Durability of YSZ coated Ti2AlC in 1300°C high velocity burner rig tests

A thermal barrier coating system survived 500 h in cyclic burner rig tests at 1300°C, exceeding the life of all previous systems. An yttria stabilized zirconia (7YSZ) thermal barrier coating (TBC) was plasma sprayed on the oxidation resistant Ti2AlC MAX phase and tested in a jet fuel burner. No coat...

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Veröffentlicht in:Journal of the American Ceramic Society 2020-12, Vol.103 (12), p.7014-7030
Hauptverfasser: Cuy, Michael D, Harder, Bryan J., Garg, Anita, Rogers, Richard B.
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container_title Journal of the American Ceramic Society
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creator Cuy, Michael D
Harder, Bryan J.
Garg, Anita
Rogers, Richard B.
description A thermal barrier coating system survived 500 h in cyclic burner rig tests at 1300°C, exceeding the life of all previous systems. An yttria stabilized zirconia (7YSZ) thermal barrier coating (TBC) was plasma sprayed on the oxidation resistant Ti2AlC MAX phase and tested in a jet fuel burner. No coating spallation or recession was observed, only a 2.4 mg/sq.cm mass gain due to typical cubic Al2O3 oxidation kinetics. The modest weight gain contrasted with large TBC spallation or oxide volatility losses that might occur under cyclic, high velocity (~100 m/s) burner conditions. The coating surface exhibited colonies of [111]flourite fiber-textured columns separated by craze crack patterns, but with no visible moisture attack. The thickness of the alumina scale under the YSZ face was >20 μm, more than twice that formed on TBC/superalloy systems at failure. TiO2 nodules, initially formed on the uncoated backside, were then removed as volatile hydroxides formed in high temperature, high velocity water vapor (~10%). Overall, the test indicated the exceptional stability of the YSZ/Ti2AlC system under turbine conditions, due in large part to good thermal expansion matching.
doi_str_mv 10.1111/jace.17154
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source NASA Technical Reports Server; Wiley Online Library All Journals
subjects Aeronautics (General)
alumina
Aluminum oxide
Hydroxides
Jet engine fuels
MAX phases
Nodules
Oxidation resistance
Spallation
Superalloys
Thermal barrier coatings
thermal barrier coatings (TBC)
Thermal expansion
Titanium dioxide
Turbines
Water vapor
Yttria-stabilized zirconia
Yttrium oxide
zirconia: yttria stabilized
Zirconium dioxide
title Durability of YSZ coated Ti2AlC in 1300°C high velocity burner rig tests
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