Silver(III) Periodate Complex—An Oxidant for Free Radical Induced Uncatalyzed and Ruthenium(III) Catalyzed Oxidation of Barbituric Acid

The oxidation of a heterocyclic compound—barbituric acid (BBA) by diperiodatoargentate(III) (DPA) was carried out in the absence and presence of ruthenium(III) catalyst in alkaline medium with a constant ionic strength of 0.20 mol dm –3 at 298 K. The reaction was monitored spectrophotometrically. Th...

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Veröffentlicht in:	Russian Journal of Physical Chemistry A 2020-10, Vol.94 (10), p.2010-2023
Hauptverfasser:	Bagoji, Atmanand M., Konnur, Santosh B., Gokavi, Naveen M., Buddanavar, Arunkumar T., Nandibewoor, Sharanappa T.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Kinetics and Catalysis Chemical reactions Chemistry Chemistry and Materials Science Free radicals Heterocyclic compounds Mathematical analysis Oxidation Oxidizing agents Physical Chemistry Ruthenium Spectrophotometry Thermodynamic equilibrium Unity
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