Sensitive detection using heterostructure of black phosphorus, transition metal di-chalcogenides and MXene in SPR sensor
This work presents van der Waals heterostructure (vdWh) of Black phosphorus (BP)/Transition metal di-chalcogenides (TMDs)/MXene (Ti 3 C 2 T x ) based highly sensitive novel SPR sensor for biochemical sensing. 2D layered nature of BP, TMDs, and MXene allow them to form van der Waals heterostructure b...
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creator | Pal, Sarika Verma, Alka Prajapati, Y. K. Saini, J. P. |
description | This work presents van der Waals heterostructure (vdWh) of Black phosphorus (BP)/Transition metal di-chalcogenides (TMDs)/MXene (Ti
3
C
2
T
x
) based highly sensitive novel SPR sensor for biochemical sensing. 2D layered nature of BP, TMDs, and MXene allow them to form van der Waals heterostructure by vertically stacking them together to get exotic electronic and optical properties useful for surface plasmon resonance (SPR) sensing. Unique properties of MXene like its layered architecture, larger surface area, highly accessible hydrophilic surface terminations, chemical stability, smaller work function, and strong light-matter interaction are utilized to enhance the sensitivity of the proposed sensor. The proposed work theoretically analyzes its sensitivity (S) and compares it with other structures. The anisotropic nature of 2D layered BP is used to tune the sensitivity of the proposed sensor. The highest sensitivity of 388
ο
/RIU is achieved at 633 nm wavelength for WS
2
tri-layer in the proposed biochemical sensor. The SPs field variation along normal to interface validates the highest sensitivity obtained for the proposed heterostructure SPR sensor through field plots. These results will open an innovative route to design and develop such an SPR biochemical sensor practically, with fabrication possibilities of MXene with TMDs and BP. |
doi_str_mv | 10.1007/s00339-020-03998-1 |
format | Article |
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3
C
2
T
x
) based highly sensitive novel SPR sensor for biochemical sensing. 2D layered nature of BP, TMDs, and MXene allow them to form van der Waals heterostructure by vertically stacking them together to get exotic electronic and optical properties useful for surface plasmon resonance (SPR) sensing. Unique properties of MXene like its layered architecture, larger surface area, highly accessible hydrophilic surface terminations, chemical stability, smaller work function, and strong light-matter interaction are utilized to enhance the sensitivity of the proposed sensor. The proposed work theoretically analyzes its sensitivity (S) and compares it with other structures. The anisotropic nature of 2D layered BP is used to tune the sensitivity of the proposed sensor. The highest sensitivity of 388
ο
/RIU is achieved at 633 nm wavelength for WS
2
tri-layer in the proposed biochemical sensor. The SPs field variation along normal to interface validates the highest sensitivity obtained for the proposed heterostructure SPR sensor through field plots. These results will open an innovative route to design and develop such an SPR biochemical sensor practically, with fabrication possibilities of MXene with TMDs and BP.</description><identifier>ISSN: 0947-8396</identifier><identifier>EISSN: 1432-0630</identifier><identifier>DOI: 10.1007/s00339-020-03998-1</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Applied physics ; Biochemistry ; Chalcogenides ; Characterization and Evaluation of Materials ; Condensed Matter Physics ; Heterostructures ; Machines ; Manufacturing ; Materials science ; MXenes ; Nanotechnology ; Optical and Electronic Materials ; Optical properties ; Phosphorus ; Physics ; Physics and Astronomy ; Processes ; Rapid Communications ; Sensitivity analysis ; Sensitivity enhancement ; Sensors ; Surface stability ; Surfaces and Interfaces ; Thin Films ; Transition metals ; Work functions</subject><ispartof>Applied physics. A, Materials science & processing, 2020-10, Vol.126 (10), Article 809</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-be8641f260212e9876b37bd3e5acbd52f151922fddec2df61941dff0f4280fa73</citedby><cites>FETCH-LOGICAL-c319t-be8641f260212e9876b37bd3e5acbd52f151922fddec2df61941dff0f4280fa73</cites><orcidid>0000-0002-6752-5667</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00339-020-03998-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00339-020-03998-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Pal, Sarika</creatorcontrib><creatorcontrib>Verma, Alka</creatorcontrib><creatorcontrib>Prajapati, Y. K.</creatorcontrib><creatorcontrib>Saini, J. P.</creatorcontrib><title>Sensitive detection using heterostructure of black phosphorus, transition metal di-chalcogenides and MXene in SPR sensor</title><title>Applied physics. A, Materials science & processing</title><addtitle>Appl. Phys. A</addtitle><description>This work presents van der Waals heterostructure (vdWh) of Black phosphorus (BP)/Transition metal di-chalcogenides (TMDs)/MXene (Ti
3
C
2
T
x
) based highly sensitive novel SPR sensor for biochemical sensing. 2D layered nature of BP, TMDs, and MXene allow them to form van der Waals heterostructure by vertically stacking them together to get exotic electronic and optical properties useful for surface plasmon resonance (SPR) sensing. Unique properties of MXene like its layered architecture, larger surface area, highly accessible hydrophilic surface terminations, chemical stability, smaller work function, and strong light-matter interaction are utilized to enhance the sensitivity of the proposed sensor. The proposed work theoretically analyzes its sensitivity (S) and compares it with other structures. The anisotropic nature of 2D layered BP is used to tune the sensitivity of the proposed sensor. The highest sensitivity of 388
ο
/RIU is achieved at 633 nm wavelength for WS
2
tri-layer in the proposed biochemical sensor. The SPs field variation along normal to interface validates the highest sensitivity obtained for the proposed heterostructure SPR sensor through field plots. These results will open an innovative route to design and develop such an SPR biochemical sensor practically, with fabrication possibilities of MXene with TMDs and BP.</description><subject>Applied physics</subject><subject>Biochemistry</subject><subject>Chalcogenides</subject><subject>Characterization and Evaluation of Materials</subject><subject>Condensed Matter Physics</subject><subject>Heterostructures</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Materials science</subject><subject>MXenes</subject><subject>Nanotechnology</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Phosphorus</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Processes</subject><subject>Rapid Communications</subject><subject>Sensitivity analysis</subject><subject>Sensitivity enhancement</subject><subject>Sensors</subject><subject>Surface stability</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>Transition metals</subject><subject>Work functions</subject><issn>0947-8396</issn><issn>1432-0630</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kE9rGzEQxUVJoa7bL9CTINeoGUn7T8cQ2jTgkBCnkJvQSiN7XVvrSNrQfPsqdiG3DAzDwPvNYx4h3zh85wDteQKQUjEQwEAq1TH-gcx4JQWDRsIJmYGqWtZJ1Xwin1PaQKlKiBn5u8SQhjw8I3WY0eZhDHRKQ1jRddnjmHKcbJ4i0tHTfmvsH7pfj6l0nNIZzdEc-ELtMJstdQOza7O14wrD4DBRExy9ecSAdAh0eXdPU3Ec4xfy0Zttwq__55z8_vnj4fIXW9xeXV9eLJiVXGXWY9dU3IsGBBeourbpZds7ibWxvauF5zVXQnjn0ArnG64q7rwHX4kOvGnlnJwe7-7j-DRhynozTjEUSy2qGiQXUtRFJY4qWz5OEb3ex2Fn4ovmoF8T1seEdUlYHxLWvEDyCKUiDiuMb6ffof4Ba_OAqg</recordid><startdate>20201001</startdate><enddate>20201001</enddate><creator>Pal, Sarika</creator><creator>Verma, Alka</creator><creator>Prajapati, Y. K.</creator><creator>Saini, J. P.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-6752-5667</orcidid></search><sort><creationdate>20201001</creationdate><title>Sensitive detection using heterostructure of black phosphorus, transition metal di-chalcogenides and MXene in SPR sensor</title><author>Pal, Sarika ; Verma, Alka ; Prajapati, Y. K. ; Saini, J. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-be8641f260212e9876b37bd3e5acbd52f151922fddec2df61941dff0f4280fa73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Applied physics</topic><topic>Biochemistry</topic><topic>Chalcogenides</topic><topic>Characterization and Evaluation of Materials</topic><topic>Condensed Matter Physics</topic><topic>Heterostructures</topic><topic>Machines</topic><topic>Manufacturing</topic><topic>Materials science</topic><topic>MXenes</topic><topic>Nanotechnology</topic><topic>Optical and Electronic Materials</topic><topic>Optical properties</topic><topic>Phosphorus</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Processes</topic><topic>Rapid Communications</topic><topic>Sensitivity analysis</topic><topic>Sensitivity enhancement</topic><topic>Sensors</topic><topic>Surface stability</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><topic>Transition metals</topic><topic>Work functions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pal, Sarika</creatorcontrib><creatorcontrib>Verma, Alka</creatorcontrib><creatorcontrib>Prajapati, Y. K.</creatorcontrib><creatorcontrib>Saini, J. P.</creatorcontrib><collection>CrossRef</collection><jtitle>Applied physics. A, Materials science & processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pal, Sarika</au><au>Verma, Alka</au><au>Prajapati, Y. K.</au><au>Saini, J. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sensitive detection using heterostructure of black phosphorus, transition metal di-chalcogenides and MXene in SPR sensor</atitle><jtitle>Applied physics. A, Materials science & processing</jtitle><stitle>Appl. Phys. A</stitle><date>2020-10-01</date><risdate>2020</risdate><volume>126</volume><issue>10</issue><artnum>809</artnum><issn>0947-8396</issn><eissn>1432-0630</eissn><abstract>This work presents van der Waals heterostructure (vdWh) of Black phosphorus (BP)/Transition metal di-chalcogenides (TMDs)/MXene (Ti
3
C
2
T
x
) based highly sensitive novel SPR sensor for biochemical sensing. 2D layered nature of BP, TMDs, and MXene allow them to form van der Waals heterostructure by vertically stacking them together to get exotic electronic and optical properties useful for surface plasmon resonance (SPR) sensing. Unique properties of MXene like its layered architecture, larger surface area, highly accessible hydrophilic surface terminations, chemical stability, smaller work function, and strong light-matter interaction are utilized to enhance the sensitivity of the proposed sensor. The proposed work theoretically analyzes its sensitivity (S) and compares it with other structures. The anisotropic nature of 2D layered BP is used to tune the sensitivity of the proposed sensor. The highest sensitivity of 388
ο
/RIU is achieved at 633 nm wavelength for WS
2
tri-layer in the proposed biochemical sensor. The SPs field variation along normal to interface validates the highest sensitivity obtained for the proposed heterostructure SPR sensor through field plots. These results will open an innovative route to design and develop such an SPR biochemical sensor practically, with fabrication possibilities of MXene with TMDs and BP.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00339-020-03998-1</doi><orcidid>https://orcid.org/0000-0002-6752-5667</orcidid></addata></record> |
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subjects | Applied physics Biochemistry Chalcogenides Characterization and Evaluation of Materials Condensed Matter Physics Heterostructures Machines Manufacturing Materials science MXenes Nanotechnology Optical and Electronic Materials Optical properties Phosphorus Physics Physics and Astronomy Processes Rapid Communications Sensitivity analysis Sensitivity enhancement Sensors Surface stability Surfaces and Interfaces Thin Films Transition metals Work functions |
title | Sensitive detection using heterostructure of black phosphorus, transition metal di-chalcogenides and MXene in SPR sensor |
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