Study of the Relaxational Polarization Dynamics of the LiPON Solid Electrolyte
The results of investigation of the polarization relaxation mechanism for the LiPON solid electrolyte by a discharge through an external load are presented. Test cells implemented in the form of encapsulated multilayer structures and previously studied by the standard techniques are tested on a spec...
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| Veröffentlicht in: | Russian microelectronics 2020, Vol.49 (5), p.345-357 |
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| creator | Rudyi, A. S. Lebedev, M. E. Mironenko, A. A. Mazaletskii, L. A. Naumov, V. V. Novozhilova, A. V. Fedorov, I. S. Churilov, A. B. |
| description | The results of investigation of the polarization relaxation mechanism for the LiPON solid electrolyte by a discharge through an external load are presented. Test cells implemented in the form of encapsulated multilayer structures
and previously studied by the standard techniques are tested on a special bench measuring discharge characteristics. The core of the method lies in charging the test cell from a stable voltage source up to saturation with the subsequent rapid switch to precision resistance and detection of the voltage drop. The measurements are taken in the load range from 0.1 MΩ to 10 Ω in the temperature range of –50 to 25°C. An equivalent electric circuit for the test cell is proposed, for which a mathematical model of the discharge process is constructed. In the context of the proposed model, the features of the experimental curves are explained by the processes of redox reactions of the lithium ions at the surface of the electrodes and generation of nonequilibrium charge carriers in the bulk upon the charging and discharging of the test cell. |
| doi_str_mv | 10.1134/S1063739720040095 |
| format | Article |
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and previously studied by the standard techniques are tested on a special bench measuring discharge characteristics. The core of the method lies in charging the test cell from a stable voltage source up to saturation with the subsequent rapid switch to precision resistance and detection of the voltage drop. The measurements are taken in the load range from 0.1 MΩ to 10 Ω in the temperature range of –50 to 25°C. An equivalent electric circuit for the test cell is proposed, for which a mathematical model of the discharge process is constructed. In the context of the proposed model, the features of the experimental curves are explained by the processes of redox reactions of the lithium ions at the surface of the electrodes and generation of nonequilibrium charge carriers in the bulk upon the charging and discharging of the test cell.</description><subject>Charging</subject><subject>Circuits</subject><subject>Current carriers</subject><subject>Discharge</subject><subject>Electrical Engineering</subject><subject>Electrolytes</subject><subject>Electrolytic cells</subject><subject>Engineering</subject><subject>Lithium ions</subject><subject>Multilayers</subject><subject>Polarization</subject><subject>Redox reactions</subject><subject>Solid electrolytes</subject><subject>Voltage drop</subject><issn>1063-7397</issn><issn>1608-3415</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kE9Lw0AQxRdRsFY_gLcFz9GZTLKbPUqtf6C0xeo5bJONpmy7dTcF46c3NYoH8TQzvN97DI-xc4RLREquFgiCJCkZAyQAKj1gAxSQRZRgetjtnRzt9WN2EsIKAAGEGLDpotmVLXcVb14NfzRWv-umdhtt-dxZ7euPr5PftBu9rovwQ07q-WzKF87WJR9bUzTe2bYxp-yo0jaYs-85ZM-346fRfTSZ3T2MridREUtII0JFxmhYiowkQqkTgUTLkqpYqDirKMkoU0otMUFAXZWYKVmkKUogkLqgIbvoc7feve1MaPKV2_nu65DHSQqUYgxZR2FPFd6F4E2Vb3291r7NEfJ9bfmf2jpP3HtCx25ejP9N_t_0Ce-qbCs</recordid><startdate>2020</startdate><enddate>2020</enddate><creator>Rudyi, A. S.</creator><creator>Lebedev, M. E.</creator><creator>Mironenko, A. A.</creator><creator>Mazaletskii, L. A.</creator><creator>Naumov, V. V.</creator><creator>Novozhilova, A. V.</creator><creator>Fedorov, I. S.</creator><creator>Churilov, A. B.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2020</creationdate><title>Study of the Relaxational Polarization Dynamics of the LiPON Solid Electrolyte</title><author>Rudyi, A. S. ; Lebedev, M. E. ; Mironenko, A. A. ; Mazaletskii, L. A. ; Naumov, V. V. ; Novozhilova, A. V. ; Fedorov, I. S. ; Churilov, A. B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2705-3193eea0b683710da46133bd3f26928f34838999b14101afd1897c55170307ac3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Charging</topic><topic>Circuits</topic><topic>Current carriers</topic><topic>Discharge</topic><topic>Electrical Engineering</topic><topic>Electrolytes</topic><topic>Electrolytic cells</topic><topic>Engineering</topic><topic>Lithium ions</topic><topic>Multilayers</topic><topic>Polarization</topic><topic>Redox reactions</topic><topic>Solid electrolytes</topic><topic>Voltage drop</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rudyi, A. S.</creatorcontrib><creatorcontrib>Lebedev, M. E.</creatorcontrib><creatorcontrib>Mironenko, A. A.</creatorcontrib><creatorcontrib>Mazaletskii, L. A.</creatorcontrib><creatorcontrib>Naumov, V. V.</creatorcontrib><creatorcontrib>Novozhilova, A. V.</creatorcontrib><creatorcontrib>Fedorov, I. S.</creatorcontrib><creatorcontrib>Churilov, A. B.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian microelectronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rudyi, A. S.</au><au>Lebedev, M. E.</au><au>Mironenko, A. A.</au><au>Mazaletskii, L. A.</au><au>Naumov, V. V.</au><au>Novozhilova, A. V.</au><au>Fedorov, I. S.</au><au>Churilov, A. B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study of the Relaxational Polarization Dynamics of the LiPON Solid Electrolyte</atitle><jtitle>Russian microelectronics</jtitle><stitle>Russ Microelectron</stitle><date>2020</date><risdate>2020</risdate><volume>49</volume><issue>5</issue><spage>345</spage><epage>357</epage><pages>345-357</pages><issn>1063-7397</issn><eissn>1608-3415</eissn><abstract>The results of investigation of the polarization relaxation mechanism for the LiPON solid electrolyte by a discharge through an external load are presented. Test cells implemented in the form of encapsulated multilayer structures
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| subjects | Charging Circuits Current carriers Discharge Electrical Engineering Electrolytes Electrolytic cells Engineering Lithium ions Multilayers Polarization Redox reactions Solid electrolytes Voltage drop |
| title | Study of the Relaxational Polarization Dynamics of the LiPON Solid Electrolyte |
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