-PO 4 ) was firstly fabricated using the electrospinning method of fast process and high efficiency. The as-prepared PVA/PAA-PO 4 showed excellent water stability and tensile strength besides competitive uranium uptake capacity of 277.78 mg/g. Phosphate played a vital role in the structure of PVA/PAA-PO 4 for the attractive uranium uptake capacity. PVA/PAA-PO 4 was characterized by SEM, XPS, FT-IR and omnipotence machine. The effects of pH, ionic strength, oscillation time, initial uranium concentration and temperature on the uranium adsorption with PVA/PAA-PO 4 were studied. The elution with different kinds of acids was conducted and the reusability through the adsorption-desorption cycle test was carried out. The work provided a promising candidate for uranium separation from aqueous solution.
doi_str_mv 10.1007/s10967-020-07319-x
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subjects Acrylics
Adsorption
Aqueous solutions
Chemistry
Chemistry and Materials Science
Diagnostic Radiology
Electrospinning
Elution
Hadrons
Heavy Ions
Inorganic Chemistry
Nanofibers
Nuclear Chemistry
Nuclear Physics
Physical Chemistry
Polyacrylic acid
Polyvinyl alcohol
Separation
Tensile strength
Uranium
Water stability
X ray photoelectron spectroscopy
title Phosphate functionalized poly(vinyl alcohol)/poly(acrylic acid) (PVA/PAA): an electrospinning nanofiber for uranium separation
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