Synthesis of quinoxaline, benzimidazole and pyrazole derivatives under the catalytic influence of biosurfactant-stabilized iron nanoparticles in water
We have reported the synthesis, characterization, and catalytic applications of amorphous iron nanoparticles (FeNPs) using aqueous leaves extract of renewable natural resource Boswellia serrata plant. Synthesized FeNPs were stabilized in situ by the addition of aqueous pod extracts of Acacia concinn...
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| Veröffentlicht in: | Research on chemical intermediates 2020-11, Vol.46 (11), p.5069-5086 |
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| creator | Arde, Satyanarayan M. Patil, Audumbar D. Mane, Ananda H. Salokhe, Prabha R. Salunkhe, Rajashri S. |
| description | We have reported the synthesis, characterization, and catalytic applications of amorphous iron nanoparticles (FeNPs) using aqueous leaves extract of renewable natural resource
Boswellia serrata
plant. Synthesized FeNPs were stabilized in situ by the addition of aqueous pod extracts of
Acacia concinna
as a biosurfactant (pH 3.11). The structural investigation of biosynthesized nanoparticles was performed using UV–visible spectroscopy, X-ray diffraction analysis, selected area electron diffraction, energy-dispersive X-ray spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and BET analysis. The FeNPs were amorphous in nature with average particle size ~ 19 nm and successfully employed as heterogeneous catalyst for the synthesis of quinoxaline, benzimidazole, and pyrazole derivatives in aqueous medium at ambient conditions. The FeNPs could be recycled up to five times with modest change in the catalytic activity.
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| doi_str_mv | 10.1007/s11164-020-04240-6 |
| format | Article |
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Boswellia serrata
plant. Synthesized FeNPs were stabilized in situ by the addition of aqueous pod extracts of
Acacia concinna
as a biosurfactant (pH 3.11). The structural investigation of biosynthesized nanoparticles was performed using UV–visible spectroscopy, X-ray diffraction analysis, selected area electron diffraction, energy-dispersive X-ray spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and BET analysis. The FeNPs were amorphous in nature with average particle size ~ 19 nm and successfully employed as heterogeneous catalyst for the synthesis of quinoxaline, benzimidazole, and pyrazole derivatives in aqueous medium at ambient conditions. The FeNPs could be recycled up to five times with modest change in the catalytic activity.
Graphic abstract</description><identifier>ISSN: 0922-6168</identifier><identifier>EISSN: 1568-5675</identifier><identifier>DOI: 10.1007/s11164-020-04240-6</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Aqueous solutions ; Catalysis ; Catalytic activity ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Chemistry, Multidisciplinary ; Derivatives ; Electron diffraction ; Electron microscopy ; Inorganic Chemistry ; Iron ; Microscopy ; Nanoparticles ; Natural resources ; Photoelectrons ; Physical Chemistry ; Physical Sciences ; Pyrazole ; Quinoxalines ; Science & Technology ; Spectroscopic analysis ; Spectrum analysis ; Surfactants ; Thermogravimetric analysis ; X-ray spectroscopy</subject><ispartof>Research on chemical intermediates, 2020-11, Vol.46 (11), p.5069-5086</ispartof><rights>Springer Nature B.V. 2020</rights><rights>Springer Nature B.V. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>18</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000563611100002</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c356t-dc900e4cf0f3d1a13963f89357cae371b11001547c612be09c0fe71e729e05f43</citedby><cites>FETCH-LOGICAL-c356t-dc900e4cf0f3d1a13963f89357cae371b11001547c612be09c0fe71e729e05f43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11164-020-04240-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11164-020-04240-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27931,27932,28255,41495,42564,51326</link.rule.ids></links><search><creatorcontrib>Arde, Satyanarayan M.</creatorcontrib><creatorcontrib>Patil, Audumbar D.</creatorcontrib><creatorcontrib>Mane, Ananda H.</creatorcontrib><creatorcontrib>Salokhe, Prabha R.</creatorcontrib><creatorcontrib>Salunkhe, Rajashri S.</creatorcontrib><title>Synthesis of quinoxaline, benzimidazole and pyrazole derivatives under the catalytic influence of biosurfactant-stabilized iron nanoparticles in water</title><title>Research on chemical intermediates</title><addtitle>Res Chem Intermed</addtitle><addtitle>RES CHEM INTERMEDIAT</addtitle><description>We have reported the synthesis, characterization, and catalytic applications of amorphous iron nanoparticles (FeNPs) using aqueous leaves extract of renewable natural resource
Boswellia serrata
plant. Synthesized FeNPs were stabilized in situ by the addition of aqueous pod extracts of
Acacia concinna
as a biosurfactant (pH 3.11). The structural investigation of biosynthesized nanoparticles was performed using UV–visible spectroscopy, X-ray diffraction analysis, selected area electron diffraction, energy-dispersive X-ray spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and BET analysis. The FeNPs were amorphous in nature with average particle size ~ 19 nm and successfully employed as heterogeneous catalyst for the synthesis of quinoxaline, benzimidazole, and pyrazole derivatives in aqueous medium at ambient conditions. The FeNPs could be recycled up to five times with modest change in the catalytic activity.
Graphic abstract</description><subject>Aqueous solutions</subject><subject>Catalysis</subject><subject>Catalytic activity</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry, Multidisciplinary</subject><subject>Derivatives</subject><subject>Electron diffraction</subject><subject>Electron microscopy</subject><subject>Inorganic Chemistry</subject><subject>Iron</subject><subject>Microscopy</subject><subject>Nanoparticles</subject><subject>Natural resources</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>Physical Sciences</subject><subject>Pyrazole</subject><subject>Quinoxalines</subject><subject>Science & Technology</subject><subject>Spectroscopic analysis</subject><subject>Spectrum analysis</subject><subject>Surfactants</subject><subject>Thermogravimetric analysis</subject><subject>X-ray spectroscopy</subject><issn>0922-6168</issn><issn>1568-5675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNkc1u1DAUhS1EJYaWF2BliSW4XNuJkyzRiJ9KlVgAa8txrsFVak9tp2XmRdj2WXgyPATBDnV1daXznftzCHnO4ZwDdK8z51w1DAQwaEQDTD0iG96qnrWqax-TDQxCMMVV_4Q8zfkKgLd9Dxvy49M-lG-YfabR0ZvFh_jdzD7gKzpiOPhrP5lDnJGaMNHdPq3NhMnfmuJvMdMl1I5WD2pNMfO-eEt9cPOCweLP--o6-piX5IwtJhSWixn97A84UZ9ioMGEuDOpYnN184HemYLpjJw4M2d89qeeki_v3n7efmCXH99fbN9cMitbVdhkBwBsrAMnJ264HJR0_SDbzhqUHR85P57adFZxMSIMFhx2HDsxILSukafkxeq7S_FmwVz0VVxSqCO1aFoQUig1VJVYVTbFnBM6vUv-2qS95qCPAeg1AF0D0L8D0KpC_Qrd4Rhdtv74kL8gALRKKn5cEEBsfan_jGEbl1Aq-vLhaFXLVZ2rInzF9O-G_6z3CwMRrj0</recordid><startdate>20201101</startdate><enddate>20201101</enddate><creator>Arde, Satyanarayan M.</creator><creator>Patil, Audumbar D.</creator><creator>Mane, Ananda H.</creator><creator>Salokhe, Prabha R.</creator><creator>Salunkhe, Rajashri S.</creator><general>Springer Netherlands</general><general>Springer Nature</general><general>Springer Nature B.V</general><scope>1KN</scope><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20201101</creationdate><title>Synthesis of quinoxaline, benzimidazole and pyrazole derivatives under the catalytic influence of biosurfactant-stabilized iron nanoparticles in water</title><author>Arde, Satyanarayan M. ; Patil, Audumbar D. ; Mane, Ananda H. ; Salokhe, Prabha R. ; Salunkhe, Rajashri S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-dc900e4cf0f3d1a13963f89357cae371b11001547c612be09c0fe71e729e05f43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aqueous solutions</topic><topic>Catalysis</topic><topic>Catalytic activity</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry, Multidisciplinary</topic><topic>Derivatives</topic><topic>Electron diffraction</topic><topic>Electron microscopy</topic><topic>Inorganic Chemistry</topic><topic>Iron</topic><topic>Microscopy</topic><topic>Nanoparticles</topic><topic>Natural resources</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>Physical Sciences</topic><topic>Pyrazole</topic><topic>Quinoxalines</topic><topic>Science & Technology</topic><topic>Spectroscopic analysis</topic><topic>Spectrum analysis</topic><topic>Surfactants</topic><topic>Thermogravimetric analysis</topic><topic>X-ray spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Arde, Satyanarayan M.</creatorcontrib><creatorcontrib>Patil, Audumbar D.</creatorcontrib><creatorcontrib>Mane, Ananda H.</creatorcontrib><creatorcontrib>Salokhe, Prabha R.</creatorcontrib><creatorcontrib>Salunkhe, Rajashri S.</creatorcontrib><collection>Current Chemical Reactions</collection><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>CrossRef</collection><jtitle>Research on chemical intermediates</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arde, Satyanarayan M.</au><au>Patil, Audumbar D.</au><au>Mane, Ananda H.</au><au>Salokhe, Prabha R.</au><au>Salunkhe, Rajashri S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of quinoxaline, benzimidazole and pyrazole derivatives under the catalytic influence of biosurfactant-stabilized iron nanoparticles in water</atitle><jtitle>Research on chemical intermediates</jtitle><stitle>Res Chem Intermed</stitle><stitle>RES CHEM INTERMEDIAT</stitle><date>2020-11-01</date><risdate>2020</risdate><volume>46</volume><issue>11</issue><spage>5069</spage><epage>5086</epage><pages>5069-5086</pages><issn>0922-6168</issn><eissn>1568-5675</eissn><abstract>We have reported the synthesis, characterization, and catalytic applications of amorphous iron nanoparticles (FeNPs) using aqueous leaves extract of renewable natural resource
Boswellia serrata
plant. Synthesized FeNPs were stabilized in situ by the addition of aqueous pod extracts of
Acacia concinna
as a biosurfactant (pH 3.11). The structural investigation of biosynthesized nanoparticles was performed using UV–visible spectroscopy, X-ray diffraction analysis, selected area electron diffraction, energy-dispersive X-ray spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and BET analysis. The FeNPs were amorphous in nature with average particle size ~ 19 nm and successfully employed as heterogeneous catalyst for the synthesis of quinoxaline, benzimidazole, and pyrazole derivatives in aqueous medium at ambient conditions. The FeNPs could be recycled up to five times with modest change in the catalytic activity.
Graphic abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11164-020-04240-6</doi><tpages>18</tpages></addata></record> |
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| subjects | Aqueous solutions Catalysis Catalytic activity Chemical synthesis Chemistry Chemistry and Materials Science Chemistry, Multidisciplinary Derivatives Electron diffraction Electron microscopy Inorganic Chemistry Iron Microscopy Nanoparticles Natural resources Photoelectrons Physical Chemistry Physical Sciences Pyrazole Quinoxalines Science & Technology Spectroscopic analysis Spectrum analysis Surfactants Thermogravimetric analysis X-ray spectroscopy |
| title | Synthesis of quinoxaline, benzimidazole and pyrazole derivatives under the catalytic influence of biosurfactant-stabilized iron nanoparticles in water |
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