Effect of “Sodium Sulfite–Ascorbic Acid” Complex Antioxidant Additive on the Composition, Structure and Semiconducting Properties of PbSe Film

Comparative experimental data, using dynamic light scattering methods, scanning electron and atomic force microscopy, on the composition, crystal structure, semiconductor and photoelectric properties of PbSe films deposited at the presence of sodium sulfite Na 2 SO 3 and “sodium sulfite–ascorbic aci...

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Veröffentlicht in:Physics of the solid state 2020-10, Vol.62 (10), p.1949-1959
Hauptverfasser: Maskaeva, L. N., Yurk, V. M., Markov, V. F., Voronin, V. I.
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container_end_page 1959
container_issue 10
container_start_page 1949
container_title Physics of the solid state
container_volume 62
creator Maskaeva, L. N.
Yurk, V. M.
Markov, V. F.
Voronin, V. I.
description Comparative experimental data, using dynamic light scattering methods, scanning electron and atomic force microscopy, on the composition, crystal structure, semiconductor and photoelectric properties of PbSe films deposited at the presence of sodium sulfite Na 2 SO 3 and “sodium sulfite–ascorbic acid” complex antioxidant additive are presented. Significant changes in morphology, elemental and phase composition, the period of the crystal lattice of PbSe films been synthesized in the presence of Na 2 SO 3 and Na 2 SO 3  + C 6 H 8 O 6 anti-oxidants before and after their thermoactivation at 653 K are found. It is shown that the introduction of a complex additive in comparison with Na 2 SO 3 increases the homogeneity of the particles forming the layer, decreases the microstresses in it, reduces the value of thermal band gap from 0.349 to 0.308 eV, and increases the volt-watt sensitivity of the films by 28–30%.
doi_str_mv 10.1134/S1063783420100212
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source SpringerNature Journals
subjects Antioxidants
Ascorbic acid
Atomic force microscopy
Crystal lattices
Crystal structure
Crystals
Homogeneity
Lead selenides
Oxidizing agents
Phase composition
Photoelectric effect
Photoelectricity
Photon correlation spectroscopy
Physics
Physics and Astronomy
Sodium sulfite
Solid State Physics
Structure
Sulfites
Surface Physics and Thin Films
Vitamin C
title Effect of “Sodium Sulfite–Ascorbic Acid” Complex Antioxidant Additive on the Composition, Structure and Semiconducting Properties of PbSe Film
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