Unique triple ruthenacarborane cluster
Dehalogenation of[1,2-Ph 2 -3,3-(PPh 3 ) 2 -3-Cl- closo/pseudocloso -3,1,2-RuC 2 B 9 H 9 ] − affords, in addition to the unusual “symbiotic”** cluster [(1,2-Ph 2 - pseudocloso -3,1,2-RuC 2 B 9 H 9 ) (1′,8′-Ph 2 - closo -2′,1′8′-RuC 2 B 9 H 9 )], a trace amount of a triple cluster species [(1,2-Ph 2...
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| Veröffentlicht in: | Russian chemical bulletin 2020-08, Vol.69 (8), p.1594-1597 |
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| creator | Jones, J. J. Robertson, A. P. M. Rosair, G. M. Welch, A. J. |
| description | Dehalogenation of[1,2-Ph
2
-3,3-(PPh
3
)
2
-3-Cl-
closo/pseudocloso
-3,1,2-RuC
2
B
9
H
9
]
−
affords, in addition to the unusual “symbiotic”** cluster [(1,2-Ph
2
-
pseudocloso
-3,1,2-RuC
2
B
9
H
9
) (1′,8′-Ph
2
-
closo
-2′,1′8′-RuC
2
B
9
H
9
)], a trace amount of a triple cluster species [(1,2-Ph
2
-pseudocloso-3,1,2-RuC
2
B
9
H
9
)(1′,8′-Ph
2
-closo-2′,1′,8′-RuC
2
B
9
H9)(1″,8″-Ph
2
-
closo
-2″,1″,8″-RuC
2
B
9
H
9
)], comprising three (Ph
2
RuC
2
B
9
H
9
) units linked by η
6
- coordination of Ph rings to the Ru atoms of the adjacent cluster. The structure of the triple cluster was established by X-ray crystallography, and the potential consequences of its formation are discussed. |
| doi_str_mv | 10.1007/s11172-020-2940-2 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2450403331</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2450403331</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-16edcb3a5ce571927df09645066865a96339238a00c1a4fcc223eee59739803a3</originalsourceid><addsrcrecordid>eNp1kE1LAzEQhoMoWKs_wFtB8BadyWy-jlK0CgUv9hzSNKtb6u6a7B7896as4MnLzBzej-Fh7BrhDgH0fUZELTgI4MJWZZywGUpN3KLG03KDUlwKI8_ZRc57ABDGmBm73bTN1xgXQ2r6Q1ykcfiIrQ8-bbvk27gIhzEPMV2ys9ofcrz63XO2eXp8Wz7z9evqZfmw5oFQDRxV3IUteRmi1GiF3tVgVSVLuVHSW0VkBRkPENBXdQhCUIxRWk3WAHmas5spt09deSsPbt-NqS2VTpSYCogIiwonVUhdzinWrk_Np0_fDsEdcbgJhys43BGHE8UjJk8u2vY9pr_k_00_L39gUg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2450403331</pqid></control><display><type>article</type><title>Unique triple ruthenacarborane cluster</title><source>Springer Nature - Complete Springer Journals</source><creator>Jones, J. J. ; Robertson, A. P. M. ; Rosair, G. M. ; Welch, A. J.</creator><creatorcontrib>Jones, J. J. ; Robertson, A. P. M. ; Rosair, G. M. ; Welch, A. J.</creatorcontrib><description>Dehalogenation of[1,2-Ph
2
-3,3-(PPh
3
)
2
-3-Cl-
closo/pseudocloso
-3,1,2-RuC
2
B
9
H
9
]
−
affords, in addition to the unusual “symbiotic”** cluster [(1,2-Ph
2
-
pseudocloso
-3,1,2-RuC
2
B
9
H
9
) (1′,8′-Ph
2
-
closo
-2′,1′8′-RuC
2
B
9
H
9
)], a trace amount of a triple cluster species [(1,2-Ph
2
-pseudocloso-3,1,2-RuC
2
B
9
H
9
)(1′,8′-Ph
2
-closo-2′,1′,8′-RuC
2
B
9
H9)(1″,8″-Ph
2
-
closo
-2″,1″,8″-RuC
2
B
9
H
9
)], comprising three (Ph
2
RuC
2
B
9
H
9
) units linked by η
6
- coordination of Ph rings to the Ru atoms of the adjacent cluster. The structure of the triple cluster was established by X-ray crystallography, and the potential consequences of its formation are discussed.</description><identifier>ISSN: 1066-5285</identifier><identifier>EISSN: 1573-9171</identifier><identifier>DOI: 10.1007/s11172-020-2940-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Brief Communications ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Clusters ; Crystallography ; Inorganic Chemistry ; Organic Chemistry</subject><ispartof>Russian chemical bulletin, 2020-08, Vol.69 (8), p.1594-1597</ispartof><rights>Springer Science+Business Media LLC 2020</rights><rights>Springer Science+Business Media LLC 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-16edcb3a5ce571927df09645066865a96339238a00c1a4fcc223eee59739803a3</citedby><cites>FETCH-LOGICAL-c316t-16edcb3a5ce571927df09645066865a96339238a00c1a4fcc223eee59739803a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11172-020-2940-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11172-020-2940-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Jones, J. J.</creatorcontrib><creatorcontrib>Robertson, A. P. M.</creatorcontrib><creatorcontrib>Rosair, G. M.</creatorcontrib><creatorcontrib>Welch, A. J.</creatorcontrib><title>Unique triple ruthenacarborane cluster</title><title>Russian chemical bulletin</title><addtitle>Russ Chem Bull</addtitle><description>Dehalogenation of[1,2-Ph
2
-3,3-(PPh
3
)
2
-3-Cl-
closo/pseudocloso
-3,1,2-RuC
2
B
9
H
9
]
−
affords, in addition to the unusual “symbiotic”** cluster [(1,2-Ph
2
-
pseudocloso
-3,1,2-RuC
2
B
9
H
9
) (1′,8′-Ph
2
-
closo
-2′,1′8′-RuC
2
B
9
H
9
)], a trace amount of a triple cluster species [(1,2-Ph
2
-pseudocloso-3,1,2-RuC
2
B
9
H
9
)(1′,8′-Ph
2
-closo-2′,1′,8′-RuC
2
B
9
H9)(1″,8″-Ph
2
-
closo
-2″,1″,8″-RuC
2
B
9
H
9
)], comprising three (Ph
2
RuC
2
B
9
H
9
) units linked by η
6
- coordination of Ph rings to the Ru atoms of the adjacent cluster. The structure of the triple cluster was established by X-ray crystallography, and the potential consequences of its formation are discussed.</description><subject>Brief Communications</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Clusters</subject><subject>Crystallography</subject><subject>Inorganic Chemistry</subject><subject>Organic Chemistry</subject><issn>1066-5285</issn><issn>1573-9171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LAzEQhoMoWKs_wFtB8BadyWy-jlK0CgUv9hzSNKtb6u6a7B7896as4MnLzBzej-Fh7BrhDgH0fUZELTgI4MJWZZywGUpN3KLG03KDUlwKI8_ZRc57ABDGmBm73bTN1xgXQ2r6Q1ykcfiIrQ8-bbvk27gIhzEPMV2ys9ofcrz63XO2eXp8Wz7z9evqZfmw5oFQDRxV3IUteRmi1GiF3tVgVSVLuVHSW0VkBRkPENBXdQhCUIxRWk3WAHmas5spt09deSsPbt-NqS2VTpSYCogIiwonVUhdzinWrk_Np0_fDsEdcbgJhys43BGHE8UjJk8u2vY9pr_k_00_L39gUg</recordid><startdate>20200801</startdate><enddate>20200801</enddate><creator>Jones, J. J.</creator><creator>Robertson, A. P. M.</creator><creator>Rosair, G. M.</creator><creator>Welch, A. J.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200801</creationdate><title>Unique triple ruthenacarborane cluster</title><author>Jones, J. J. ; Robertson, A. P. M. ; Rosair, G. M. ; Welch, A. J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-16edcb3a5ce571927df09645066865a96339238a00c1a4fcc223eee59739803a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Brief Communications</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Clusters</topic><topic>Crystallography</topic><topic>Inorganic Chemistry</topic><topic>Organic Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jones, J. J.</creatorcontrib><creatorcontrib>Robertson, A. P. M.</creatorcontrib><creatorcontrib>Rosair, G. M.</creatorcontrib><creatorcontrib>Welch, A. J.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian chemical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jones, J. J.</au><au>Robertson, A. P. M.</au><au>Rosair, G. M.</au><au>Welch, A. J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Unique triple ruthenacarborane cluster</atitle><jtitle>Russian chemical bulletin</jtitle><stitle>Russ Chem Bull</stitle><date>2020-08-01</date><risdate>2020</risdate><volume>69</volume><issue>8</issue><spage>1594</spage><epage>1597</epage><pages>1594-1597</pages><issn>1066-5285</issn><eissn>1573-9171</eissn><abstract>Dehalogenation of[1,2-Ph
2
-3,3-(PPh
3
)
2
-3-Cl-
closo/pseudocloso
-3,1,2-RuC
2
B
9
H
9
]
−
affords, in addition to the unusual “symbiotic”** cluster [(1,2-Ph
2
-
pseudocloso
-3,1,2-RuC
2
B
9
H
9
) (1′,8′-Ph
2
-
closo
-2′,1′8′-RuC
2
B
9
H
9
)], a trace amount of a triple cluster species [(1,2-Ph
2
-pseudocloso-3,1,2-RuC
2
B
9
H
9
)(1′,8′-Ph
2
-closo-2′,1′,8′-RuC
2
B
9
H9)(1″,8″-Ph
2
-
closo
-2″,1″,8″-RuC
2
B
9
H
9
)], comprising three (Ph
2
RuC
2
B
9
H
9
) units linked by η
6
- coordination of Ph rings to the Ru atoms of the adjacent cluster. The structure of the triple cluster was established by X-ray crystallography, and the potential consequences of its formation are discussed.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11172-020-2940-2</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1066-5285 |
| ispartof | Russian chemical bulletin, 2020-08, Vol.69 (8), p.1594-1597 |
| issn | 1066-5285 1573-9171 |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Brief Communications Chemistry Chemistry and Materials Science Chemistry/Food Science Clusters Crystallography Inorganic Chemistry Organic Chemistry |
| title | Unique triple ruthenacarborane cluster |
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