Michael addition curable coatings from renewable resources with enhanced adhesion performance
Novel malonate-functional polyesters from biobased and potentially biobased monomers were developed and cured through the base-catalyzed carbon-Michael addition reaction with acryloyl-functional oligomers. Both drop-in monomers, such as fully biobased diethyl malonate, and alternative raw materials,...
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| Veröffentlicht in: | JCT research 2020-09, Vol.17 (5), p.1123-1130 |
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| creator | Noordover, Bart Liu, William McCracken, Eric DeGooyer, Bill Brinkhuis, Richard Lunzer, Florian |
| description | Novel malonate-functional polyesters from biobased and potentially biobased monomers were developed and cured through the base-catalyzed carbon-Michael addition reaction with acryloyl-functional oligomers. Both drop-in monomers, such as fully biobased diethyl malonate, and alternative raw materials, such as isosorbide and vegetable oil, were introduced. Isosorbide-based polyesters show improved performance to humidity in terms of adhesion on epoxy-amine primer, while vegetable oil-containing resins lead to improved coating appearance due to better flow and levelling. This study demonstrates that biobased malonate resins, having renewable contents up to 53%, offer attractive performance benefits in 2K RMA paints. It is anticipated that, with the development of additional fully biobased polyols, renewable contents in excess of 80% can be achieved. |
| doi_str_mv | 10.1007/s11998-020-00351-2 |
| format | Article |
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It is anticipated that, with the development of additional fully biobased polyols, renewable contents in excess of 80% can be achieved.</description><identifier>ISSN: 1547-0091</identifier><identifier>EISSN: 1935-3804</identifier><identifier>EISSN: 2168-8028</identifier><identifier>DOI: 10.1007/s11998-020-00351-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adhesion ; Chemistry and Materials Science ; Corrosion and Coatings ; Industrial Chemistry/Chemical Engineering ; Materials Science ; Michael reaction ; Monomers ; Oligomers ; Polyester resins ; Polyesters ; Polymer Sciences ; Polymers ; Polyols ; Primers (coatings) ; Raw materials ; Renewable resources ; Surfaces and Interfaces ; Thin Films ; Tribology ; Vegetable oils</subject><ispartof>JCT research, 2020-09, Vol.17 (5), p.1123-1130</ispartof><rights>American Coatings Association 2020</rights><rights>American Coatings Association 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-b9ecdcd91b221b390e1cfc6430fda2358711ae9d591626653bf3e72b2e3bfe5a3</citedby><cites>FETCH-LOGICAL-c356t-b9ecdcd91b221b390e1cfc6430fda2358711ae9d591626653bf3e72b2e3bfe5a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11998-020-00351-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11998-020-00351-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Noordover, Bart</creatorcontrib><creatorcontrib>Liu, William</creatorcontrib><creatorcontrib>McCracken, Eric</creatorcontrib><creatorcontrib>DeGooyer, Bill</creatorcontrib><creatorcontrib>Brinkhuis, Richard</creatorcontrib><creatorcontrib>Lunzer, Florian</creatorcontrib><title>Michael addition curable coatings from renewable resources with enhanced adhesion performance</title><title>JCT research</title><addtitle>J Coat Technol Res</addtitle><description>Novel malonate-functional polyesters from biobased and potentially biobased monomers were developed and cured through the base-catalyzed carbon-Michael addition reaction with acryloyl-functional oligomers. 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It is anticipated that, with the development of additional fully biobased polyols, renewable contents in excess of 80% can be achieved.</description><subject>Adhesion</subject><subject>Chemistry and Materials Science</subject><subject>Corrosion and Coatings</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Materials Science</subject><subject>Michael reaction</subject><subject>Monomers</subject><subject>Oligomers</subject><subject>Polyester resins</subject><subject>Polyesters</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Polyols</subject><subject>Primers (coatings)</subject><subject>Raw materials</subject><subject>Renewable resources</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>Tribology</subject><subject>Vegetable oils</subject><issn>1547-0091</issn><issn>1935-3804</issn><issn>2168-8028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9UMtOwzAQtBBIlMIPcLLE2bC24yQ-ooqXVMQFjshynE2TqnWKnaji73EbJG6cdjQ7M7saQq453HKA4i5yrnXJQAADkIozcUJmXEvFZAnZacIqK9JK83NyEeMaQBRlKWfk87VzrcUNtXXdDV3vqRuDrTZIXW-Hzq8ibUK_pQE97o98wNiPwWGk-25oKfrWeod1CmgxHgJ2GJo-bA_sJTlr7Cbi1e-ck4_Hh_fFM1u-Pb0s7pfMSZUPrNLoaldrXgnBK6kBuWtcnkloaiukKgvOLepaaZ6LPFeyaiQWohKYECor5-Rmyt2F_mvEOJh1-tGnk0ZkCmRZgFZJJSaVC32MARuzC93Whm_DwRxqNFONJtVojjUakUxyMsUk9isMf9H_uH4AQ7F3Aw</recordid><startdate>20200901</startdate><enddate>20200901</enddate><creator>Noordover, Bart</creator><creator>Liu, William</creator><creator>McCracken, Eric</creator><creator>DeGooyer, Bill</creator><creator>Brinkhuis, Richard</creator><creator>Lunzer, Florian</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200901</creationdate><title>Michael addition curable coatings from renewable resources with enhanced adhesion performance</title><author>Noordover, Bart ; Liu, William ; McCracken, Eric ; DeGooyer, Bill ; Brinkhuis, Richard ; Lunzer, Florian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-b9ecdcd91b221b390e1cfc6430fda2358711ae9d591626653bf3e72b2e3bfe5a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adhesion</topic><topic>Chemistry and Materials Science</topic><topic>Corrosion and Coatings</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Materials Science</topic><topic>Michael reaction</topic><topic>Monomers</topic><topic>Oligomers</topic><topic>Polyester resins</topic><topic>Polyesters</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Polyols</topic><topic>Primers (coatings)</topic><topic>Raw materials</topic><topic>Renewable resources</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><topic>Tribology</topic><topic>Vegetable oils</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Noordover, Bart</creatorcontrib><creatorcontrib>Liu, William</creatorcontrib><creatorcontrib>McCracken, Eric</creatorcontrib><creatorcontrib>DeGooyer, Bill</creatorcontrib><creatorcontrib>Brinkhuis, Richard</creatorcontrib><creatorcontrib>Lunzer, Florian</creatorcontrib><collection>CrossRef</collection><jtitle>JCT research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Noordover, Bart</au><au>Liu, William</au><au>McCracken, Eric</au><au>DeGooyer, Bill</au><au>Brinkhuis, Richard</au><au>Lunzer, Florian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Michael addition curable coatings from renewable resources with enhanced adhesion performance</atitle><jtitle>JCT research</jtitle><stitle>J Coat Technol Res</stitle><date>2020-09-01</date><risdate>2020</risdate><volume>17</volume><issue>5</issue><spage>1123</spage><epage>1130</epage><pages>1123-1130</pages><issn>1547-0091</issn><eissn>1935-3804</eissn><eissn>2168-8028</eissn><abstract>Novel malonate-functional polyesters from biobased and potentially biobased monomers were developed and cured through the base-catalyzed carbon-Michael addition reaction with acryloyl-functional oligomers. 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| identifier | ISSN: 1547-0091 |
| ispartof | JCT research, 2020-09, Vol.17 (5), p.1123-1130 |
| issn | 1547-0091 1935-3804 2168-8028 |
| language | eng |
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| subjects | Adhesion Chemistry and Materials Science Corrosion and Coatings Industrial Chemistry/Chemical Engineering Materials Science Michael reaction Monomers Oligomers Polyester resins Polyesters Polymer Sciences Polymers Polyols Primers (coatings) Raw materials Renewable resources Surfaces and Interfaces Thin Films Tribology Vegetable oils |
| title | Michael addition curable coatings from renewable resources with enhanced adhesion performance |
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